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Bio-oil
Pyrolysis oil, sometimes also known as bio-crude or bio-oil, is a synthetic fuel under investigation as substitute for petroleum. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about with subsequent cooling. Pyrolysis oil is a kind of tar and normally contains levels of oxygen too high to be considered a pure hydrocarbon. This high oxygen content results in non-volatility, corrosiveness, immiscibility with fossil fuels, thermal instability, and a tendency to polymerize when exposed to air. As such, it is distinctly different from petroleum products. Removing oxygen from bio-oil or nitrogen from algal bio-oil is known as upgrading. Standards There are few standards for pyrolysis oil because of limited efforts to produce it. One of the few standards is from ASTM. Feedstock decomposition Pyrolysis is a well established technique for decomposition of organic material at elevated temperatures in the absence of oxygen into oil and other c ...
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Bio-oil
Pyrolysis oil, sometimes also known as bio-crude or bio-oil, is a synthetic fuel under investigation as substitute for petroleum. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about with subsequent cooling. Pyrolysis oil is a kind of tar and normally contains levels of oxygen too high to be considered a pure hydrocarbon. This high oxygen content results in non-volatility, corrosiveness, immiscibility with fossil fuels, thermal instability, and a tendency to polymerize when exposed to air. As such, it is distinctly different from petroleum products. Removing oxygen from bio-oil or nitrogen from algal bio-oil is known as upgrading. Standards There are few standards for pyrolysis oil because of limited efforts to produce it. One of the few standards is from ASTM. Feedstock decomposition Pyrolysis is a well established technique for decomposition of organic material at elevated temperatures in the absence of oxygen into oil and other c ...
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Hydrothermal Liquefaction
Hydrothermal liquefaction (HTL) is a thermal depolymerization process used to convert wet biomass, and other macromolecules, into crude-like oil under moderate temperature and high pressure. The crude-like oil has high energy density with a lower heating value of 33.8-36.9 MJ/kg and 5-20 wt% oxygen and renewable chemicals. The process has also been called hydrous pyrolysis. The reaction usually involves homogeneous and/or heterogeneous catalysts to improve the quality of products and yields. Carbon and hydrogen of an organic material, such as biomass, peat or low-ranked coals (lignite) are thermo-chemically converted into hydrophobic compounds with low viscosity and high solubility. Depending on the processing conditions, the fuel can be used as produced for heavy engines, including marine and rail or upgraded to transportation fuels, such as diesel, gasoline or jet-fuels. The process may be a significant in the creation of fossil fuels. Simple heating without water, anhydrous pyro ...
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Biochar
Biochar is the lightweight black residue, made of carbon and Ash (analytical chemistry), ashes, remaining after the pyrolysis of biomass. Biochar is defined by the International Biochar Initiative as "the solid material obtained from the thermochemical conversion of biomass in an reducing atmosphere, oxygen-limited environment". Biochar is a stable solid that is rich in Pyrolysis, pyrogenic carbon and can endure in soil for thousands of years. The refractory stability of biochar leads to the concept of pyrogenic carbon capture and storage (PyCCS), i.e. carbon sequestration in the form of biochar. It may be a means to Climate change mitigation, mitigate climate change. Biochar may increase the soil fertility of acidic soils and increase agricultural productivity. History The word "biochar" is a late 20th century English neologism derived from the Greek Language, Greek word , ''bios'', "life" and "Char (chemistry), char" (charcoal produced by carbonisation of biomass). It ...
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Synthetic Fuel
Synthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by reforming of natural gas. Common ways for refining synthetic fuels include the Fischer–Tropsch conversion, methanol to gasoline conversion, or direct coal liquefaction. Classification and principles The term 'synthetic fuel' or 'synfuel' has several different meanings and it may include different types of fuels. More traditional definitions define 'synthetic fuel' or 'synfuel' as any liquid fuel obtained from coal or natural gas. In its Annual Energy Outlook 2006, the Energy Information Administration defines synthetic fuels as fuels produced from coal, natural gas, or biomass feedstocks through chemical conversion into synthetic crude and/or synthetic liquid products. A number of synthetic fuel's definitions include fuels produced from bi ...
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Biomass
Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms biomass and biofuel interchangeably, while others consider biofuel to be a ''liquid'' or ''gaseous'' fuel used for transportation, as defined by government authorities in the US and EU. The European Union's Joint Research Centre defines solid biofuel as raw or processed organic matter of biological origin used for energy, such as firewood, wood chips, and wood pellets. In 2019, biomass was used to produce 57 EJ (exajoules) of energy, compared to 190 EJ from crude oil, 168 EJ from coal, 144 EJ from natural gas, 30 EJ from nuclear, 15 EJ from hydro and 13 EJ from wind, solar and geothermal combined. Approximately 86% of modern bioenergy is used for heating applications, with 9% used for transport and 5% for electricity. Most of the global b ...
