Alkaline Igneous Rocks
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Alkaline Igneous Rocks
The alkaline magma series is a chemically distinct range of magma compositions that describes the evolution of an alkaline mafic magma into a more evolved, silica-rich end member. Geochemical characterization Rocks in the alkaline magma series are distinguished from rocks in the subalkaline tholeiitic and calc-alkaline magma series by their high content of alkali metal oxides (K2O plus Na2O) relative to silica (SiO2). They are distinct from the rare peralkaline magmas, which have excess alkali oxides relative to alumina (Na2O + K2O > Al2O3). Alkaline magmas tend to show high titanium oxide (TiO2) content, typically in excess of 3% by weight. Other incompatible elements, such as phosphorus and light rare earth elements, are also elevated. This is attributed to a very low degree of partial melting of the source rock, with only 5% or less of the source rock going into the magma melt. Petrography All alkaline series magmas are thought to have evolved from a primitive ...
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Magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles. Magma is produced by melting of the mantle or the crust in various tectonic settings, which on Earth include subduction zones, continental rift zones, mid-ocean ridges and hotspots. Mantle and crustal melts migrate upwards through the crust where they are thought to be stored in magma chambers or trans-crustal crystal-rich mush zones. During magma's storage in the crust, its composition may be modified by fractional crystallization, contamination with crustal melts, magma mixing, and degassing. Following its ascent through the crust, magma may feed a volcano and be extruded as lava, or it may solidify underground to form an intrusion, such as a ...
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Basanite
Basanite () is an igneous, volcanic (extrusive) rock with aphanitic to porphyritic texture. It is composed mostly of feldspathoids, pyroxenes, olivine, and plagioclase and forms from magma low in silica and enriched in alkali metal oxides that solidifies rapidly close to the Earth's surface. Description Basanite is an aphanitic (fine-grained) igneous rock that is low in silica and enriched in alkali metals. Of its total content of quartz, feldspar, and feldspathoid ( QAPF), between 10% and 60% by volume is feldspathoid and over 90% of the feldspar is plagioclase. Quartz is never present. This places basanite in the basanite/tephrite field of the QAPF diagram. Basanite is further distinguished from tephrite by having a normative olivine content greater than 10%. While the IUGS recommends classification by mineral content whenever possible, volcanic rock can be glassy or so fine-grained that this is impractical, and then the rock is classified chemically using the TAS classifica ...
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Leucitite
Leucitite or leucite rock is an igneous rock containing leucite. It is scarce, many countries such as England being entirely without them. However, they are of wide distribution, occurring in every quarter of the globe. Taken collectively, they exhibit a considerable variety of types and are of great interest petrographically. For the presence of this mineral it is necessary that the silica percentage of the rock should be low, since leucite is incompatible with free quartz and reacts with it to form potassium feldspar. Because it weathers rapidly, leucite is most common in lavas of recent and Tertiary age, which have a fair amount of potassium, or at any rate have potassium equal to or greater than sodium; if sodium is abundant nepheline occurs rather than leucite. In pre-Tertiary rocks leucite readily decomposes and changes to zeolites, analcite and other secondary minerals. Leucite also is rare in plutonic rocks and dike rocks, but leucite syenite and leucite tinguaite bear witnes ...
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Analcite
Analcime (; ) or analcite is a white, gray, or colorless tectosilicate mineral. Analcime consists of hydrated sodium aluminium silicate in cubic crystalline form. Its chemical formula is Na Al Si2 O6· H2O. Minor amounts of potassium and calcium substitute for sodium. A silver-bearing synthetic variety also exists (Ag-analcite). Analcime is usually classified as a zeolite mineral, but structurally and chemically it is more similar to the feldspathoids. Analcime occurs as a primary mineral in analcime basalt and other alkaline igneous rocks. It also occurs as cavity and vesicle fillings associated with prehnite, calcite, and zeolites. Locations Well known locations for sourcing analcime include Croft Quarry in Leicestershire, UK; the Cyclopean Islands east off Sicily and near Trentino in northern Italy; Victoria in Australia; Kerguelen Island in the Indian Ocean; in the Lake Superior copper district of Michigan, Bergen Hill, New Jersey, Golden, Colorado, and at Searles Lake, C ...
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Melilite
Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is ( Ca, Na)2( Al, Mg, Fe2+) SiOxygen.html" ;"title="Silicon">Si)Silicon.html" ;"title="Silicon.html" ;"title=" Al,Silicon">Si)Silicon">SiOxygen">O7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series. Minerals of the melilite group are sorosilicates. They have the same basic structure, of general formula ''A''2''B(T''2O7). The melilite structure consist of pairs of fused ''T''O4, where ''T'' may be Si, Al, B, in bow-tie form. Sharing one corner, the formula of the pair is ''T''2O7. These bow-ties a ...
