Thermal Capillary Wave
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Thermal Capillary Wave
Thermal motion is able to produce capillary waves at the molecular scale. At this scale, gravity and hydrodynamics can be neglected, and only the surface tension contribution is relevant. Capillary wave theory (CWT) is a classic account of how thermal fluctuations distort an interface. It starts from some intrinsic surface h(x,y,t) that is distorted. Its energy will be proportional to its area: :E_\mathrm= \sigma \int dx\, dy\, \left sqrt-1\rightapprox \frac \int dx\, dy\, \left \left( \frac\right)^2+\left(\frac\right)^2 \right where the first equality is the area in this ( de Monge) representation, and the second applies for small values of the derivatives (surfaces not too rough). The constant of proportionality, \sigma, is the surface tension. By performing a Fourier analysis treatment, normal modes are easily found. Each contributes an energy proportional to the square of its amplitude; therefore, according to classical statistical mechanics, equipartition holds, and the ...
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Capillary Waves
A capillary wave is a wave traveling along the phase boundary of a fluid, whose dynamics and phase velocity are dominated by the effects of surface tension. Capillary waves are common in nature, and are often referred to as ripples. The wavelength of capillary waves on water is typically less than a few centimeters, with a phase speed in excess of 0.2–0.3 meter/second. A longer wavelength on a fluid interface will result in gravity–capillary waves which are influenced by both the effects of surface tension and gravity, as well as by fluid inertia. Ordinary gravity waves have a still longer wavelength. When generated by light wind in open water, a nautical name for them is cat's paw waves. Light breezes which stir up such small ripples are also sometimes referred to as cat's paws. On the open ocean, much larger ocean surface waves (seas and swells) may result from coalescence of smaller wind-caused ripple-waves. Dispersion relation The dispersion relation describes the ...
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Surface Tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play. One is an inward force on the surface molecules causing the liquid to contract. Second is a tangential force parallel to the surface of the liquid. This ''tangential'' force is generally referred to as the surface tension. The net effect is the liquid behaves as if its surface were covered with a stretched elastic membrane. But this analogy must not be taken too far as the tension in an elastic membrane is dependent on the amount of deformation of the m ...
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Thermal Fluctuations
In statistical mechanics, thermal fluctuations are random deviations of a system from its average state, that occur in a system at equilibrium.In statistical mechanics they are often simply referred to as fluctuations. All thermal fluctuations become larger and more frequent as the temperature increases, and likewise they decrease as temperature approaches absolute zero. Thermal fluctuations are a basic manifestation of the temperature of systems: A system at nonzero temperature does not stay in its equilibrium microscopic state, but instead randomly samples all possible states, with probabilities given by the Boltzmann distribution. Thermal fluctuations generally affect all the degrees of freedom of a system: There can be random vibrations (phonons), random rotations ( rotons), random electronic excitations, and so forth. Thermodynamic variables, such as pressure, temperature, or entropy, likewise undergo thermal fluctuations. For example, for a system that has an equilibriu ...
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Gaspard Monge
Gaspard Monge, Comte de Péluse (9 May 1746 – 28 July 1818) was a French mathematician, commonly presented as the inventor of descriptive geometry, (the mathematical basis of) technical drawing, and the father of differential geometry. During the French Revolution he served as the Minister of the Marine, and was involved in the reform of the French educational system, helping to found the École Polytechnique. Biography Early life Monge was born at Beaune, Côte-d'Or, the son of a merchant. He was educated at the college of the Oratorians at Beaune. In 1762 he went to the Collège de la Trinité at Lyon, where, one year after he had begun studying, he was made a teacher of physics at the age of just seventeen. After finishing his education in 1764 he returned to Beaune, where he made a large-scale plan of the town, inventing the methods of observation and constructing the necessary instruments; the plan was presented to the town, and is still preserved in their library. ...
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Fourier Analysis
In mathematics, Fourier analysis () is the study of the way general functions may be represented or approximated by sums of simpler trigonometric functions. Fourier analysis grew from the study of Fourier series, and is named after Joseph Fourier, who showed that representing a function as a sum of trigonometric functions greatly simplifies the study of heat transfer. The subject of Fourier analysis encompasses a vast spectrum of mathematics. In the sciences and engineering, the process of decomposing a function into oscillatory components is often called Fourier analysis, while the operation of rebuilding the function from these pieces is known as Fourier synthesis. For example, determining what component frequencies are present in a musical note would involve computing the Fourier transform of a sampled musical note. One could then re-synthesize the same sound by including the frequency components as revealed in the Fourier analysis. In mathematics, the term ''Fourier ...
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Capillary Wave
A capillary wave is a wave traveling along the phase boundary of a fluid, whose dynamics and phase velocity are dominated by the effects of surface tension. Capillary waves are common in nature, and are often referred to as ripples. The wavelength of capillary waves on water is typically less than a few centimeters, with a phase speed in excess of 0.2–0.3 meter/second. A longer wavelength on a fluid interface will result in gravity–capillary waves which are influenced by both the effects of surface tension and gravity, as well as by fluid inertia. Ordinary gravity waves have a still longer wavelength. When generated by light wind in open water, a nautical name for them is cat's paw waves. Light breezes which stir up such small ripples are also sometimes referred to as cat's paws. On the open ocean, much larger ocean surface waves (seas and swells) may result from coalescence of smaller wind-caused ripple-waves. Dispersion relation The dispersion relation describes ...
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Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ...
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