Alite
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Alite
Alite is an impure form of tricalcium silicate, , sometimes formulated as ( in cement chemist notation), typically with 3-4% of substituent oxides. It is the major, and characteristic, phase in Portland cement. The name was given by Törnebohm in 1897 to a crystal identified in microscopic investigation of Portland cement. Hatrurite is the name of a mineral that is substituted . Composition and structure The alite found in Portland cement differs in composition from simple tricalcium silicate. It is a solid solution and contains minor amounts of other oxides besides CaO and . A typical composition is: Based on this, the formula can be expressed as . In practice, the composition varies with the bulk composition of the clinker, subject to certain limits. Substitution of calcium ions or orthosilicate ions requires that electric charges be kept in balance. For instance, a limited number of orthosilicate () ions can be replaced with sulfate () ions, provided that for each s ...
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Siliceous Limestone
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear molecule. The starkly different structures of the dioxide ...
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Amorphous Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear molecule. The starkly different structures of the dio ...
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Tricalcium Silicate
Alite is an impure form of tricalcium silicate, , sometimes formulated as ( in cement chemist notation), typically with 3-4% of substituent oxides. It is the major, and characteristic, phase in Portland cement. The name was given by Törnebohm in 1897 to a crystal identified in microscopic investigation of Portland cement. Hatrurite is the name of a mineral that is substituted . Composition and structure The alite found in Portland cement differs in composition from simple tricalcium silicate. It is a solid solution and contains minor amounts of other oxides besides CaO and . A typical composition is: Based on this, the formula can be expressed as . In practice, the composition varies with the bulk composition of the clinker, subject to certain limits. Substitution of calcium ions or orthosilicate ions requires that electric charges be kept in balance. For instance, a limited number of orthosilicate () ions can be replaced with sulfate () ions, provided that for each s ...
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Portland Cement
Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th century by Joseph Aspdin, and is usually made from limestone. It is a fine powder, produced by heating limestone and clay minerals in a kiln to form clinker, grinding the clinker, and adding 2 to 3 percent of gypsum. Several types of portland cement are available. The most common, called ordinary portland cement (OPC), is grey, but white Portland cement is also available. Its name is derived from its resemblance to Portland stone which was quarried on the Isle of Portland in Dorset, England. It was named by Joseph Aspdin who obtained a patent for it in 1824. His son William Aspdin is regarded as the inventor of "modern" portland cement due to his developments in the 1840s. The low cost and widespread availability of the limestone, sh ...
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Belite
Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation). Etymology The name was given by Törnebohm in 1897 to a crystal identified in microscopic investigation of Portland cement. Belite is a name in common use in the cement industry, but is not a recognised mineral name. It occurs naturally as the mineral larnite, the name being derived from Larne, Northern Ireland, the closest town to Scawt Hill where it was discovered. Composition and structure The belite found in Portland cement differs in composition from pure dicalcium silicate. It is a solid solution and contains minor amounts of other oxides besides CaO and SiO2. A typical composition:Taylor H.F.W. (1990), ''Cement Chemistry'', Academic Press, 1990, , pp. 10-11. Based on this, the formula can be expressed as Ca1.94Mg0.02Na0.01K0.03Fe0.02Al0.07Si0.90P0.01O3.93. In pra ...
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Clinker (cement)
200px, Typical clinker nodules 200px, Hot clinker Cement clinker is a solid material produced in the manufacture of Portland cement as an intermediary product. Clinker occurs as lumps or nodules, usually to in diameter. It is produced by sintering (fusing together without melting to the point of liquefaction) limestone and aluminosilicate materials such as clay during the cement kiln stage. Composition and preparation The Portland clinker essentially consists of four mineral phases: two calcium silicates, alite (Ca3Si) and belite (Ca2Si), along with tricalcium aluminate (Ca3Al) and calcium aluminoferrite (Ca4AlFe). These main mineral phases are produced by heating at high temperature clays and limestone. Portland cement clinker is made by heating a homogeneous mixture of raw materials in a rotary kiln at high temperature. The products of the chemical reaction aggregate together at their sintering temperature, about . Aluminium oxide and iron oxide are present only as a ...
