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Wellman–Lord Process
The Wellman–Lord process is a regenerable process to remove sulfur dioxide from flue gas (flue-gas desulfurization) without creating a throwaway sludge product. In this process, sulfur dioxide from flue gas is absorbed in a sodium sulfite solution in water forming sodium bisulfite; other components of flue gas are not absorbed. After lowering the temperature the bisulfite is converted to the sodium pyrosulfite which precipitates. Upon heating, the two previously described chemical reactions are reversed, and sodium pyrosulfite is converted to a concentrated stream of sulfur dioxide and sodium sulfite. The sulfur dioxide can be used for further reactions (e.g. the production of sulfuric acid), and the sulfite is reintroduced into the process. :Na2SO3 + SO2 + H2O → 2NaHSO3 :2NaHSO3 → Na2S2O5↓ + H2O :Na2S2O5 + H2O → 2NaHSO3 :2NaHSO3 → Na2SO3 + SO2 + H2O In its initial version ( Crane Station, Maryland, 1968) the process was based on potassium sulfite, but the economi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfur Dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of copper extraction and the burning of sulfur- bearing fossil fuels. Structure and bonding SO2 is a bent molecule with ''C''2v symmetry point group. A valence bond theory approach considering just ''s'' and ''p'' orbitals would describe the bonding in terms of resonance between two resonance structures. The sulfur–oxygen bond has a bond order of 1.5. There is support for this simple approach that does not invoke ''d'' orbital participation. In terms of electron-counting formalism, the sulfur atom has an oxidation state of +4 and a formal charge of +1. Occurrence Sulfur dioxide is found on Earth and exists in very small concentrations and in the atmosphere at about 1 ppm. On other planets, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flue Gas
Flue gas is the gas exiting to the atmosphere via a flue, which is a pipe or channel for conveying exhaust gases from a fireplace, oven, furnace, boiler or steam generator. Quite often, the flue gas refers to the combustion exhaust gas produced at power plants. Its composition depends on what is being burned, but it will usually consist of mostly nitrogen (typically more than two-thirds) derived from the combustion of air, carbon dioxide (), and water vapor as well as excess oxygen (also derived from the combustion air). It further contains a small percentage of a number of pollutants, such as particulate matter (like soot), carbon monoxide, nitrogen oxides, and sulfur oxides. Most fossil fuels are combusted with ambient air (as differentiated from combustion with pure oxygen). Since ambient air contains about 79 volume percent gaseous nitrogen (N2), which is essentially non-combustible, the largest part of the flue gas from most fossil-fuel combustion is uncombusted nitrogen. Ca ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flue-gas Desulfurization
Flue-gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide () from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes such as waste incineration. Methods Since stringent environmental regulations limiting emissions have been enacted in many countries, is being removed from flue gases by a variety of methods. Common methods used: * Wet scrubbing using a slurry of alkaline sorbent, usually limestone or lime, or seawater to scrub gases; * Spray-dry scrubbing using similar sorbent slurries; *Wet sulfuric acid process recovering sulfur in the form of commercial quality sulfuric acid; * SNOX Flue gas desulfurization removes sulfur dioxide, nitrogen oxides and particulates from flue gases; *Dry sorbent injection systems that introduce powdered hydrated lime (or other sorbent material) into exhaust ducts to eliminate and from process emissions. For a typical coal-fired power station, flue-ga ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Sulfite
Sodium sulfite (sodium sulphite) is the inorganic compound with the chemical formula Na2 SO3. A white, water-soluble solid, it is used commercially as an antioxidant and preservative. A heptahydrate is also known but it is less useful because of its greater susceptibility toward oxidation by air. Preparation Sodium sulfite can be prepared by treating a solution of sodium hydroxide with sulfur dioxide. When conducted in warm water, Na2SO3 initially precipitates as a white solid. With more SO2, the solid dissolves to give the disulfite, which crystallizes upon cooling. :SO2 + 2 NaOH -> Na2SO3 + H2O Sodium sulfite is made industrially by treating sulfur dioxide with a solution of sodium carbonate. The overall reaction is: :SO2 + Na2CO3 -> Na2SO3 + CO2 Applications Sodium sulfite is primarily used in the pulp and paper industry. It has been also applied in the thermomechanical conversion of wood to fibres (''defibration'') for producing medium density fibreboards (M ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Bisulfite
Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO3. Sodium bisulfite in fact is not a real compound, but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions. It appears in form of white or yellowish-white crystals with an odor of sulfur dioxide. For properties of sodium bisulfite, refer to the table located to the right. Regardless of its ill-defined nature, sodium bisulfite is used in many different industries such a food additive with E number E222 in the food industry, a reducing agent in the cosmetic industry, and a decomposer of residual hypochlorite used in the bleaching industry. Synthesis Sodium bisulfite solutions can be prepared by treating a solution of suitable base, such as sodium hydroxide or sodium bicarbonate with sulfur dioxide. :SO2 + NaOH → NaHSO3 :SO2 + NaHCO3 → NaHSO3 + CO2 Attempts to crystallize the product yield Sodium me ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Pyrosulfite
