Uranium Hydride
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Uranium Hydride
Uranium hydride, also called uranium trihydride (UH3), is an inorganic compound and a hydride of uranium. Properties Uranium hydride is a highly toxic, brownish grey to brownish black pyrophoric powder or brittle solid. Its density at 20 °C is 10.95 g cm−3, much lower than that of uranium (19.1 g cm−3). It has a metallic conductivity, is slightly soluble in hydrochloric acid and decomposes in nitric acid. Two crystal modifications of uranium hydride exist, both cubic: an α form that is obtained at low temperatures and a β form that is grown when the formation temperature is above 250 °C. After growth, both forms are metastable at room temperature and below, but the α form slowly converts to the β form upon heating to 100 °C. Both α- and β-UH3 are ferromagnetic at temperatures below ~180 K. Above 180 K, they are paramagnetic. Formation in uranium metal Hydrogen gas reaction Exposure of uranium metal to hydrogen leads to hydrogen embrittlement. Hydrog ...
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Pyrophoric
A substance is pyrophoric (from grc-gre, πυροφόρος, , 'fire-bearing') if it ignites spontaneously in air at or below (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). Examples are organolithium compounds and triethylborane. Pyrophoric materials are often water-reactive as well and will ignite when they contact water or humid air. They can be handled safely in atmospheres of argon or (with a few exceptions) nitrogen. Fire Classes#Metal, Class D fire extinguisher#Class D dry powder and other agents for metal fires, fire extinguishers are designated for use in fires involving pyrophoric materials. A related concept is hypergolic propellant, hypergolicity, in which two compounds spontaneously ignite when mixed. Uses The creation of spark (fire), sparks from metals is based on the pyrophoricity of small metal particles, and pyrophoric alloys are made for this purpose. The sparking mechanisms in lighters and various toys, using fe ...
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Halide
In chemistry, a halide (rarely halogenide) is a binary chemical compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluoride, chloride, bromide, iodide, astatide, or theoretically tennesside compound. The alkali metals combine directly with halogens under appropriate conditions forming halides of the general formula, MX (X = F, Cl, Br or I). Many salts are halides; the ''hal-'' syllable in ''halide'' and ''halite'' reflects this correlation. All Group 1 metals form halides that are white solids at room temperature. A halide ion is a halogen atom bearing a negative charge. The halide anions are fluoride (), chloride (), bromide (), iodide () and astatide (). Such ions are present in all ionic halide salts. Halide minerals contain halides. All these halides are colourless, high melting crystalline solids having high negative enthalpies of formation. Test ...
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Spent Fuel Pond
Spent fuel pools (SFP) are storage pools (or "ponds" in the United Kingdom) for spent fuel from nuclear reactors. They are typically 40 or more feet (12 m) deep, with the bottom 14 feet (4.3 m) equipped with storage racks designed to hold fuel assemblies removed from reactors. A reactor's local pool is specially designed for the reactor in which the fuel was used and is situated at the reactor site. Such pools are used for short-term cooling of the fuel rods. This allows short-lived isotopes to decay and thus reduces the ionizing radiation and decay heat emanating from the rods. The water cools the fuel and provides radiological protection from its radiation. Pools also exist on sites remote from reactors, for longer term storage such as the Independent Spent Fuel Storage Installation (ISFSI), located at the Morris Operation, or as a production buffer for 10 to 20 years before being sent for reprocessing or dry cask storage. While only about 20 feet (about 6 m) of wat ...
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Spent Nuclear Fuel
Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and depending on its point along the nuclear fuel cycle, it may have considerably different isotopic constituents. The term "fuel" is slightly confusing, as it implies a combustion of some type, which does not occur in a nuclear power plant. Nevertheless, this term is generally accepted. Nature of spent fuel Nanomaterial properties In the oxide fuel, intense temperature gradients exist that cause fission products to migrate. The zirconium tends to move to the centre of the fuel pellet where the temperature is highest, while the lower-boiling fission products move to the edge of the pellet. The pellet is likely to contain many small bubble-like pores that form during use; the fission product xenon migrates to these voids. Some of this xeno ...
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Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as ...
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Helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling and melting point are the lowest among all the elements. It is the second lightest and second most abundant element in the observable universe (hydrogen is the lightest and most abundant). It is present at about 24% of the total elemental mass, which is more than 12 times the mass of all the heavier elements combined. Its abundance is similar to this in both the Sun and in Jupiter, due to the very high nuclear binding energy (per nucleon) of helium-4, with respect to the next three elements after helium. This helium-4 binding energy also accounts for why it is a product of both nuclear fusion and radioactive decay. The most common isotope of helium in the universe is helium-4, the vast majority of which was formed during t ...
