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Bifenox
Bifenox is the ISO common name for an organic compound used as an herbicide. It acts by inhibiting the enzyme protoporphyrinogen oxidase which is necessary for chlorophyll synthesis. History The nitrophenyl ethers are a well-known class of herbicides, the oldest member of which was nitrofen, invented by Rohm & Haas and first registered for sale in 1964. This area of chemistry became very competitive, with the Mobil Oil Corporation's filing in 1969 and grant in 1974 of a patent to the structural analog with a COOCH3 group adjacent to the nitro group of nitrofen. Bifenox was launched with the brand name Mowdown in 1981. Meanwhile Rohm & Haas had patented and developed acifluorfen (as its sodium salt with brand name Blazer) in 1980. Both compounds had much improved properties including a wider spectrum of herbicidal effect and good safety to some crops, including soybean. Synthesis The preparation of bifenox first described in the Mobil patent includes as its final step an Ullma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bifenox Synthesis
Bifenox is the International Organization for Standardization, ISO trivial name, common name for an organic compound used as an herbicide. It acts by enzyme inhibitor, inhibiting the enzyme protoporphyrinogen oxidase which is necessary for chlorophyll Chlorophyllide, synthesis. History The nitrophenyl ethers are a well-known class of herbicides, the oldest member of which was nitrofen, invented by Rohm and Haas, Rohm & Haas and first registered for sale in 1964. This area of chemistry became very competitive, with the Mobil, Mobil Oil Corporation's filing in 1969 and grant in 1974 of a patent to the structural analog with a COOCH3 group adjacent to the nitro group of nitrofen. Bifenox was launched with the brand name Mowdown in 1981. Meanwhile Rohm & Haas had patented and developed acifluorfen (as its sodium salt with brand name Blazer) in 1980. Both compounds had much improved properties including a wider spectrum of herbicidal effect and good safety to some crops, including soy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acifluorfen
Acifluorfen is the ISO common name for an organic compound used as an herbicide. It acts by inhibiting the enzyme protoporphyrinogen oxidase which is necessary for chlorophyll synthesis. Soybeans naturally have a high tolerance to acifluorfen and its salts, via metabolic disposal by glutathione ''S''-transferase. It is effective against broadleaf weeds and grasses and is used agriculturally on fields growing soybeans, peanuts, peas, and rice. History The nitrophenyl ethers are a well-known class of herbicides, the oldest member of which was nitrofen, invented by Rohm & Haas and first registered for sale in 1964. This area of chemistry became very competitive, with the Mobil Oil Corporation's filing in 1969 and grant in 1974 of a patent to the structural analog with a COOCH3 group adjacent to the nitro group of nitrofen. This product, bifenox, was launched with the brand name Mowdown in 1981. Meanwhile Rohm & Haas introduced acifluorfen (as its sodium salt with brand na ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ullmann Condensation
The Ullmann condensation or Ullmann-type reaction is the copper-promoted conversion of aryl halides to aryl ethers, aryl thioethers, aryl nitriles, and aryl amines. These reactions are examples of cross-coupling reactions. Ullmann-type reactions are comparable to Buchwald–Hartwig reactions but usually require higher temperatures. Traditionally these reaction requires high-boiling polar solvents such as ''N''-methylpyrrolidone, nitrobenzene, or dimethylformamide and high temperatures (often in excess of 210 °C) with stoichiometric amounts of copper. Aryl halide were required to be activated by electron-withdrawing groups. Traditional Ullmann style reactions used "activated" copper powder, e.g. prepared in situ by the reduction of copper sulfate by zinc metal in hot water. The methodology improved with the introduction of soluble copper catalysts supported by diamines and acetylacetonate ligands. Ullmann ether synthesis: C-O coupling Illustrative of the traditional Ullm ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Papaver Rhoeas
