Beryllium Nitrate
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Beryllium Nitrate
Beryllium nitrate is an inorganic compound with the idealized chemical formula Be(NO3)2. The formula suggests a salt, but, as for many beryllium compounds, the compound is highly covalent. Little of its chemistry is well known. "When added to water, brown fumes are evolved; when hydrolyzed in sodium hydroxide solution, both nitrate and nitrite ions are produced." Synthesis and reactions The straw-colored adduct Be(NO3)2(N2O4) forms upon treatment of beryllium chloride with dinitrogen tetroxide: :BeCl2 + 3N2O4 → Be(NO3)2(N2O4) + 2NOCl Upon heating, this adduct loses N2O4 and produces colorless Be(NO3)2. Further heating of Be(NO3)2 induces conversion to basic beryllium nitrate, which adopts a structure akin to that for basic berylium acetate Basic beryllium acetate is the chemical compound with the formula Be4O(O2CCH3)6. This Chemical compound, compound adopts a distinctive structure, but it has no applications and has been only lightly studied. It is a colourless s ...
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Magnesium Nitrate
Magnesium nitrate refers to inorganic compounds with the formula Mg(NO3)2(H2O)x, where x = 6, 2, and 0. All are white solids. The anhydrous material is hygroscopic, quickly forming the hexahydrate upon standing in air. All of the salts are very soluble in both water and ethanol. Occurrence, preparation, structure Being highly water soluble, magnesium nitrate occurs naturally only in mines and caverns as ''nitromagnesite'' (hexahydrate form).Mindat, http://www.mindat.org/min-2920.html The magnesium nitrate used in commerce is made by the reaction of nitric acid and various magnesium salts. Use The principal use is as a dehydrating agent in the preparation of concentrated nitric acid. Its fertilizer grade has 10.5% nitrogen and 9.4% magnesium, so it is listed as 10.5-0-0 + 9.4% Mg. Fertilizer blends containing magnesium nitrate also have ammonium nitrate, calcium nitrate, potassium nitrate and micronutrients in most cases; these blends are used in the greenhouse and hydro ...
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Calcium Nitrate
Calcium nitrate, also called ''Norgessalpeter'' (Norwegian salpeter), is an inorganic compound with the formula Ca(NO3)2(H2O)x. The anhydrous compound, which is rarely encountered, absorbs moisture from the air to give the tetrahydrate. Both anhydrous and hydrated forms are colourless salts. Calcium nitrate is mainly used as a component in fertilizers, but it has other applications. Nitrocalcite is the name for a mineral which is a hydrated calcium nitrate that forms as an efflorescence where manure contacts concrete or limestone in a dry environment as in stables or caverns. A variety of related salts are known including calcium ammonium nitrate decahydrate and calcium potassium nitrate decahydrate. Production and reactivity Norgessalpeter was synthesized at Notodden, Norway in 1905 by the Birkeland–Eyde process. Most of the world's calcium nitrate is now made in Porsgrunn. It is produced by treating limestone with nitric acid, followed by neutralization with ammonia: :CaCO3 + ...
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Strontium Nitrate
Strontium nitrate is an inorganic compound composed of the elements strontium, nitrogen and oxygen with the formula Sr( NO3)2. This colorless solid is used as a red colorant and oxidizer in pyrotechnics. Preparation Strontium nitrate is typically generated by the reaction of nitric acid on strontium carbonate. : 2 HNO3 + SrCO3 → Sr(NO3)2 + H2O + CO2 Uses Like many other strontium salts, strontium nitrate is used to produce a rich red flame in fireworks and road flares. The oxidizing properties of this salt are advantageous in such applications.MacMillan, J. Paul; Park, Jai Won; Gerstenberg, Rolf; Wagner, Heinz; Köhler, Karl and Wallbrecht, Peter (2002) "Strontium and Strontium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, Weinheim. Strontium nitrate can aid in eliminating and lessening skin irritations. When mixed with glycolic acid, strontium nitrate reduces the sensation of skin irritation significantly better than using glycolic ac ...
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Barium Nitrate
Barium nitrate is the inorganic compound with the chemical formula Ba( NO3)2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics. Manufacture, occurrence, and reactions Barium nitrate is manufactured by two processes that start with the main source material for barium, the carbonate. The first involves dissolving barium carbonate in nitric acid, allowing any iron impurities to precipitate, then filtered, evaporated, and crystallized. The second requires combining barium sulfide with nitric acid. It occurs naturally as the very rare mineral nitrobarite. At elevated temperatures, barium nitrate decomposes to barium oxide: : 2Ba(NO3)2 → 2BaO + 4NO2 + O2 Applications Barium nitrate is used in the production of BaO-containing materials. Military Although no longer produced, Baratol is an explosive composed of barium nitrate, TNT and binder; the high density of barium ni ...
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Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ...
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Chemical Formula
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include Subscript and superscript, subscripts and superscripts. A chemical formula is not a chemical nomenclature, chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called ''empirical formulae'', which use letters and numbers ind ...
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Dinitrogen Tetroxide
Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide (NTO), and occasionally (usually among ex-USSR/Russia rocket engineers) as amyl, is the chemical compound N2O4. It is a useful reagent in chemical synthesis. It forms an equilibrium mixture with nitrogen dioxide. Its molar mass is 92.011 g/mol. Dinitrogen tetroxide is a powerful oxidizer that is hypergolic (spontaneously reacts) upon contact with various forms of hydrazine, which has made the pair a common bipropellant for rockets. Structure and properties Dinitrogen tetroxide could be regarded as two nitro groups (-NO2) bonded together. It forms an equilibrium mixture with nitrogen dioxide. The molecule is planar with an N-N bond distance of 1.78Å and N-O distances of 1.19Å. The N-N distance corresponds to a weak bond, since it is significantly longer than the average N-N single bond length of 1.45Å. This exceptionally weak σ bond (amounting to overlapping of the ''sp''2 hybrid orbitals of the two NO2 units) ...
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Basic Berylium Acetate
Basic beryllium acetate is the chemical compound with the formula Be4O(O2CCH3)6. This compound adopts a distinctive structure, but it has no applications and has been only lightly studied. It is a colourless solid that is soluble in organic solvents. Preparation It can be prepared by treating basic beryllium carbonate with hot acetic acid. : 2 + 6 AcOH → + 5 + 2 Basic beryllium acetate is insoluble in water but soluble in chloroform, consistent with it being nonpolar. It melts and sublimes in a vacuum without decomposition. Structure "Basic acetates" consist of an ensemble of metal centres bound to a central oxide ion, and a collection of acetate ligands. Basic beryllium acetate has a tetrahedral Be4O6+ core with acetates (CH3CO2−) spanning each of the pairs of Be2+ centres. It consists of interlocking six-membered Be2O3C rings. The structure is relevant to its considerable stability (the compound is distillable at 330 °C). Uses The solubility of the salt ...
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Beryllium Compounds
Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form minerals. Notable gemstones high in beryllium include beryl ( aquamarine, emerald) and chrysoberyl. It is a relatively rare element in the universe, usually occurring as a product of the spallation of larger atomic nuclei that have collided with cosmic rays. Within the cores of stars, beryllium is depleted as it is fused into heavier elements. Beryllium constitutes about 0.0004 percent by mass of Earth's crust. The world's annual beryllium production of 220 tons is usually manufactured by extraction from the mineral beryl, a difficult process because beryllium bonds strongly to oxygen. In structural applications, the combination of high flexural rigidity, thermal stability, thermal conductivity and low density (1.85 times that of water) ...
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