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Passivation (chemistry)
Passivation, in physical chemistry and engineering, refers to coating a material so it becomes "passive", that is, less readily affected or corroded by the environment. Passivation involves creation of an outer layer of shield material that is applied as a microcoating, created by chemical reaction with the base material, or allowed to build by spontaneous oxidation in the air. As a technique, passivation is the use of a light coat of a protective material, such as metal oxide, to create a shield against corrosion. Passivation of silicon is used during fabrication of microelectronic devices. In electrochemical treatment of water, passivation reduces the effectiveness of the treatment by increasing the circuit resistance, and active measures are typically used to overcome this effect, the most common being polarity reversal, which results in limited rejection of the fouling layer. When exposed to air, many metals naturally form a hard, relatively inert surface layer, usually an ...
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Fuel Rod
Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergoing and sustaining nuclear fission. The three most relevant fissile isotopes are uranium-233, uranium-235 and plutonium-239. When the unstable nuclei of these atoms are hit by a slow-moving neutron, they frequently split, creating two daughter nuclei and two or three more neutrons. In that case, the neutrons released go on to split more nuclei. This creates a self-sustaining chain reaction that is controlled in a nuclear reactor, or uncontrolled in a nuclear weapon. Alternatively, if the nucleus absorbs the neutron without splitting, it creates a heavier nucleus with one additional neutron. The processes involved in mining, refining, purifying, using, and disposing of nuclear fuel are collectively known as the nuclear fuel cycle. Not all typ ...
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Cladding (nuclear Fuel)
Cladding is an outer layer of material covering another. It may refer to the following: *Cladding (boiler), the layer of insulation and outer wrapping around a boiler shell *Cladding (construction), materials applied to the exterior of buildings **Wall cladding, exterior material applied to the walls of a building **Copper cladding, applying copper to the exterior of buildings **Rainscreen cladding, an exterior wall detail to create a capillary break and to allow drainage and evaporation of water *Cladding (fiber optics), fiber optics property to contain light in the core of the fiber by total internal reflection *Cladding (metalworking), a bonding together of dissimilar metals *Cladding (nuclear fuel) Cladding is an outer layer of material covering another. It may refer to the following: *Cladding (boiler), the layer of insulation and outer wrapping around a boiler shell *Cladding (construction), materials applied to the exterior of buildings ..., the outer layer of the fuel ...
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Magnox
Magnox is a type of nuclear power/production reactor that was designed to run on natural uranium with graphite as the moderator and carbon dioxide gas as the heat exchange coolant. It belongs to the wider class of gas-cooled reactors. The name comes from the magnesium-aluminium alloy used to clad the fuel rods inside the reactor. Like most other " Generation I nuclear reactors", the Magnox was designed with the dual purpose of producing electrical power and plutonium-239 for the nascent nuclear weapons programme in Britain. The name refers specifically to the United Kingdom design but is sometimes used generically to refer to any similar reactor. As with other plutonium-producing reactors, conserving neutrons is a key element of the design. In magnox, the neutrons are moderated in large blocks of graphite. The efficiency of graphite as a moderator allows the Magnox to run using natural uranium fuel, in contrast with the more common commercial light-water reactor which re ...
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Liquid Hydrogen
Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point of 33  K. However, for it to be in a fully liquid state at atmospheric pressure, H2 needs to be cooled to .IPTS-1968
iupac.org, accessed 2020-01-01
A common method of obtaining liquid hydrogen involves a compressor resembling a jet engine in both appearance and principle. Liquid hydrogen is typically used as a concentrated form of . Storing it as liquid takes less space than storing it as a gas at ...
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Atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. Atoms are extremely small, typically around 100 picometers across. They are so small that accurately predicting their behavior using classical physics, as if they were tennis balls for example, is not possible due to quantum effects. More than 99.94% of an atom's mass is in the nucleus. The protons have a positive electric charge, the electrons have a negative electric charge, and the neutrons have no electric charge. If the number of protons and electrons are equal, then the atom is electrically neutral. If an atom has more or fewer electrons than protons, then it has an overall negative or positive charge, respectively – such atoms are called ions. The electrons of an atom are a ...
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