''Papaver rhoeas'', with common names including common poppy, corn poppy, corn rose, field poppy, Flanders poppy, and red poppy, is an annual herbaceous species of flowering plant in the poppy family Papaveraceae. It is a temperate native with a very wide distribution area, from Africa to temperate and tropical Asia and Europe. It is regarded as an agricultural weed (hence the common names including "corn" and "field"). As the plant thrives in areas of disturbed soil, it was often abundant in agricultural fields before the advent of herbicides. Flushes of poppies may still appear in fields where herbicides are not used, as well as those in fallow. The corn poppy and its cultivars such as the Shirley poppy are widely grown in gardens, and are frequently found in packets of seed labelled "wildflower mixes". Since World War I, it has been used in the Commonwealth as a symbol of remembrance for fallen soldiers. Description ''Papaver rhoeas'' is a variable, erect annual, fo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Myosotis Arvensis
''Myosotis arvensis'' or field forget-me-not is a herbaceous annual plant, annual to short lived perennial plant, perennial flowering plant in the family Boraginaceae. Clive Stace describes this plant as having the following characteristics: * Upright, to ; softly hairy, with hairs at more-or-less right-angles to the stem. * Flowers grey-blue, across, saucer shaped in profile; sepal tube with hooked hairs; April–October. * Mature fruit dark brown, shiny. * Mature calyx (botany), calyx on spreading stalks longer than sepal tube; calyx (botany), calyx teeth conceal the ripe fruit. * Basal leaves stalked, in a rosette; upper leaves not stalked. * Generally found on open, well drained ground; common throughout the British Isles. Gallery File:Myosotis arvensis, general view.jpg, General view File:Myosotis arvensis, flower head 3.jpg, Flower head File:Myosotis arvensis, flower.jpg, Close up of flower; the background squares are 5mm across File:Myosotis arvensis, flower from side 1 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lamium Purpureum
''Lamium purpureum'', known as red dead-nettle, purple dead-nettle, or purple archangel, is an annual herbaceous flowering plant native to Europe and Asia. Varieties: * ''Lamium purpureum'' var. ''hybridum'' (Vill.) Vill. (synonym: ''Lamium hybridum'' Vill.) Description ''Lamium purpureum'' grows with square stems to 5–20 cm Parnell, J. and Curtis, T. 2012. ''Webb's An Irish Flora.'' Cork University Press. (rarely 30 cm) in height. The leaf, leaves have fine hairs, are green at the bottom and shade to purplish at the top; they are 2–4 cm long and broad, with a 1–2 cm petiole (leaf stalk), and wavy to serrated margins. The Floral symmetry, zygomorphic flowers are bright red-purple, with a top hood-like petal, two lower lip petal lobes and minute fang-like lobes between. The Petal, corolla shows a line of hairs near the base of the tube. They may be produced throughout the year, including mild weather in winter. This allows bees to gather its nectar for f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Galium Aparine
''Galium aparine'', with common names including cleavers, clivers, catchweed and sticky willy among others, is an annual, herbaceous plant of the family Rubiaceae. Names ''Galium aparine'' is known by a variety of common names in English. They include ''hitchhikers'', ''cleavers'', ''clivers'', ''bedstraw'', ''(small) goosegrass'' (not to be confused with other plants known as ''goosegrass''), ''catchweed'', ''stickyweed'', ''sticky bob'', ''stickybud'', ''stickyback'', ''sticky molly'', ''robin-run-the-hedge'', ''sticky willy'', ''sticky willow'', ''stickyjack'', ''stickeljack'', ''grip grass, sticky grass, bobby buttons, whippysticks'', and ''velcro plant''. ''Galium'' is Dioscorides’ name for the plant. It is derived from the Greek word for ‘milk’, because the flowers of '' Galium verum'' were used to curdle milk in cheese making.Gledhill, David (2008). "The Names of Plants". Cambridge University Press. (hardback), (paperback). pp 52, 174 ''Aparine'' is a name used b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Capsella Bursa-pastoris
''Capsella bursa-pastoris'', known as shepherd's purse because of its triangular flat fruits, which are purse-like, is a small annual and ruderal flowering plant in the mustard family (Brassicaceae). It is native to eastern Europe and Asia minor, but is naturalized and considered a common weed in many parts of the world, especially in colder climates, including British Isles, where it is regarded as an archaeophyte,Preston CD, Pearman DA & Dines TD (2002) New Atlas of the British Flora. Oxford University Press North America and China, but also in the Mediterranean and North Africa. ''C. bursa-pastoris'' is the second-most prolific wild plant in the world, and is common on cultivated ground and waysides and meadows. Scientists have referred to this species as a 'protocarnivore', since it has been found that its seeds attract and kill nematodes as a means to locally enrich the soil. History Pictured and published in 1486. Description ''Capsella bursa-pastoris'' plants grow from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pesticide Formulation