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Belgium
Belgium, ; french: Belgique ; german: Belgien officially the Kingdom of Belgium, is a country in Northwestern Europe. The country is bordered by the Netherlands to the north, Germany to the east, Luxembourg to the southeast, France to the southwest, and the North Sea to the northwest. It covers an area of and has a population of more than 11.5 million, making it the 22nd most densely populated country in the world and the 6th most densely populated country in Europe, with a density of . Belgium is part of an area known as the Low Countries, historically a somewhat larger region than the Benelux group of states, as it also included parts of northern France. The capital and largest city is Brussels; other major cities are Antwerp, Ghent, Charleroi, Liège, Bruges, Namur, and Leuven. Belgium is a sovereign state and a federal constitutional monarchy with a parliamentary system. Its institutional organization is complex and is structured on both regional ...
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Chert
Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a chemical precipitate or a diagenetic replacement, as in petrified wood. Chert is typically composed of the petrified remains of siliceous ooze, the biogenic sediment that covers large areas of the deep ocean floor, and which contains the silicon skeletal remains of diatoms, silicoflagellates, and radiolarians. Precambrian cherts are notable for the presence of fossil cyanobacteria. In addition to microfossils, chert occasionally contains macrofossils. However, some chert is devoid of any fossils. Chert varies greatly in color (from white to black), but most often manifests as gray, brown, grayish brown and light green to rusty redW.L. Roberts, T.J. Campbell, G.R. Rapp Jr., "Encyclopedia of Mineralogy, Second Edition", 1990. R.S. M ...
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Portlandite
Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2). Occurrence Portlandite occurs in a variety of environments. At the type location in Northern Ireland it occurs as an alteration of calc–silicate rocks by contact metamorphism of larnite–spurrite. It occurs as fumarole deposits in the Vesuvius area. In Jebel Awq, Oman it occurs as precipitates from an alkaline spring emanating from ultramafic bedrock. In the Chelyabinsk coal basin of Russia it is produced by combustion of coal seams and similarly by spontaneous combustion of bitumen in the Hatrurim Formation of the Negev desert in Israel and the Maqarin area, Jordan. It also occurs in the manganese mining area of Kuruman, Cape Province, South Africa in the Kalahari Desert where it occurs as large crystals and masses. It occurs in association with afwillite, calcite, larnite, sp ...
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Sulfate
The sulfate or sulphate ion is a polyatomic ion, polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salt (chemistry), salts of sulfuric acid and many are prepared from that acid. Spelling "Sulfate" is the spelling recommended by International Union of Pure and Applied Chemistry, IUPAC, but "sulphate" was traditionally used in British English. Structure The sulfate anion consists of a central sulfur atom surrounded by four equivalent oxygen atoms in a tetrahedron, tetrahedral arrangement. The symmetry is the same as that of methane. The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. The sulfate ion carries an overall charge (physics), charge of −2 and it is the conjugate acid, conjugate base of the bisulfate (or hydrogensulfate) ion, , which is in turn the conjugate base of , sulfuric acid. Organic sulf ...
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Tournai
Tournai or Tournay ( ; ; nl, Doornik ; pcd, Tornai; wa, Tornè ; la, Tornacum) is a city and municipality of Wallonia located in the province of Hainaut, Belgium. It lies southwest of Brussels on the river Scheldt. Tournai is part of Eurometropolis Lille–Kortrijk–Tournai, which had 2,155,161 residents in 2008. Tournai is one of the oldest cities in Belgium and has played an important role in the country's cultural history. It was the first capital of the Frankish Empire, with Clovis I being born here. Geography Tournai is located in the Picardy Wallonia and Romance Flanders region of Belgium, at the southern limit of the Flemish plain, in the basin of the River Scheldt (''Escaut'' in French, ''Schelde'' in Dutch). Administratively, the town is part of the Province of Hainaut, itself part of Wallonia. It is also a municipality that is part of the French-speaking Community of Belgium. Tournai has its own arrondissements, both administrative and judicial. Its ar ...
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Tournaisian
The Tournaisian is in the ICS geologic timescale the lowest stage or oldest age of the Mississippian, the oldest subsystem of the Carboniferous. The Tournaisian age lasted from Ma to Ma. It is preceded by the Famennian (the uppermost stage of the Devonian) and is followed by the Viséan. Name and regional alternatives The Tournaisian was named after the Belgian city of Tournai. It was introduced in scientific literature by Belgian geologist André Hubert Dumont in 1832. Like many Devonian and lower Carboniferous stages, the Tournaisian is a unit from West European regional stratigraphy that is now used in the official international time scale. The Tournaisian correlates with the regional North American Kinderhookian and lower Osagean stages and the Chinese Tangbagouan regional stage. In British stratigraphy, the Tournaisian contains three substages: the Hastarian, Ivorian and lower part of the Chadian (the upper part falls in the Viséan). Stratigraphy The base of ...
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