Sodium metabisulfite or sodium pyrosulfite (IUPAC spelling; Br. E. sodium metabisulphite or sodium pyrosulphite) is an inorganic compound of chemical formula Na2S2O5. The substance is sometimes referred to as disodium metabisulfite. It is used as a disinfectant, antioxidant, and preservative agent. Preparation Sodium metabisulfite can be prepared by treating a solution of sodium hydroxide with sulfur dioxide. When conducted in warm water, Na2SO3 initially precipitates as a yellow solid. With more SO2, the solid dissolves to give the disulfite, which crystallises upon cooling. :SO2 + 2 NaOH → Na2SO3 + H2O :SO2 + Na2SO3 → Na2S2O5 which yields a residue of colourless solid Na2S2O5. Chemical structure The anion metabisulfite consists of an SO2 group linked to an SO3 group, with the negative charge more localised on the SO3 end. The S–S bond length is 2.22 Å, and the "thionate" and "thionite" S–O distances are 1.46 and 1.50 Å, respectively. Reactivity Upon d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Charles P
Charles is a masculine given name predominantly found in English and French speaking countries. It is from the French form ''Charles'' of the Proto-Germanic name (in runic alphabet) or ''*karilaz'' (in Latin alphabet), whose meaning was "free man". The Old English descendant of this word was '' Ċearl'' or ''Ċeorl'', as the name of King Cearl of Mercia, that disappeared after the Norman conquest of England. The name was notably borne by Charlemagne (Charles the Great), and was at the time Latinized as ''Karolus'' (as in ''Vita Karoli Magni''), later also as '' Carolus''. Some Germanic languages, for example Dutch and German, have retained the word in two separate senses. In the particular case of Dutch, ''Karel'' refers to the given name, whereas the noun ''kerel'' means "a bloke, fellow, man". Etymology The name's etymology is a Common Germanic noun ''*karilaz'' meaning "free man", which survives in English as churl (< Old English ''ċeorl''), which developed its depr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Sulfite
Potassium sulfite is the inorganic compound with the formula K2SO3. It is the salt of potassium cation and sulfite anion. It is a white solid that is highly soluble in water. Use Potassium sulfite is widely used for preserving food and beverages. Production and reactions Potassium sulfite is produced by the thermal decomposition of potassium metabisulfite Potassium metabisulfite, K2S2O5, also known as potassium pyrosulfite, is a white crystalline powder with a pungent odour. It is mainly used as an antioxidant or chemical sterilant. As a disulfite, it is chemically very similar to sodium metabi ... at 190°C: :K2S2O5 → K2SO3 + SO2 References Potassium compounds Sulfites {{inorganic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
USEPA
The Environmental Protection Agency (EPA) is an Independent agencies of the United States government, independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon proposed the establishment of EPA on July 9, 1970; it began operation on December 2, 1970, after Nixon signed an executive order. The Reorganization Plan No. 3, order establishing the EPA was ratified by committee hearings in the House and Senate. The agency is led by its Administrator of the Environmental Protection Agency, administrator, who is appointed by the President of the United States, president and approved by the United States Senate, Senate. The current administrator is Michael S. Regan. The EPA is not a Cabinet of the United States, Cabinet department, but the administrator is normally given Cabinet of the United States#Cabinet-level officials, cabinet rank. The EPA has its headquarters in Washington, D.C., regional offices for ea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mitchell Station, Indiana
Mitchell may refer to: People *Mitchell (surname) *Mitchell (given name) Places Australia * Mitchell, Australian Capital Territory, a light-industrial estate * Mitchell, New South Wales, a suburb of Bathurst * Mitchell, Northern Territory, a suburb of Palmerston * Mitchell, Queensland, a town * Mitchell, South Australia, on lower Eyre Peninsula * Division of Mitchell, a federal Australian Electoral Division in north-west Sydney, New South Wales * Electoral district of Mitchell (Queensland), a former electoral district * Electoral district of Mitchell (South Australia), a state electoral district * Electoral district of Mitchell (Western Australia) a state electoral district * Shire of Mitchell, a local government area in Victoria Canada * Mitchell, Ontario * Mitchell, Manitoba, an unincorporated community * Mitchell Island, British Columbia * Mitchell Island (Nunavut) United Kingdom * Mitchell, Cornwall, a village * Mitchell (UK Parliament constituency) United S ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula . It is a colorless, odorless and viscous liquid that is miscible with water. Pure sulfuric acid does not exist naturally on Earth due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is highly corrosive towards other materials, from rocks to metals, since it is an oxidant with powerful dehydrating properties. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid, but to the contrary dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus the reverse procedure of adding water to the acid should not be performed since the heat released may boi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lakeland, Florida
Lakeland is the most populous city in Polk County, Florida, part of the Tampa Bay Area, located along Interstate 4 east of Tampa. According to the 2020 U.S. Census Bureau release, the city had a population of 112,641. Lakeland is a principal city of the Lakeland–Winter Haven Metropolitan Statistical Area. European-American settlers arrived in Lakeland from Missouri, Kentucky, Tennessee, Georgia and South Carolina in the 1870s. The city expanded in the 1880s with the arrival of rail service, with the first freedmen railway workers settling here in 1883.Kimberly C. Moore, "Confederate vets, former slaves form Lakeland’s history" ''The Ledger'', 09 May 2018; accessed 27 June 2018 They and European immigrants also came ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