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Pyrolysis
The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''pyro'' "fire", "heat", "fever" and '' lysis'' "separating". Pyrolysis is most commonly used in the treatment of organic materials. It is one of the processes involved in charring wood.''Burning of wood''
, InnoFireWood's website. Accessed on 2010-02-06.
In general, pyrolysis of organic substances produces volatile products and leaves , a carbon-rich solid residue. Extreme pyrolysis, which leaves mostly

Second-generation Biofuels
Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel. First-generation biofuels are made from sugar-starch feedstocks (e.g., sugarcane and corn) and edible oil feedstocks (e.g., rapeseed and soybean oil), which are generally converted into bioethanol and biodiesel, respectively. Second-generation biofuels are made from different feedstocks and therefore may require different technology to extract useful energy from them. Second generation feedstocks include lignocellulosic biomass or woody crops, agricultural residues or waste, as well as dedicated non-food energy crops grown on marginal land unsuitable for food production. The term second-generation biofuels is used loosely to describe both the 'advanced' technology used to process feedstocks into biofuel, but also the use of non-food crops, biomass ...
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Pyrolysis
The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''pyro'' "fire", "heat", "fever" and '' lysis'' "separating". Pyrolysis is most commonly used in the treatment of organic materials. It is one of the processes involved in charring wood.''Burning of wood''
, InnoFireWood's website. Accessed on 2010-02-06.
In general, pyrolysis of organic substances produces volatile products and leaves , a carbon-rich solid residue. Extreme pyrolysis, which leaves mostly

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Coal-oil
Coal oil is a shale oil obtained from the destructive distillation of cannel coal, mineral wax, or bituminous shale, once used widely for illumination. Chemically similar to the more refined, petroleum-derived kerosene, it consists mainly of several hydrocarbons of the alkane series, with 10 to 16 carbon atoms in each molecule, with a boiling point of 175 °C to 325 °C (347 °F to 617 °F), higher than gasoline or the petroleum ethers, and lower than the oils. Because kerosene was first derived from cannel coal, classified as terrestrial type of oil shale, it continued to be popularly referred to as "coal oil" even after production shifted to petroleum as a feedstock. Refined hydrocarbons of the alkane series with 10 to 16 carbon atoms are the same thing whether taken from coal or petroleum. History The term was in use by the late 18th century for oil produced as a by-product of the production of coal gas and coal tar. In the early 19th century, it was di ...
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Heat Of Combustion
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions. The chemical reaction is typically a hydrocarbon or other organic molecule reacting with oxygen to form carbon dioxide and water and release heat. It may be expressed with the quantities: * energy/mole of fuel * energy/mass of fuel * energy/volume of the fuel There are two kinds of enthalpy of combustion, called high(er) and low(er) heat(ing) value, depending on how much the products are allowed to cool and whether compounds like are allowed to condense. The high heat values are conventionally measured with a bomb calorimeter. Low heat values are calculated from high heat value test data. They may also be calculated as the difference betw ...
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Thermal Depolymerization
Thermal depolymerization (TDP) is the process of converting a polymer into a monomer or a mixture of monomers, by predominantly thermal means. It may be catalysed or un-catalysed and is distinct from other forms of depolymerisation which may rely on the use of chemicals or biological action. This process is associated with an increase in entropy. For most polymers thermal depolymerisation is chaotic process, giving a mixture of volatile compounds. Materials may be depolymerised in this way during waste management, with the volatile components produced being burnt as a form of synthetic fuel in a waste-to-energy process. For other polymers thermal depolymerisation is an ordered process giving a single product, or limited range of products, these transformations are usually more valuable and form the basis of some plastic recycling technologies. Disordered depolymerisation For most polymeric materials thermal depolymerisation proceeds in a disordered manner, with random chain scissi ...
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Coal-tar
Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasis and seborrheic dermatitis (dandruff). It may be used in combination with ultraviolet light therapy. Industrially it is a railroad tie preservative and used in the surfacing of roads. Coal tar was listed as a known human carcinogen in the first Report on Carcinogens from the U.S. Federal Government. Coal tar was discovered circa 1665 and used for medical purposes as early as the 1800s. Circa 1850, the discovery that it could be used as the main ingredient in synthetic dyes engendered an entire industry. It is on the World Health Organization's List of Essential Medicines. Coal tar is available as a generic medication and over the counter. Side effects include skin irritation, sun sensitivity, allergic reactions, and skin discoloration. ...
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