Ultra High Temperature Ceramic Matrix Composite
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Ultra High Temperature Ceramic Matrix Composite
Ultra-high temperature ceramic matrix composites (UHTCMC) or Ultra-high Temperature Ceramic Composites (UHTCC) are a class of refractory ceramic matrix composites ( CMCs), which aspires to overcome the limits associated with currently used CMCs (C/C and C/SiC) in aerospace field as thermal protection systems (TPS) and rocket nozzles. Carbon fiber reinforced carbon matrix ( C/C) can be used up to 3000 °C because carbon is the element with the highest melting point however C/C are ablative materials which dissipate energy consuming themselves. Carbon fiber reinforced silicon carbide matrix composites ( C/SiC) and Silicon carbide fiber reinforced silicon carbide matrix composites ( SiC/SiC) are considered reusable materials because silicon carbide is a hard material with a low erosion and it forms a silica glass layer during oxidation which prevents further oxidation of inner material. Unfortunately above a certain temperature (it depends on environmental conditions of oxygen p ...
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Ceramic Matrix Composite
In materials science, ceramic matrix composites (CMCs) are a subgroup of composite materials and a subgroup of ceramics. They consist of ceramic fibers embedded in a ceramic matrix. The fibers and the matrix both can consist of any ceramic material, whereby carbon and carbon fibers can also be regarded as a ceramic material. Introduction The motivation to develop CMCs was to overcome the problems associated with the conventional technical ceramics like alumina, silicon carbide, aluminum nitride, silicon nitride or zirconia – they fracture easily under mechanical or thermo-mechanical loads because of cracks initiated by small defects or scratches. The crack resistance is very low, as in glass. To increase the crack resistance or fracture toughness, particles (so-called monocrystalline ''whiskers'' or ''platelets'') were embedded into the matrix. However, the improvement was limited, and the products have found application only in some ceramic cutting tools. So far only the i ...
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Silicon Monoxide
Silicon monoxide is the chemical compound with the formula SiO where silicon is present in the oxidation state +2. In the vapour phase, it is a diatomic molecule. It has been detected in stellar objects and has been described as the most common oxide of silicon in the universe.Peter Jutzi and Ulrich Schubert (2003) ''Silicon chemistry: from the atom to extended systems''. Wiley-VCH . Solid form When SiO gas is cooled rapidly, it condenses to form a brown/black polymeric glassy material, (SiO)''n'', which is available commercially and used to deposit films of SiO. Glassy (SiO)''n'' is air and moisture sensitive. Oxidation Its surface readily oxidizes in air at room temperature, giving an SiO2 surface layer that protects the material from further oxidation. However, (SiO)''n'' irreversibly disproportionates into SiO2 and Si in a few hours between 400 °C and 800 °C and very rapidly between 1,000 °C and 1,440 °C, although the reaction does not go to completi ...
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Carbon Fibers
Carbon fibers or carbon fibres (alternatively CF, graphite fiber or graphite fibre) are fibers about in diameter and composed mostly of carbon atoms. Carbon fibers have several advantages: high stiffness, high tensile strength, high strength to weight ratio, high chemical resistance, high-temperature tolerance, and low thermal expansion. These properties have made carbon fiber very popular in aerospace, civil engineering, military, motorsports, and other competition sports. However, they are relatively expensive compared to similar fibers, such as glass fiber, basalt fibers, or plastic fibers. To produce a carbon fiber, the carbon atoms are bonded together in crystals that are more or less aligned parallel to the fiber's long axis as the crystal alignment gives the fiber a high strength-to-volume ratio (in other words, it is strong for its size). Several thousand carbon fibers are bundled together to form a tow, which may be used by itself or woven into a fabric. Carbon f ...
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Silicon Carbide Fibers
Silicon carbide fibers are fibers ranging from 5 to 150 micrometres in diameter and composed primarily of silicon carbide molecules. Depending on manufacturing process, they may have some excess silicon or carbon, or have a small amount of oxygen. Relative to organic fibers and some ceramic fibers, silicon carbide fibers have high stiffness, high tensile strength, low weight, high chemical resistance, high temperature tolerance and low thermal expansion. (refs) These properties have made silicon carbide fiber the choice for hot section components in the next generation of gas turbines, e.g. the LEAP engine from GE (General Electric). Manufacture There are several manufacturing approaches to making silicon carbide fibers. The one with the longest historical experience, invented in 1975 and called the Yajima process, uses a pre-ceramic liquid polymer that is injected through a spinneret to produce solidified green (unfired) fibers that go through a series of processing steps, inc ...
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Framework Programmes For Research And Technological Development
The Framework Programmes for Research and Technological Development, also called Framework Programmes or abbreviated FP1 to FP9, are funding programmes created by the European Union/European Commission to support and foster research in the European Research Area (ERA). Starting in 2014, the funding programmes were named Horizon. The funding programmes began in 1984 and continue to the present day. The most recent programme, Horizon Europe, has a budget of 95.5 billion Euros to be distributed over 7 years. The specific objectives and actions vary between funding periods. In FP6 and FP7, focus was on technological research. In Horizon 2020, the focus was on innovation, delivering economic growth faster, and delivering solutions to end users that are often governmental agencies. Background Conducting European research policies and implementing European research programmes is an obligation under the Amsterdam Treaty, which includes a chapter on research and technological development. ...
