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Bismuth Pentafluoride
Bismuth pentafluoride is an inorganic compound with the formula BiF5. It is a white solid that is highly reactive. The compound is of interest to researchers but not of particular value. Structure BiF5 is polymeric and consists of linear chains of ''trans''-bridged corner sharing BiF6 octahedra. This is the same structure as ''α''-UF5. Preparation BiF5 can be prepared by treating BiF3 with F2 at 500 °C. :BiF3 + F2 → BiF5 In an alternative synthesis, ClF3 is the fluorinating agent at 350 °C. :BiF3 + ClF3 → BiF5 + ClF Reactions Bismuth pentafluoride is the most reactive of the pnictogen pentafluorides and is an extremely strong fluorinating agent. It reacts vigorously with water to form ozone and oxygen difluoride, and with iodine or sulfur at room temperature. BiF5 fluorinates paraffin oil (hydrocarbons In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Octahedral Molecular Geometry
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix '' octa''. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, , which is not octahedral in the mathematical sense due to the orientation of the bonds, is referred to as octahedral. The concept of octahedral coordination geometry was developed by Alfred Wer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorinating Agent
In chemistry, halogenation is a chemical reaction that entails the introduction of one or more halogens into a compound. Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polymers, drugs. This kind of conversion is in fact so common that a comprehensive overview is challenging. This article mainly deals with halogenation using elemental halogens (F2, Cl2, Br2, I2). Halides are also commonly introduced using salts of the halides and halogen acids. Many specialized reagents exist for and introducing halogens into diverse substrates, e.g. thionyl chloride. Organic chemistry Several pathways exist for the halogenation of organic compounds, including free radical halogenation, ketone halogenation, electrophilic halogenation, and halogen addition reaction. The nature of the substrate determines the pathway. The facility of halogenation is influenced by the halogen. Fluorine and chlorine are more electrophilic and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorides
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nomen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bismuth Compounds
Bismuth compounds are compounds containing the element bismuth (Bi). Bismuth forms trivalent and pentavalent compounds, the trivalent ones being more common. Many of its chemical properties are similar to those of arsenic and antimony, although they are less toxic than derivatives of those lighter elements. Oxides and sulfides At elevated temperatures, the vapors of the metal combine rapidly with oxygen, forming the yellow trioxide, . Wiberg, p. 768. Greenwood, p. 553. When molten, at temperatures above 710 °C, this oxide corrodes any metal oxide and even platinum. Krüger, p. 185 On reaction with a base, it forms two series of oxyanions: , which is polymeric and forms linear chains, and . The anion in is a cubic octameric anion, , whereas the anion in is tetrameric. The dark red bismuth(V) oxide, , is unstable, liberating gas upon heating. The compound NaBiO3 is a strong oxidising agent. Greenwood, p. 578. Bismuth sulfide, , occurs naturally in bismuth ores. It i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chlorine Monofluoride
Chlorine monofluoride is a volatile interhalogen compound with the chemical formula ClF. It is a colourless gas at room temperature and is stable even at high temperatures. When cooled to −100 °C, ClF condenses as a pale yellow liquid. Many of its properties are intermediate between its parent halogens, Cl2 and F2. Reactivity Chlorine monofluoride is a versatile fluorinating agent, converting metals and non-metals to their fluorides and releasing Cl2 in the process. For example, it converts tungsten to tungsten hexafluoride and selenium to selenium tetrafluoride: :W + 6 ClF → WF6 + 3 Cl2 :Se + 4 ClF → SeF4 + 2 Cl2 FCl can also chlorofluorinate compounds, either by addition across a multiple bond or via oxidation. For example, it adds fluorine and chlorine to the carbon of carbon monoxide, yielding carbonyl chloride fluoride: :CO + ClF → See also *Chlorine fluoride A chlorine fluoride is an interhalogen compound containing only chlorine and fluorine. {, cl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chlorine
Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval alchemists, which commonly involved the heating of chloride salts like ammonium chloride ( sal ammoniac) and sodium chloride (common salt), producing various chemical substances containing chlorine such as hydrogen chloride, mercury(II) chloride (corrosive sublimate), and hydrochloric acid (in the form of ). However, the nature of free chlorine gas as a separate substance was only recognised aroun ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromine Trifluoride
