Triacetate
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Triacetate
Cellulose triacetate, (triacetate, CTA or TAC) is a chemical compound produced from cellulose and a source of acetate esters, typically acetic anhydride. Triacetate is commonly used for the creation of fibres and film base. It is chemically similar to cellulose acetate. Its distinguishing characteristic is that in triacetate, at least "92 percent of the hydroxyl groups are acetylated." During the manufacture of triacetate, the cellulose is completely acetylated; whereas in normal cellulose acetate or cellulose diacetate, it is only partially acetylated. Triacetate is significantly more heat resistant than cellulose acetate. History Triacetate, whose chemical equation is 6H7O2(OOCCH3)3sub>n, was first produced commercially in the U.S. in 1954 by Celanese Corporation. Eastman Kodak was a manufacturer of CTA until March 15, 2007. For almost 3 years, Mitsubishi Rayon Co. Ltd. was the only manufacturer. In 2010, Eastman Chemical announced a 70% increase in cellulose triacetate out ...
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Cellulose Acetate
In biochemistry, cellulose acetate refers to any acetate ester of cellulose, usually cellulose diacetate. It was first prepared in 1865. A bioplastic, cellulose acetate is used as a film base in photography, as a component in some coatings, and as a frame material for eyeglasses; it is also used as a synthetic fiber in the manufacture of cigarette filters and playing cards. In cellulose acetate film, photographic film, cellulose acetate film replaced nitrate film in the 1950s, being far less flammable and cheaper to produce. History In 1865, French chemist Paul Schützenberger discovered that cellulose reacts with acetic anhydride to form cellulose acetate. The German chemists Arthur Eichengrün and Theodore Becker invented the first soluble forms of cellulose acetate in 1903. In 1904, Camille Dreyfus (chemist), Camille Dreyfus and his younger brother Henri Dreyfus, Henri performed chemical research and development on cellulose acetate in a shed in their father's garden in Basel ...
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Fibres
Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate fibers, for example carbon fiber and ultra-high-molecular-weight polyethylene. Synthetic fibers can often be produced very cheaply and in large amounts compared to natural fibers, but for clothing natural fibers can give some benefits, such as comfort, over their synthetic counterparts. Natural fibers Natural fibers develop or occur in the fiber shape, and include those produced by plants, animals, and geological processes. They can be classified according to their origin: *Vegetable fibers are generally based on arrangements of cellulose, often with lignin: examples include cotton, hemp, jute, flax, abaca, piña, ramie, sisal, bagasse, and banana. Plant fibers are employed in the manufacture of paper and textile (cloth), and dietar ...
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Cellulose
Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall of green plants, many forms of algae and the oomycetes. Some species of bacteria secrete it to form biofilms. Cellulose is the most abundant organic polymer on Earth. The cellulose content of cotton fiber is 90%, that of wood is 40–50%, and that of dried hemp is approximately 57%. Cellulose is mainly used to produce paperboard and paper. Smaller quantities are converted into a wide variety of derivative products such as cellophane and rayon. Conversion of cellulose from energy crops into biofuels such as cellulosic ethanol is under development as a renewable fuel source. Cellulose for industrial use is mainly obtained from wood pulp and cotton. Some animals, particularly ruminants and termites, can digest cellulose with the help of ...
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Film Base
A film base is a transparent substrate which acts as a support medium for the photosensitive emulsion that lies atop it. Despite the numerous layers and coatings associated with the emulsion layer, the base generally accounts for the vast majority of the thickness of any given film stock. Since the late 19th century, there have been three major types of film base in use: nitrate (until about 1951), acetate, and polyester. Nitrate In the literature of photography "nitrate" is used as a synonym for the chemical nitrocellulose. It is also referred to as "cellulose nitrate". Nitrocellulose is guncotton, the first replacement propellant for gun powder in firearms. Film stock with a nitrate base was the first transparent flexible plasticized base commercially available, thanks to celluloid developments by John Carbutt, Hannibal Goodwin, and Eastman Kodak in the 1880s. Eastman was the first to manufacture the film stock for public sale, in 1889. Unfortunately, nitrate also had the ...
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Spinning (textiles)
Spinning is a twisting technique to form yarn from fibers. The fiber intended is drawn out, twisted, and wound onto a bobbin. A few popular fibers that are spun into yarn other than cotton, which is the most popular, are viscose (the most common form of rayon), and synthetic polyester. Originally done by hand using a spindle whorl, starting in the 500s AD the spinning wheel became the predominant spinning tool across Asia and Europe. The spinning jenny and spinning mule, invented in the late 1700s, made mechanical spinning far more efficient than spinning by hand, and especially made cotton manufacturing one of the most important industries of the Industrial Revolution. Process The yarn issuing from the drafting rollers passes through a thread-guide, round a Ring spinning#How it works, traveller that is free to rotate around a ring, and then onto a tube or bobbin, which is carried on to a Spindle (textiles), spindle, the axis of which passes through a center of the ring. The spin ...
