Viscometry
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Viscometry
A viscometer (also called viscosimeter) is an instrument used to measure the viscosity of a fluid. For liquids with viscosities which vary with flow conditions, an instrument called a rheometer is used. Thus, a rheometer can be considered as a special type of viscometer. Viscometers only measure under one flow condition. In general, either the fluid remains stationary and an object moves through it, or the object is stationary and the fluid moves past it. The drag caused by relative motion of the fluid and a surface is a measure of the viscosity. The flow conditions must have a sufficiently small value of Reynolds number for there to be laminar flow. At 20°C, the dynamic viscosity (kinematic viscosity × density) of water is 1.0038 mPa·s and its kinematic viscosity (product of flow time × factor) is 1.0022mm2/s. These values are used for calibrating certain types of viscometers. Standard laboratory viscometers for liquids U-tube viscometers These devices are also known as gl ...
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Stokes' Law
In 1851, George Gabriel Stokes derived an expression, now known as Stokes' law, for the frictional force – also called drag force – exerted on spherical objects with very small Reynolds numbers in a viscous fluid. Stokes' law is derived by solving the Stokes flow limit for small Reynolds numbers of the Navier–Stokes equations.Batchelor (1967), p. 233. Statement of the law The force of viscosity on a small sphere moving through a viscous fluid is given by: :F_ = 6 \pi \mu R v where: * ''F''d is the frictional force – known as Stokes' drag – acting on the interface between the fluid and the particle * ''μ'' is the dynamic viscosity (some authors use the symbol ''η'') * ''R'' is the radius of the spherical object * ''v'' is the flow velocity relative to the object. In SI units, ''F''d is given in newtons (= kg m s−2), ''μ'' in Pa·s (= kg m−1 s−1), ''R'' in meters, and ''v'' in m/s. Stokes' law makes the following assumptions for the behavior of a particle i ...
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Rheometer
A rheometer is a laboratory device used to measure the way in which a dense fluid (a liquid, suspension or slurry) flows in response to applied forces. It is used for those fluids which cannot be defined by a single value of viscosity and therefore require more parameters to be set and measured than is the case for a viscometer. It measures the rheology of the fluid. There are two distinctively different types of ''rheometers''. Rheometers that control the applied shear stress or shear strain are called rotational or shear rheometers, whereas rheometers that apply extensional stress or extensional strain are extensional rheometers. Rotational or shear type rheometers are usually designed as either a native strain-controlled instrument (control and apply a user-defined shear strain which can then measure the resulting shear stress) or a native stress-controlled instrument (control and apply a user-defined shear stress and measure the resulting shear strain). Meanings and ...
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Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is ...
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Polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'' ...
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Saybolt Universal Second
Saybolt universal viscosity (SUV), and the related Saybolt FUROL viscosity (SFV), are specific standardised tests producing measures of kinematic viscosity. ''FUROL'' is an acronym for ''fuel and road oil''. Saybolt universal viscosity is specified by the ASTM ASTM International, formerly known as American Society for Testing and Materials, is an international standards organization that develops and publishes voluntary consensus technical standards for a wide range of materials, products, systems, an ...D2161. Both tests are considered obsolete to other measures of kinematic viscosity, but their results are quoted widely in technical literature. In both tests, the time taken for 60ml of the liquid, held at a specific temperature, to flow through a calibrated tube, is measured, using a Saybolt viscometer.
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Fuel Viscosity Control
Fuel viscosity control is a technique to control viscosity and temperature of fuel oil (FO) for efficient combustion in diesel engines of motor vessels and generators of oil-fired power plants. Fuel oil's viscosity strongly depends on the temperature, the higher is the temperature the lower is the viscosity. For optimal combustion the viscosity of the fuel should be in the range of 10–20{{nbsp cSt. To maintain this value a combination of viscometer, PID controller and heater is used. Viscometer measures the actual viscosity of the fuel, this value is compared with the set point in the controller and the command is sent to the heater to adjust the temperature of the fuel. See also *Diesel fuel *Fuel oil *Viscosity *Viscometer A viscometer (also called viscosimeter) is an instrument used to measure the viscosity of a fluid. For liquids with viscosities which vary with flow conditions, an instrument called a rheometer is used. Thus, a rheometer can be considered as a spec ... ...