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Nephelinite
Nephelinite is a fine-grained or aphanitic igneous rock made up almost entirely of nepheline and clinopyroxene (variety augite). If olivine is present, the rock may be classified as an olivine nephelinite. Nephelinite is dark in color and may resemble basalt in hand specimen. However, basalt consists mostly of clinopyroxene (augite) and calcic plagioclase. Basalt, alkali basalt, basanite, tephritic nephelinite, and nephelinite differ partly in the relative proportions of plagioclase and nepheline. Alkali basalt may contain minor nepheline and does contain nepheline in its CIPW normative mineralogy. A critical ratio in the classification of these rocks is the ratio nepheline/(nepheline plus plagioclase). Basanite has a value of this ratio between 0.1 and 0.6 and also contains more than 10% olivine. Tephritic nephelinite has a value between 0.6 and 0.9. Nephelinite has a value greater than 0.9. Le Maitre (2002) defines and discusses these and other criteria in the classification of i ...
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Tristanite
Latite is an igneous, volcanic rock, with aphanitic- aphyric to aphyric-porphyritic texture. Its mineral assemblage is usually alkali feldspar and plagioclase in approximately equal amounts. Quartz is less than five percent and is absent in a feldspathoid-bearing latite, and olivine is absent in a quartz-bearing latite. When quartz content is greater than five percent the rock is classified as quartz latite.Classification of Igneous Rocks
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Leucite
Leucite is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra but, as first observed by Sir David Brewster in 1821, they are not optically isotropic, and are therefore pseudo-cubic. Goniometric measurements made by Gerhard vom Rath in 1873 led him to refer the crystals to the tetragonal system. Optical investigations have since proved the crystals to be still more complex in character, and to consist of several orthorhombic or monoclinic individuals, which are optically biaxial and repeatedly twinned, giving rise to twin-lamellae and to striations on the faces. When the crystals are raised to a temperature of about 500 °C they become optically isotropic and the twin-lamellae and striations disappear, although they reappear when the crystals are cooled again. This pseudo-cubic character of leucite is very similar to that of the mineral boracit ...
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Trachybasalt
Trachybasalt is a volcanic rock with a composition between trachyte and basalt. It resembles basalt but has a high content of alkali metal oxides. Minerals in trachybasalt include alkali feldspar, calcic plagioclase, olivine, clinopyroxene and likely very small amounts of leucite or analcime. Description An aphanitic (fine-grained) igneous rock is classified as trachybasalt when it has a silica content of about 49% and a total alkali metal oxide content of about 6%. This places trachybasalt in the S1 field of the TAS classification, TAS diagram. Trachybasalt is further divided into sodium-rich ''hawaiite'' and potassium-rich ''potassic trachybasalt'', with wt% > + 2 for hawaiite. The intrusive equivalent of trachybasalt is monzonite. Trachybasalt is not defined on the QAPF diagram, which classifies crystalline igneous rock by its relative content of feldspars and quartz. However, the U.S. Geological Survey defines trachybasalt as a mafic volcanic rock (composed of over 35% maf ...
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Phonolite
Phonolite is an uncommon extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous rock trachyte that contains nepheline or leucite rather than quartz. Its intrusive equivalent is nepheline syenite. Phonolite is typically fine grained and compact. The name ''phonolite'' comes from the Ancient Greek meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name ''clinkstone'' is given as a synonym. Formation Unusually, phonolite forms from magma with a relatively low silica content, generated by low degrees of partial melting (less than 10%) of highly aluminous rocks of the lower crust such as tonalite, monzonite and metamorphic rocks. Melting of such rocks to a very low degree promotes the liberation of aluminium, potassium, sodium and calcium by melting of f ...
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Trachyte
Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and alkali metals. It is the volcanic equivalent of syenite. Trachyte is common wherever alkali magma is erupted, including in late stages of ocean island volcanismMacDonald 1983, pp. 51-52 and in continental rift valleys, above mantle plumes,Philpotts and Ague 2009, pp. 390-394 and in areas of back-arc extension. Trachyte has also been found in Gale crater on Mars. Trachyte has been used as decorative building stone and was extensively used as dimension stone in the Roman Empire and the Republic of Venice. Chemical composition Trachyte has a silica content of 60 to 65% and an alkali oxide content of over 7%. This gives it less SiO2 than rhyolite and more (Na2O plus K2O) than dacite. These chemical differences are consistent with the positio ...
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Benmoreite
Benmoreite is a silica-undersaturated volcanic rock of intermediate composition. It is a sodium-rich variety of trachyandesite and belongs to the alkalic suite of igneous rocks. Nepheline benmoreite An origin by fractionation from basanite through nepheline hawaiite to nepheline benmoreite has been demonstrated for a volcanic suite in the McMurdo Volcanic Group of late Cenozoic age in McMurdo Sound area of Antarctica. Nepheline benmoreite magmas derived from mantle sources, containing lherzolite xenoliths, display similarities to some plutonic nepheline syenite Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are al ...s. See also * References Petrology Intermediate rocks Volcanic rocks {{petrology-stub ...
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