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Cellulose Diacetate
Cellulose diacetate, sometimes called diacetate, is a synthetic polymer made by treating cellulose with acetic acid. It consists of two acetyl functional groups on each unit of D-anhydroglucopyranose of the cellulose molecule. It was first developed in the United States. It is fragile since it is based on cellulose. When cellulose diacetate deteriorates, it shrinks and releases acetic acid causing vinegar syndrome. Cellulose diacetate has been used to make fabrics, membranes, filaments, and many consumer products. From 1922 to 1957 it was used to make film stock, mainly in smaller formats such as 8 mm, 16 mm, 35 mm, and 70 mm. It has also been used in seed coating applications.Friuli, M., Nitti, P., Cafuero, L. et al. Cellulose Acetate and Cardanol Based Seed Coating for Intraspecific Weeding Coupled with Natural Herbicide Spraying. J Polym Environ (2020). https://doi.org/10.1007/s10924-020-01821-9 In photography, a film substrate made from cellulose diacetate is called sa ...
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Fabric
Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the only manufacturing method, and many other methods were later developed to form textile structures based on their intended use. Knitting and non-woven are other popular types of fabric manufacturing. In the contemporary world, textiles satisfy the material needs for versatile applications, from simple daily clothing to bulletproof jackets, spacesuits, and doctor's gowns. Textiles are divided into two groups: Domestic purposes onsumer textilesand technical textiles. In consumer textiles, aesthetics and comfort are the most important factors, but in technical textiles, functional properties are the priority. Geotextiles, industrial textiles, medical textiles, and many other areas are examples of technical textiles, whereas clothing and ...
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Acetic Acid
Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water and other trace elements. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important Reagent, chemical reagent and industrial chemical, used primarily in the production of cellulose acetate for photographic film, polyvinyl acetate for wood Adhesive, glue, and synthetic fibres and fabrics. In households, diluted acetic acid is often used in descaling agents. In the food industry, acetic acid is controlled by the E number, food additive code E260 as an acidity regulator and as a condiment. In biochemistry, the acetyl group, derived from acetic acid, is fundamental to all forms of life. When bound to coenzyme A, it is central to the metabolism of carbohydrates and fats. The global ...
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Saponification
Saponification is a process of converting esters into soaps and alcohols by the action of aqueous alkali (for example, aqueous sodium hydroxide solutions). Soaps are salts of fatty acids, which in turn are carboxylic acids with long carbon chains. Sodium stearate is a typical soap. Saponification of fats Vegetable oils and animal fats are the traditional materials that are saponified. These greasy materials, triesters called triglycerides, are mixtures derived from diverse fatty acids. Triglycerides can be converted to soap in either a one- or a two-step process. In the traditional one-step process, the triglyceride is treated with a strong base (e.g. lye), which cleaves the ester bond, releasing fatty acid salts (soaps) and glycerol. This process is also the main industrial method for producing glycerol. In some soap-making, the glycerol is left in the soap. If necessary, soaps may be precipitated by salting it out with sodium chloride. Fat in a corpse converts into adipoce ...
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Finishing (textiles)
In textile manufacturing, finishing refers to the processes that convert the woven or knitted cloth into a usable material and more specifically to any process performed after dyeing the yarn or fabric to improve the look, performance, or "hand" (feel) of the finish textile or clothing. The precise meaning depends on context. Fabric after leaving the loom or knitting machine is not readily useable. Called grey cloth at this stage, it contains natural and added impurities. Sometimes it is also processed at fiber or yarn stages of textile manufacturing. Grey fiber or yarn or fabric goes through a series of processes such as wet processing and finishing. Finishing is a broad range of physical and chemical treatments that complete one stage of textile manufacturing and may prepare for the next step, making the product more receptive to the next stage of manufacturing. Finishing adds value to the product and makes it more attractive, useful, and functional for the end-user. Improvi ...
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Acetyl Group
In organic chemistry, acetyl is a functional group with the chemical formula and the structure . It is sometimes represented by the symbol Ac (not to be confused with the element actinium). In IUPAC nomenclature, acetyl is called ethanoyl, although this term is barely heard. The acetyl group contains a methyl group () single-bonded to a carbonyl (). The carbonyl center of an acyl radical has one nonbonded electron with which it forms a chemical bond to the remainder ''R'' of the molecule. The acetyl moiety is a component of many organic compounds, including acetic acid, the neurotransmitter acetylcholine, acetyl-CoA, acetylcysteine, acetaminophen (also known as paracetamol), and acetylsalicylic acid (also known as aspirin). Acetylation In nature The introduction of an acetyl group into a molecule is called acetylation. In biological organisms, acetyl groups are commonly transferred from acetyl-CoA to other organic molecules. Acetyl-CoA is an intermediate both ...
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Evaporate
Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidity affects rate of evaporation of water. When the molecules of the liquid collide, they transfer energy to each other based on how they collide. When a molecule near the surface absorbs enough energy to overcome the vapor pressure, it will escape and enter the surrounding air as a gas. When evaporation occurs, the energy removed from the vaporized liquid will reduce the temperature of the liquid, resulting in evaporative cooling. On average, only a fraction of the molecules in a liquid have enough heat energy to escape from the liquid. The evaporation will continue until an equilibrium is reached when the evaporation of the liquid is equal to its condensation. In an enclosed environment, a liquid will evaporate until the surrounding air is ...
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