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European Commission
The European Commission (EC) is the executive of the European Union (EU). It operates as a cabinet government, with 27 members of the Commission (informally known as "Commissioners") headed by a President. It includes an administrative body of about 32,000 European civil servants. The Commission is divided into departments known as Directorates-General (DGs) that can be likened to departments or ministries each headed by a Director-General who is responsible to a Commissioner. There is one member per member state, but members are bound by their oath of office to represent the general interest of the EU as a whole rather than their home state. The Commission President (currently Ursula von der Leyen) is proposed by the European Council (the 27 heads of state/governments) and elected by the European Parliament. The Council of the European Union then nominates the other members of the Commission in agreement with the nominated President, and the 27 members as a team are then ...
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Heat Shield
In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is also often used to refer to the thermal energy contained in a system as a component of its internal energy and that is reflected in the temperature of the system. For both uses of the term, heat is a form of energy. An example of formal vs. informal usage may be obtained from the right-hand photo, in which the metal bar is "conducting heat" from its hot end to its cold end, but if the metal bar is considered a thermodynamic system, then the energy flowing within the metal bar is called internal energy, not heat. The hot metal bar is also transferring heat to its surroundings, a correct statement for both the strict and loose meanings of ''heat''. Another example of informal usage is the term '' heat content'', used despite the fact that p ...
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Ultra-high-temperature Ceramics
Ultra-high-temperature ceramics (UHTCs) are a class of refractory ceramics that offer excellent stability at temperatures exceeding 2,000 °C being investigated as possible thermal protection system (TPS) materials, coatings for materials subjected to high temperatures, and bulk materials for heating elements. Broadly speaking, UHTCs are borides, carbides, nitrides, and oxides of early transition metals. Current efforts have focused on heavy, early transition metal borides such as hafnium diboride (HfB2) and zirconium diboride (ZrB2); additional UHTCs under investigation for TPS applications include hafnium nitride (HfN), zirconium nitride (ZrN), titanium carbide (TiC), titanium nitride (TiN), thorium dioxide (ThO2), tantalum carbide (TaC) and their associated composites. History Beginning in the early 1960s, demand for high-temperature materials by the nascent aerospace industry prompted the US Air Force Materials Laboratory to begin funding the development of a new class ...
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Silicon Monoxide
Silicon monoxide is the chemical compound with the formula SiO where silicon is present in the oxidation state +2. In the vapour phase, it is a diatomic molecule. It has been detected in stellar objects and has been described as the most common oxide of silicon in the universe.Peter Jutzi and Ulrich Schubert (2003) ''Silicon chemistry: from the atom to extended systems''. Wiley-VCH . Solid form When SiO gas is cooled rapidly, it condenses to form a brown/black polymeric glassy material, (SiO)''n'', which is available commercially and used to deposit films of SiO. Glassy (SiO)''n'' is air and moisture sensitive. Oxidation Its surface readily oxidizes in air at room temperature, giving an SiO2 surface layer that protects the material from further oxidation. However, (SiO)''n'' irreversibly disproportionates into SiO2 and Si in a few hours between 400 °C and 800 °C and very rapidly between 1,000 °C and 1,440 °C, although the reaction does not go to completi ...
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Ceramic Matrix Composite
In materials science, ceramic matrix composites (CMCs) are a subgroup of composite materials and a subgroup of ceramics. They consist of ceramic fibers embedded in a ceramic matrix. The fibers and the matrix both can consist of any ceramic material, whereby carbon and carbon fibers can also be regarded as a ceramic material. Introduction The motivation to develop CMCs was to overcome the problems associated with the conventional technical ceramics like alumina, silicon carbide, aluminum nitride, silicon nitride or zirconia – they fracture easily under mechanical or thermo-mechanical loads because of cracks initiated by small defects or scratches. The crack resistance is very low, as in glass. To increase the crack resistance or fracture toughness, particles (so-called monocrystalline ''whiskers'' or ''platelets'') were embedded into the matrix. However, the improvement was limited, and the products have found application only in some ceramic cutting tools. So far only the i ...
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Silicon Carbide
Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal since 1893 for use as an abrasive. Grains of silicon carbide can be bonded together by sintering to form very hard ceramics that are widely used in applications requiring high endurance, such as car brakes, car clutches and ceramic plates in bulletproof vests. Large single crystals of silicon carbide can be grown by the Lely method and they can be cut into gems known as synthetic moissanite. Electronic applications of silicon carbide such as light-emitting diodes (LEDs) and Cat's whisker detector, detectors in early radios were first demonstrated around 1907. SiC is used in semiconductor electronics devices that operate at high temperatures or high voltages, or both. Natural occurrence Naturally occurring moissanite is found in only minut ...
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Fused Quartz
Fused quartz, fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses in which other ingredients are added which change the glasses' optical and physical properties, such as lowering the melt temperature. Fused quartz, therefore, has high working and melting temperatures, making it less desirable for most common applications. The terms fused quartz and fused silica are used interchangeably, but can refer to different manufacturing techniques, as noted below, resulting in different trace impurities. However fused quartz, being in the glassy state, has quite different physical properties compared to crystalline quartz. Due to its physical properties it finds specialty uses in semiconductor fabrication and laboratory equipment, for instance. Compared to other common glasses, the optical transmission of pure silica extends well into the ultraviolet and infra ...
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