Z-Stoff
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Z-Stoff
Z-Stoff (, "substance Z") was a name for calcium permanganate or sodium permanganate mixed in water. It was normally used as a catalyst for T-Stoff (high-test peroxide) in military rocket programs by Nazi Germany during World War II. Z-Stoff was used in the cold engine of the Messerschmitt Me 163, Messerschmitt Me 163 A airplane, in the earlier, self-contained HWK 109-500 ''Starthilfe'' RATO booster motor for manned aircraft (usually in pairs or multiples of two for such uses), and a smaller derivation of the ''Starthilfe'' unit, the Walter HWK 109-507, HWK 109-507 booster engine used with the Henschel Hs 293 anti-ship guided missile. T-Stoff decomposed by Z-Stoff was commonly used by World War II German military to generate steam for powering of fuel pumps in airplanes and rockets. The reaction produces manganese dioxide, which tends to clog the steam generators. Later generations of the Hellmuth Walter, Walter Rocket used solid-state catalyst instead of its water solution. ...
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T-Stoff
T-Stoff (; 'substance T') was a stabilised high test peroxide used in Germany during World War II. T-Stoff was specified to contain 80% (occasionally 85%) hydrogen peroxide (H2O2), remainder water, with traces (<0.1%) of stabilisers. Stabilisers used included 0.0025% , a mixture of phosphoric acid, and 8-oxyquinoline, and sodium stannate.


Uses

The decomposition of T-Stoff into hot steam and oxygen caused by the addition of the catalyst

