Bioenergy With Carbon Capture And Storage
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Bioenergy With Carbon Capture And Storage
Bioenergy with carbon capture and storage (BECCS) is the process of extracting bioenergy from biomass and capturing and storing the carbon, thereby removing it from the atmosphere. The carbon in the biomass comes from the greenhouse gas carbon dioxide (CO2) which is extracted from the atmosphere by the biomass when it grows. Energy is extracted in useful forms (electricity, heat, biofuels, etc.) as the biomass is utilized through combustion, fermentation, pyrolysis or other conversion methods. Some of the carbon in the biomass is converted to CO2 or biochar which can then be stored by geologic sequestration or land application, respectively, enabling carbon dioxide removal (CDR) and making BECCS a negative emissions technology (NET). The potential range of negative emissions from BECCS was estimated to be zero to 22 gigatonnes per year. , five facilities around the world were actively using BECCS technologies and were capturing approximately 1.5 million tonnes per year of CO2. ...
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Bioenergy
Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms biomass and biofuel interchangeably, while others consider biofuel to be a ''liquid'' or ''gaseous'' fuel used for transportation, as defined by government authorities in the US and EU. The European Union's Joint Research Centre defines solid biofuel as raw or processed organic matter of biological origin used for energy, such as firewood, wood chips, and wood pellets. In 2019, biomass was used to produce 57 EJ (exajoules) of energy, compared to 190 EJ from crude oil, 168 EJ from coal, 144 EJ from natural gas, 30 EJ from nuclear, 15 EJ from hydropower, hydro and 13 EJ from wind power, wind, solar power, solar and geothermal energy, geothermal combined. Approximately 86% of modern bioenergy is used for heating applications, with 9% used for tra ...
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Climate Change Feedback
Climate change feedbacks are important in the understanding of global warming because feedback processes amplify or diminish the effect of each climate forcing, and so play an important part in determining the climate sensitivity and future climate state. Feedback in general is the process in which changing one quantity changes a second quantity, and the change in the second quantity in turn changes the first. Positive (or reinforcing) feedback amplifies the change in the first quantity while negative (or balancing) feedback reduces it. The term "forcing" means a change which may "push" the climate system in the direction of warming or cooling. An example of a climate forcing is increased atmospheric concentrations of greenhouse gases. By definition, forcings are external to the climate system while feedbacks are internal; in essence, feedbacks represent the internal processes of the system. Some feedbacks may act in relative isolation to the rest of the climate system; others ...
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Oxidizer
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to a substrate. Combust ...
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Oxy-fuel Combustion Process
Oxy-fuel combustion is the process of burning a fuel using pure oxygen, or a mixture of oxygen and recirculated flue gas, instead of air. Since the nitrogen component of air is not heated, fuel consumption is reduced, and higher flame temperatures are possible. Historically, the primary use of oxy-fuel combustion has been in welding and cutting of metals, especially steel, since oxy-fuel allows for higher flame temperatures than can be achieved with an air-fuel flame. It has also received a lot of attention in recent decades as a potential carbon capture and storage technology. There is currently research being done in firing fossil fuel power plants with an oxygen-enriched gas mix instead of air. Almost all of the nitrogen is removed from input air, yielding a stream that is approximately 95% oxygen. Firing with pure oxygen would result in too high a flame temperature, so the mixture is diluted by mixing with recycled flue gas, or staged combustion. The recycled flue gas can also ...
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Post Combustion Capture
Post-combustion capture refers to the removal of ''CO2'' from power station flue gas prior to its compression, transportation and storage in suitable geological formations, as part of carbon capture and storage. A number of different techniques are applicable, almost all of which are adaptations of acid gas removal processes used in the chemical and petrochemical industries. Many of these techniques existed before World War II and, consequently, post-combustion capture is the most developed of the various carbon-capture methodologies. Calcium looping is a promising second generation post-combustion capture technology in which calcium oxide, often referred to as the ''sorbent'', is used to separate CO2 from the flue gas. ThANICA projectfocuses on developing a novel indirectly heated carbonate lopping process for lowering the energy penalty and CO2 avoidance costs for CO2 capture from lime and cement plants. See also * Acid gas * Carbon capture and storage Carbon capture and st ...
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Combined Cycle
A combined cycle power plant is an assembly of heat engines that work in tandem from the same source of heat, converting it into mechanical energy. On land, when used to make electricity the most common type is called a combined cycle gas turbine (CCGT) plant. The same principle is also used for marine propulsion, where it is called a combined gas and steam (COGAS) plant. Combining two or more thermodynamic cycles improves overall efficiency, which reduces fuel costs. The principle is that after completing its cycle in the first engine, the working fluid (the exhaust) is still hot enough that a second subsequent heat engine can extract energy from the heat in the exhaust. Usually the heat passes through a heat exchanger so that the two engines can use different working fluids. By generating power from multiple streams of work, the overall efficiency can be increased by 50–60%. That is, from an overall efficiency of the system of say 34% for a simple cycle, to as much as 64% ...
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Syngas
Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as a fuel. Historically, it has been used as a replacement for gasoline, when gasoline supply has been limited; for example, wood gas was used to power cars in Europe during WWII (in Germany alone half a million cars were built or rebuilt to run on wood gas). Production Syngas is produced by steam reforming or partial oxidation of natural gas or liquid hydrocarbons, or coal gasification. Steam reforming of methane is an endothermic reaction requiring 206 kJ/mol of methane: : In principle, but rarely in practice, biomass and related hydrocarbon feedstocks could be used to generate biogas and biochar in waste-to-energy gasification facilities. The gas generated (mostly methane and carbon dioxide) is sometimes described as ''syngas'' but its co ...
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Gasification
Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock. An advantage of gasification is that syngas can be more efficient than direct combustion of the original feedstock material because it can be combusted at higher temperatures so that the thermodynamic upper li ...
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Lime Kilns
A lime kiln is a kiln used for the calcination of limestone ( calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is : CaCO3 + heat → CaO + CO2 This reaction can take place at anywhere above 840 °C (1544 °F), but is generally considered to occur at 900 °C(1655 °F) (at which temperature the partial pressure of CO2 is 1 atmosphere), but a temperature around 1000 °C (1832 °F) (at which temperature the partial pressure of CO2 is 3.8 atmospheres) is usually used to make the reaction proceed quickly.Parkes, G.D. and Mellor, J.W. (1939). ''Mellor's Modern Inorganic Chemistry'' London: Longmans, Green and Co. Excessive temperature is avoided because it produces unreactive, "dead-burned" lime. Slaked lime (calcium hydroxide) can be formed by mixing quicklime with water. Early lime use Because it is so readily made by heating limestone, lime must have been known from the earlies ...
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Recovery Boiler
Recovery boiler is the part of kraft process of pulping where chemicals for white liquor are recovered and reformed from black liquor, which contains lignin from previously processed wood. The black liquor is burned, generating heat, which is usually used in the process of making electricity, much as in a conventional steam power plant. The invention of the recovery boiler by G.H. Tomlinson in the early 1930s was a milestone in the advancement of the kraft process. Recovery boilers are also used in the (less common) sulfite process of wood pulping; this article deals only with recovery boiler use in the kraft process. Function of recovery boilers Concentrated black liquor contains organic dissolved wood residue in addition to sodium sulfate from the cooking chemicals added at the digester. Combustion of the organic portion of chemicals produces heat. In the recovery boiler, heat is used to produce high pressure steam, which is used to generate electricity in a turbine. The turb ...
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