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Thixotropic
Thixotropy is a time-dependent shear thinning property. Certain gels or fluids that are thick or viscous under static conditions will flow (become thinner, less viscous) over time when shaken, agitated, shear-stressed, or otherwise stressed (time-dependent viscosity). They then take a fixed time to return to a more viscous state. Some non-Newtonian pseudoplastic fluids show a time-dependent change in viscosity; the longer the fluid undergoes shear stress, the lower its viscosity. A thixotropic fluid is a fluid which takes a finite time to attain equilibrium viscosity when introduced to a steep change in shear rate. Some thixotropic fluids return to a gel state almost instantly, such as ketchup, and are called pseudoplastic fluids. Others such as yogurt take much longer and can become nearly solid. Many gels and colloids are thixotropic materials, exhibiting a stable form at rest but becoming fluid when agitated. Thixotropy arises because particles or structured solutes require ...
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Surface Roughness
Surface roughness, often shortened to roughness, is a component of surface finish (surface texture). It is quantified by the deviations in the direction of the normal vector of a real surface from its ideal form. If these deviations are large, the surface is rough; if they are small, the surface is smooth. In surface metrology, roughness is typically considered to be the high-frequency, short-wavelength component of a measured surface. However, in practice it is often necessary to know both the amplitude and frequency to ensure that a surface is fit for a purpose. Roughness plays an important role in determining how a real object will interact with its environment. In tribology, rough surfaces usually wear more quickly and have higher friction coefficients than smooth surfaces. Roughness is often a good predictor of the performance of a mechanical component, since irregularities on the surface may form nucleation sites for cracks or corrosion. On the other hand, roughness may pr ...
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Stokes Flow
Stokes flow (named after George Gabriel Stokes), also named creeping flow or creeping motion,Kim, S. & Karrila, S. J. (2005) ''Microhydrodynamics: Principles and Selected Applications'', Dover. . is a type of fluid flow where advective inertial forces are small compared with viscous forces. The Reynolds number is low, i.e. \mathrm \ll 1. This is a typical situation in flows where the fluid velocities are very slow, the viscosities are very large, or the length-scales of the flow are very small. Creeping flow was first studied to understand lubrication. In nature this type of flow occurs in the swimming of microorganisms, sperm and the flow of lava. In technology, it occurs in paint, MEMS devices, and in the flow of viscous polymers generally. The equations of motion for Stokes flow, called the Stokes equations, are a linearization of the Navier–Stokes equations, and thus can be solved by a number of well-known methods for linear differential equations. The primary Green's ...
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Gravitational Acceleration
In physics, gravitational acceleration is the acceleration of an object in free fall within a vacuum (and thus without experiencing drag). This is the steady gain in speed caused exclusively by the force of gravitational attraction. All bodies accelerate in vacuum at the same rate, regardless of the masses or compositions of the bodies; the measurement and analysis of these rates is known as gravimetry. At a fixed point on the surface, the magnitude of Earth's gravity results from combined effect of gravitation and the centrifugal force from Earth's rotation. At different points on Earth's surface, the free fall acceleration ranges from , depending on altitude, latitude, and longitude. A conventional standard value is defined exactly as . Locations of significant variation from this value are known as gravity anomalies. This does not take into account other effects, such as buoyancy or drag. Relation to the Universal Law Newton's law of universal gravitation states that ...
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Stokes Radius
The Stokes radius or Stokes–Einstein radius of a solute is the radius of a hard sphere that diffuses at the same rate as that solute. Named after George Gabriel Stokes, it is closely related to solute mobility, factoring in not only size but also solvent effects. A smaller ion with stronger hydration, for example, may have a greater Stokes radius than a larger ion with weaker hydration. This is because the smaller ion drags a greater number of water molecules with it as it moves through the solution. Stokes radius is sometimes used synonymously with effective hydrated radius in solution. Hydrodynamic radius, ''R''''H'', can refer to the Stokes radius of a polymer or other macromolecule. Spherical case According to Stokes’ law, a perfect sphere traveling through a viscous liquid feels a drag force proportional to the frictional coefficient f: F_\text = fs = (6 \pi \eta a)s where \eta is the liquid's viscosity, s is the sphere's drift speed, and a is its radius. Because ...
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Gravitational Force
In physics, gravity () is a fundamental interaction which causes mutual attraction between all things with mass or energy. Gravity is, by far, the weakest of the four fundamental interactions, approximately 1038 times weaker than the strong interaction, 1036 times weaker than the electromagnetic force and 1029 times weaker than the weak interaction. As a result, it has no significant influence at the level of subatomic particles. However, gravity is the most significant interaction between objects at the macroscopic scale, and it determines the motion of planets, stars, galaxies, and even light. On Earth, gravity gives weight to physical objects, and the Moon's gravity is responsible for sublunar tides in the oceans (the corresponding antipodal tide is caused by the inertia of the Earth and Moon orbiting one another). Gravity also has many important biological functions, helping to guide the growth of plants through the process of gravitropism and influencing the circulati ...
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