The biological activity of a pesticide, be it chemical or biological in nature, is determined by its active ingredient (AI - also called the ''active substance''). Pesticide products very rarely consist of pure technical material. The AI is usually formulated with other materials and this is the product as sold, but it may be further diluted in use. Formulations improves the properties of a chemical for handling, storage, application and may substantially influence effectiveness and safety. Formulation terminology follows a 2-letter convention: (''e.g.'' GR: granules) listed by CropLife International (formerly GIFAP then GCPF) in the ''Catalogue of Pesticide Formulation Types'' (Monograph 2); see download page Some manufacturers do not follow these industry standards, which can cause confusion for users. Water-miscible formulations By far the most frequently used products are formulations for mixing with water then applying as sprays. Water miscible, older formulations include: * ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
European Food Safety Authority
The European Food Safety Authority (EFSA) is the agency of the European Union (EU) that provides independent scientific advice and communicates on existing and emerging risks associated with the food chain. EFSA was established in February 2002, is based in Parma, Italy, and for 2021 it has a budget of €118.6 million, and a total staff of 542. The work of EFSA covers all matters with a direct or indirect impact on food and feed safety, including animal health and welfare, plant protection and plant health and nutrition. EFSA supports the European Commission, the European Parliament and EU member states in taking effective and timely risk management decisions that ensure the protection of the health of European consumers and the safety of the food and feed chain. EFSA also communicates to the public in an open and transparent way on all matters within its remit. Structure Based on a regulation of 2002, the EFSA is composed of four bodies: * Management Board * Executive Dir ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Regulation Of Pesticides In The European Union
A pesticide, also called Plant Protection Product (PPP), which is a term used in regulatory documents, consists of several different components. The active ingredient in a pesticide is called “active substance” and these active substances either consist of chemicals or micro-organisms. The aims of these active substances are to specifically take action against organisms that are harmful to plants (Art. 2(2), Regulation (EC) No 1107/2009). In other words, active substances are the active components against pests and plant diseases. In the Regulation (EC) No 1107/2009, a pesticide is defined based on how it is used. Thus, pesticides have to fulfill certain criteria in order to be called pesticides. Among others, the criteria include that they either protect plants against harmful organisms - by killing or in other ways preventing the organism from performing harm, that they enhance the natural ability of plants to defend themselves against these harmful organisms, or that they kil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lipid Peroxidation
Lipid peroxidation is the chain of reactions of oxidative degradation of lipids. It is the process in which radical (chemistry), free radicals "steal" electrons from the lipids in cell membranes, resulting in cell damage. This process proceeds by a free radical chain reaction#Chemical chain reactions, chain reaction mechanism. It most often affects polyunsaturated fatty acids, because they contain multiple double bonds in between which lie methylene bridges (-CH2-) that possess especially reactive hydrogen atoms. As with any radical reaction, the reaction consists of three major steps: initiation, propagation, and termination. The chemical products of this oxidation are known as lipid peroxides or lipid oxidation products (LOPs). Initiation Initiation is the step in which a fatty acid radical (chemistry), radical is produced. The most notable initiators in living cells are reactive oxygen species (ROS), such as hydroxyl radical, OH· and hydroperoxyl, HOO·, which combines wi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
