Aluminium Oxide Hydroxide
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Aluminium Oxide Hydroxide
Aluminium hydroxide oxide or aluminium oxyhydroxide, AlO(OH) is found as one of two well defined crystalline phases, which are also known as the minerals boehmite and diaspore. The minerals are important constituents of the aluminium ore, bauxite. List of related compounds and minerals The aluminium oxides, oxide hydroxides, and hydroxides can be summarized as follows: * aluminium oxides ** corundum (Al2O3) * aluminium oxide hydroxides ** diaspore (α-AlO(OH)) ** boehmite or böhmite (γ-AlO(OH)) ** akdalaite (5Al2O3·H2O) (once believed to be 4Al2O3·H2O), also called tohdite * aluminium hydroxides ** gibbsite (often designated as γ-Al(OH)3, but sometimes as α-Al(OH)3,N.N. Greenwood and A. Earnshaw, "Chemistry of Elements", 2nd edition, Butterworth and Heinemann, 1997. sometimes called hydrargillite or hydrargyllite) ** bayerite (designated often as α-Al(OH)3 but sometimes as β-Al(OH)3) ** doyleite Doyleite is a rare aluminum trihydroxide mineral named in honor of its di ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into distinct ...
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Boehmite
Boehmite or böhmite is an aluminium oxide hydroxide (γ-AlO(OH)) mineral, a component of the aluminium ore bauxite. It is dimorphous with diaspore. It crystallizes in the orthorhombic dipyramidal system and is typically massive in habit. It is white with tints of yellow, green, brown or red due to impurities. It has a vitreous to pearly luster, a Mohs hardness of 3 to 3.5 and a specific gravity of 3.00 to 3.07. It is colorless in thin section, optically biaxial positive with refractive indices of nα = 1.644 - 1.648, nβ = 1.654 - 1.657 and nγ = 1.661 - 1.668. Boehmite occurs in tropical laterites and bauxites developed on alumino-silicate bedrock. It also occurs as a hydrothermal alteration product of corundum and nepheline. It occurs with kaolinite, gibbsite and diaspore in bauxite deposits; and with nepheline, gibbsite, diaspore, natrolite and analcime in nepheline pegmatites. Industrially, it is used as an inexpensive flame retardant additive for fire-safe polymers. ...
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Diaspore
Diaspore , also known as diasporite, empholite, kayserite, or tanatarite, is an aluminium oxide hydroxide mineral, α-AlO(OH), crystallizing in the orthorhombic system and isomorphous with goethite. It occurs sometimes as flattened crystals, but usually as lamellar or scaly masses, the flattened surface being a direction of perfect cleavage on which the lustre is markedly pearly in character. It is colorless or greyish-white, yellowish, sometimes violet in color, and varies from translucent to transparent. It may be readily distinguished from other colorless transparent minerals with a perfect cleavage and pearly luster—like mica, talc, brucite and gypsum— by its greater hardness of 6.5–7. The specific gravity is 3.4. When heated before the blowpipe it decrepitates violently, breaking up into white pearly scales. The mineral occurs as an alteration product of corundum or emery and is found in granular limestone and other crystalline rocks. Well-developed crystals ar ...
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Aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity tow ...
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Bauxite
Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) and diaspore (α-AlO(OH)), mixed with the two iron oxides goethite (FeO(OH)) and haematite (Fe2O3), the aluminium clay mineral kaolinite (Al2Si2O5(OH)4) and small amounts of anatase (TiO2) and ilmenite (FeTiO3 or FeO.TiO2). Bauxite appears dull in luster and is reddish-brown, white, or tan. In 1821, the French geologist Pierre Berthier discovered bauxite near the village of Les Baux in Provence, southern France. Formation Numerous classification schemes have been proposed for bauxite but, , there was no consensus. Vadász (1951) distinguished lateritic bauxites (silicate bauxites) from karst bauxite ores (carbonate bauxites): * The carbonate bauxites occur predominantly in Europe, Guyana, Suriname, and Jamaica above carbonate rocks (limestone and do ...
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Corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange. The name "corundum" is derived from the Tamil- Dravidian word ''kurundam'' (ruby-sapphire) (appearing in Sanskrit as ''kuruvinda''). Because of corundum's hardness (pure corundum is defined to have 9.0 on the Mohs scale), it can scratch almost all other minerals. It is commonly used as an abrasive on sandpaper and on large tools used in machining metals, plastics, and wood. Emery, a variety of corundum with no value a ...