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HWK 109-500
The Walter HWK 109-500 was a liquid-fuelled rocket engine developed by Walter in Germany during the Second World War. Description The 109-500 is a self-contained, modular monopropellant ''Starthilfe'' (take-off assist) engine in a pod, able to produce thrust for thirty seconds. After the fuel was expended, the pod was jettisoned and it returned to earth by parachute, with the parachute packed externally, onto the blunt forward end of the pod. The T-Stoff monopropellant, stored in the large spherical tank within the ''Starthilfe'' module's forward end, needed to react with a catalyst to provide the boosting thrust for an aircraft on takeoff - this Z-Stoff sodium or calcium-based, alkaline permanganate-compound (in an aqueous solution) catalyst was provided in a small tank above the reaction chamber just forward of the exhaust nozzle, with compressed air from a network of five pressure tanks driving the monopropellant and catalyst together through the reaction chamber, which ...
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Walter HWK 109-507
The HWK 109-507 was a liquid-propellant rocket engine developed by Germany during World War II. It was used to propel the Hs 293 anti-ship guided missile. It was produced by Hellmuth Walter Kommanditgesellschaft (HWK). Like other Walter engines it used hydrogen peroxide as a propellant. Missile The Hs293 has been variously described as a missile or as a boosted glide bomb. It consisted of an SC500 bomb casing, fitted with wings, engine and radio control. Control equipment was housed in a rearward extension of the bomb casing but the motor was mounted in a separate housing beneath. It had originally been developed as an unpowered glide bomb, "Gustav Schwartz Propellerwerke", and the engine was added later. After flight tests, a visible tracking flare was also added, in a further rearward extension. As the engine was mounted below the missile fuselage, the exhaust nozzle pointed downwards at 30°, so as to align the line of thrust with the centre of gravity of the missile. The ...
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List Of Stoffs
During World War II, Germany fielded many aircraft and rockets whose fuels, and oxidizers, were designated (letter)-''Stoff'' (). The following list of stoffs refers to the World War II aerospace meanings if not noted otherwise. Meaning of ''stoff'' The German word ''Stoff'' (plural ''Stoffe''), like the English word ''stuff'', derives from Old French ''estoffe'', however the meanings are somewhat different. Stoff has a fairly broad range of meanings, including "chemical substance" or "matter", "fuel" and "cloth", depending on the context. The German names of the common elements hydrogen, oxygen and nitrogen are ''Wasserstoff'', ''Sauerstoff'' and ''Stickstoff'' ("hydrogen" being a scientific Greek neologism for "constituent of water", "oxygen" for "constituent of acids", "nitrogen" for "constituent of nitre", i.e. saltpeter - although the German root ''stick-'' is derived from ''ersticken'', "to smother, suffocate", referring to its property of not supporting combustion and res ...
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Calcium Permanganate
Calcium permanganate is an oxidizing agent and chemical compound with the chemical formula Ca(MnO4)2. This salt consists of the metal calcium and two permanganate ions. Preparation The salt is prepared from the reaction of potassium permanganate with calcium chloride or from the reaction of aluminium permanganate with calcium oxide. It can also be prepared by reacting manganese dioxide with a solution of calcium hypochlorite and a little bit of calcium hydroxide to increase the pH level. Uses Calcium permanganate is used in the textile industry, for sterilization of water, and as a deodorizer. It is believed to help whiten teeth. It was formerly used as a component of rocket fuel by the Luftwaffe. Safety It is noncombustible, but being a strong oxidizing agent, it will accelerate the burning of combustible material. If the combustible material is finely divided, the resulting mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignit ...
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Messerschmitt Me 163
The Messerschmitt Me 163 Komet is a rocket-powered interceptor aircraft primarily designed and produced by the German aircraft manufacturer Messerschmitt. It is the only operational rocket-powered fighter aircraft in history as well as the first piloted aircraft of any type to exceed in level flight. Development of what would become the Me 163 can be traced back to 1937 and the work of the German aeronautical engineer Alexander Lippisch and the ''Deutsche Forschungsanstalt für Segelflug'' (DFS). Initially an experimental programme that drew upon traditional glider designs while integrating various new innovations such as the rocket engine, the development ran into organisational issues until Lippisch and his team were transferred to Messerschmitt in January 1939. Plans for a propeller-powered intermediary aircraft were quickly dropped in favour of proceeding directly to rocket propulsion. On 1 September 1941, the prototype performed its maiden flight, where upon quickly ...
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Sodium Permanganate
Sodium permanganate is the inorganic compound with the formula Na MnO4. It is closely related to the more commonly encountered potassium permanganate, but it is generally less desirable, because it is more expensive to produce. It is mainly available as the monohydrate. This salt absorbs water from the atmosphere and has a low melting point. Being about 15 times more soluble than KMnO4, sodium permanganate finds some applications where very high concentrations of MnO4− are sought. Preparation and properties Sodium permanganate cannot be prepared analogously to the route to KMnO4 because the required intermediate manganate salt, Na2MnO4, does not form. Thus less direct routes are used including conversion from KMnO4.Arno H. Reidies "Manganese Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. Sodium permanganate behaves similarly to potassium permanganate. It dissolves readily in water to give deep purple solutions, evaporation of whi ...
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Catalyst
Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst. Catalysis may be classified as either homogeneous, whose components are dispersed in the same phase (usually gaseous or liquid) as the reactant, or heterogeneous, whose components are not in the same phase. Enzymes and other biocatalysts are often considered as a third category. Catalysis is ubiquitous in chemical industry of all kinds. Estimates are that 90% of all commercially produced chemical products involve catalysts at some s ...
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High-test Peroxide
High-test peroxide (HTP) is a highly concentrated (85 to 98%) solution of hydrogen peroxide, with the remainder consisting predominantly of water. In contact with a catalyst, it decomposes into a high-temperature mixture of steam and oxygen, with no remaining liquid water. It was used as a propellant of HTP rockets and torpedoes, and has been used for high-performance vernier engines. Properties Hydrogen peroxide works best as a propellant in extremely high concentrations (roughly over 70%). Although any concentration of peroxide will generate some hot gas (oxygen plus some steam), at concentrations above approximately 67%, the heat of decomposing hydrogen peroxide becomes large enough to completely vaporize all the liquid at standard pressure. This represents a safety and utilization turning point, since decomposition of any concentration above this amount is capable of transforming the liquid entirely to heated gas (the higher the concentration, the hotter the resulting gas). Thi ...
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Rocket
A rocket (from it, rocchetto, , bobbin/spool) is a vehicle that uses jet propulsion to accelerate without using the surrounding air. A rocket engine produces thrust by reaction to exhaust expelled at high speed. Rocket engines work entirely from propellant carried within the vehicle; therefore a rocket can fly in the vacuum of space. Rockets work more efficiently in a vacuum and incur a loss of thrust due to the opposing pressure of the atmosphere. Multistage rockets are capable of attaining escape velocity from Earth and therefore can achieve unlimited maximum altitude. Compared with airbreathing engines, rockets are lightweight and powerful and capable of generating large accelerations. To control their flight, rockets rely on momentum, airfoils, auxiliary reaction engines, gimballed thrust, momentum wheels, deflection of the exhaust stream, propellant flow, spin, or gravity. Rockets for military and recreational uses date back to at least 13th-century China. Signific ...
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Nazi Germany
Nazi Germany (lit. "National Socialist State"), ' (lit. "Nazi State") for short; also ' (lit. "National Socialist Germany") (officially known as the German Reich from 1933 until 1943, and the Greater German Reich from 1943 to 1945) was the German state between 1933 and 1945, when Adolf Hitler and the Nazi Party controlled the country, transforming it into a dictatorship. Under Hitler's rule, Germany quickly became a totalitarian state where nearly all aspects of life were controlled by the government. The Third Reich, meaning "Third Realm" or "Third Empire", alluded to the Nazi claim that Nazi Germany was the successor to the earlier Holy Roman Empire (800–1806) and German Empire (1871–1918). The Third Reich, which Hitler and the Nazis referred to as the Thousand-Year Reich, ended in May 1945 after just 12 years when the Allies defeated Germany, ending World War II in Europe. On 30 January 1933, Hitler was appointed chancellor of Germany, the head of gove ...
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World War II
World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposing military alliances: the Allies and the Axis powers. World War II was a total war that directly involved more than 100 million personnel from more than 30 countries. The major participants in the war threw their entire economic, industrial, and scientific capabilities behind the war effort, blurring the distinction between civilian and military resources. Aircraft played a major role in the conflict, enabling the strategic bombing of population centres and deploying the only two nuclear weapons ever used in war. World War II was by far the deadliest conflict in human history; it resulted in 70 to 85 million fatalities, mostly among civilians. Tens of millions died due to genocides (including the Holocaust), starvation, ma ...
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