Wakenroder's Liquid
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Wakenroder's Liquid
Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula Sn(SO3H)2 (''n'' > 2). Trithionic acid (H2S3O6), tetrathionic acid (H2S4O6) are simple examples. They are the conjugate acids of polythionates. The compounds of ''n'' < 80 are expected to exist, and those of ''n'' < 20 have already been synthesized. Dithionic acid (H2S2O6) does not belong to the polythionic acids due to strongly different properties.


Nomenclature

All polythionates anion contains chains of sulfur atoms attached to the terminal SO3H-groups. Names of polythionic acids are determined by the number of atoms in the chain of sulfur atoms: * – dithionic acid * – trithionic acid * – * – , etc.


History

Numerous acids and salts of this group have a venerable history, and chemistry systems, where they exist, dates back to the studies John Dalton devoted to the behavior of hy ...
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