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Akdalaite
Akdalaite ( IMA symbol: Akd) is a very rare mineral found in Kazakhstan and has the formula 5 Al2 O3· H2O. It was formerly believed to be 4 Al2 O3· H2O. It is therefore the same as tohdite an artificially produced phase. Studies on the crystal structure and spectra indicate that this is an aluminium oxide hydroxide.Ab-initio quantum mechanical study of akdalaite (5Al2O3· H2O): structure and vibrational spectrum, Demichelis, R.; Noel, Y.; Zicovich-Wilson, C. M.; Roetti, C.; Valenzano, L.; Dovesi, R., Journal of Physics: Conference Series, Volume 117, Issue 1, pp. 012013 (2008)., References External links Fact sheetfrom mindat.org Mindat.org is a non-commercial online database, claiming to be the largest mineral database and mineralogy, mineralogical reference website on the Internet. It is used by professional mineralogists, geologists, and amateur mineral collecting, mi ... Fact sheetfrowebmineral.com Oxide minerals Hydroxide minerals Aluminium minerals Hexagonal min ...
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Aluminium Hydroxide
Aluminium hydroxide, Al(OH)3, is found in nature as the mineral gibbsite (also known as hydrargillite) and its three much rarer polymorphs: bayerite, doyleite, and nordstrandite. Aluminium hydroxide is amphoteric, i.e., it has both basic and acidic properties. Closely related are aluminium oxide hydroxide, AlO(OH), and aluminium oxide or alumina (Al2O3), the latter of which is also amphoteric. These compounds together are the major components of the aluminium ore bauxite. Aluminium hydroxide also forms a gelatinous precipitate in water. Structure Al(OH)3 is built up of double layers of hydroxyl groups with aluminium ions occupying two-thirds of the octahedral holes between the two layers. Four polymorphs are recognized. All feature layers of octahedral aluminium hydroxide units, with hydrogen bonds between the layers. The polymorphs differ in terms of the stacking of the layers. All forms of Al(OH)3 crystals are hexagonal : *gibbsite is also known as γ-Al(OH)3 or α-Al(OH) ...
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Gibbsite
Gibbsite, Al(OH)3, is one of the mineral forms of aluminium hydroxide. It is often designated as γ-Al(OH)3 (but sometimes as α-Al(OH)3.). It is also sometimes called hydrargillite (or hydrargyllite). Gibbsite is an important ore of aluminium in that it is one of three main phases that make up the rock bauxite. Gibbsite has three named structural polymorphs or polytypes: bayerite (designated often as α-Al(OH)3, but sometimes as β-Al(OH)3), ''doyleite'', and nordstrandite. Gibbsite can be monoclinic or Triclinic crystal system, triclinic, while bayerite is monoclinic. Doyleite and nordstrandite are triclinic forms. Structure The structure of gibbsite is interesting and analogous to the basic structure of the micas. The basic structure forms stacked sheets of linked octahedron, octahedra. Each octahedron is composed of an aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Alum ...
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Bayerite
Gibbsite, Al(OH)3, is one of the mineral forms of aluminium hydroxide. It is often designated as γ-Al(OH)3 (but sometimes as α-Al(OH)3.). It is also sometimes called hydrargillite (or hydrargyllite). Gibbsite is an important ore of aluminium in that it is one of three main phases that make up the rock bauxite. Gibbsite has three named structural polymorphs or polytypes: bayerite (designated often as α-Al(OH)3, but sometimes as β-Al(OH)3), ''doyleite'', and nordstrandite. Gibbsite can be monoclinic or triclinic, while bayerite is monoclinic. Doyleite and nordstrandite are triclinic forms. Structure The structure of gibbsite is interesting and analogous to the basic structure of the micas. The basic structure forms stacked sheets of linked octahedra. Each octahedron is composed of an aluminium ion bonded to six hydroxide groups, and each hydroxide group is shared by two aluminium octahedra. One third of the potential octahedral spaces are missing a central aluminium. The ...
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Doyleite
Doyleite is a rare aluminum trihydroxide mineral named in honor of its discoverer, the Canadian physician Earl Joseph (Jess) Doyle. It was first definitively described in 1985 (although a partial description was published in 1979) and it is approved by the International Mineralogical Association, IMA. It was described from Mont Saint-Hilaire, where it is extremely rare. Properties Doyleite grows in small square tabular crystals, which form rosettes. Individual crystals can grow up to 8 mm. The mineral has a layered micaceous structure. This pinacoidal mineral mostly consists of oxygen (61.53%) and aluminum (34.59%), but also contains hydrogen (3.88%). Doyleite does not display any radioactive properties. At room temperature, doyleite is not soluble in a 1:1 ratio of sulfuric acid, hydrogen chloride, and nitric acid. Crystals are tabular on (010), which show forms of , , and . Occasionally, however, it shows forms of and . Some specimens are coated with a thin film of dark ...
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