Bromine trifluoride is an interhalogen compound with the formula BrF3. At room temperature, it is a straw-coloured liquid with a pungent odor which decomposes violently on contact with water and organic compounds. It is a powerful fluorinating agent and an ionizing inorganic solvent. It is used to produce uranium hexafluoride (UF6) in the processing and reprocessing of nuclear fuel. Synthesis Bromine trifluoride was first described by Paul Lebeau in 1906, who obtained the material by the reaction of bromine with fluorine at 20 °C: : The disproportionation of bromine monofluoride also gives bromine trifluoride: : Structure Like ClF3 and IF3, the BrF3 molecule is T-shaped and planar. In the VSEPR formalism, the bromine center is assigned two electron pairs. The distance from the bromine each axial fluorine is 1.81 Å and to the equatorial fluorine is 1.72 Å. The angle between an axial fluorine and the equatorial fluorine is slightly smaller than 90° — the 86.2 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromine
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table ( halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek (bromos) meaning "stench", referring to its sharp and pungent smell. Elemental bromine is very reactive and thus does not occur as a native element in nature but it occurs in colourless soluble crystalline mineral halide salts, analogous to table salt. In fact, bromine and all the halogens are so reactive that they form bonds in pairs—never in single atoms. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its accumulation in the oceans. Comme ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium Hexafluoride
Uranium hexafluoride (), (sometimes called "hex") is an inorganic compound with the formula UF6. Uranium hexafluoride is a volatile white solid that reacts with water, releasing corrosive hydrofluoric acid. The compound reacts mildly with aluminium, forming a thin surface layer of AlF3 that resists any further reaction from the compound. UF6 is used in the process of enriching uranium, which produces fuel for nuclear reactors and nuclear weapons. Preparation Milled uranium ore—U3O8 or "yellowcake"—is dissolved in nitric acid, yielding a solution of uranyl nitrate UO2(NO3)2. Pure uranyl nitrate is obtained by solvent extraction, then treated with ammonia to produce ammonium diuranate ("ADU", (NH4)2U2O7). Reduction with hydrogen gives UO2, which is converted with hydrofluoric acid (HF) to uranium tetrafluoride, UF4. Oxidation with fluorine yields UF6. During nuclear reprocessing, uranium is reacted with chlorine trifluoride to give UF6: :U + 2 ClF3 → UF6 + Cl2 Prope ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium Tetrafluoride
Uranium tetrafluoride is the inorganic compound with the formula UF4. It is a green solid with an insignificant vapor pressure and low solubility in water. Uranium in its tetravalent ( uranous) state is important in various technological processes. In the uranium refining industry it is known as green salt. Production UF4 is prepared from UO2 in a fluidized bed by reaction with HF. The UO2 is derived from mining operations. Around 60,000 tonnes per year are prepared in this way annually. A common impurity is UO2F2. UF4 is susceptible to hydrolysis as well. UF4 is formed by the reaction of UF6 with hydrogen gas in a vertical tube-type reactor. UF4 is less stable than the uranium oxides and reacts slowly with moisture at ambient temperature, forming UO2 and HF, the latter of which is very corrosive and toxic; it is thus less favourable for long-term disposal. The bulk density of UF4 varies from about 2.0 g/cm3 to about 4.5 g/cm3 depending on the production process and the pr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorocarbon
Fluorocarbons are chemical compounds with carbon-fluorine bonds. Compounds that contain many C-F bonds often has distinctive properties, e.g., enhanced stability, volatility, and hydrophobicity. Fluorocarbons and their derivatives are commercial polymers, refrigerants, drugs, and anesthetics. Nomenclature Perfluorocarbons or PFCs, are organofluorine compounds with the formula CxFy, i.e., they contain only carbon and fluorine. The terminology is not strictly followed and many fluorine-containing organic compounds are called fluorocarbons. Compounds with the prefix perfluoro- are hydrocarbons, including those with heteroatoms, wherein all C-H bonds have been replaced by C-F bonds. Fluorocarbons includes perfluoroalkanes, fluoroalkenes, fluoroalkynes, and perfluoroaromatic compounds. Perfluoroalkanes Chemical properties Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. Its strength is a r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrocarbons
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or exemplified by the odors of gasoline and lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene). In the fossil fuel industries, ''hydrocarbon'' refers to the naturally occurring petroleum, natural gas and coal, and to their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are ca ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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