Thawing
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Thawing
Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or pressure, which increases the substance's temperature to the melting point. At the melting point, the ordering of ions or molecules in the solid breaks down to a less ordered state, and the solid "melts" to become a liquid. Substances in the molten state generally have reduced viscosity as the temperature increases. An exception to this principle is the element sulfur, whose viscosity increases in the range of 160 °C to 180 °C due to polymerization. Some organic compounds melt through mesophases, states of partial order between solid and liquid. First order phase transition From a thermodynamics point of view, at the melting point the change in Gibbs free energy ''∆G'' of the substances is zero, but there are non-zero changes in the enthalpy ...
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Melting Icecubes
Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or pressure, which increases the substance's temperature to the melting point. At the melting point, the ordering of ions or molecules in the solid breaks down to a less ordered state, and the solid "melts" to become a liquid. Substances in the molten state generally have reduced viscosity as the temperature increases. An exception to this principle is the element sulfur, whose viscosity increases in the range of 160 °C to 180 °C due to polymerization. Some organic compounds melt through mesophases, states of partial order between solid and liquid. First order phase transition From a thermodynamics point of view, at the melting point the change in Gibbs free energy ''∆G'' of the substances is zero, but there are non-zero changes in the enthalpy ( ...
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Gibbs Free Energy
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy change , measured in joules in SI) is the ''maximum'' amount of non-expansion work that can be extracted from a closed system (one that can exchange heat and work with its surroundings, but not matter) at fixed temperature and pressure. This maximum can be attained only in a completely reversible process. When a system transforms reversibly from an initial state to a final state under these conditions, the decrease in Gibbs free energy equals the work done by the system to its surroundings, minus the work of the pressure forces. The Gibbs energy is the thermodynamic potential that is minim ...
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Glass-liquid Transition
The glass–liquid transition, or glass transition, is the gradual and reversible transition in amorphous materials (or in amorphous regions within semicrystalline materials) from a hard and relatively brittle "glassy" state into a viscous or rubbery state as the temperature is increased. ISO 11357-2: Plastics – Differential scanning calorimetry – Part 2: Determination of glass transition temperature (1999). An amorphous solid that exhibits a glass transition is called a glass. The reverse transition, achieved by supercooling a viscous liquid into the glass state, is called vitrification. The glass-transition temperature ''T''g of a material characterizes the range of temperatures over which this glass transition occurs (as an experimental definition, typically marked as 100 s of relaxation time). It is always lower than the melting temperature, ''T''m, of the crystalline state of the material, if one exists. Hard plastics like polystyrene and poly(methyl methacrylate) are u ...
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Crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. The word ''crystal'' derives from the Ancient Greek word (), meaning both "ice" and "rock crystal", from (), "icy cold, frost". Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i.e. many microscopic crystals fused together into a single solid. Polycrystals include most metals, rocks, ceramics, and ice. A third category of ...
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Max Born
Max Born (; 11 December 1882 – 5 January 1970) was a German physicist and mathematician who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics and supervised the work of a number of notable physicists in the 1920s and 1930s. Born won the 1954 Nobel Prize in Physics for his "fundamental research in quantum mechanics, especially in the statistical interpretation of the wave function". Born entered the University of Göttingen in 1904, where he met the three renowned mathematicians Felix Klein, David Hilbert, and Hermann Minkowski. He wrote his PhD thesis on the subject of "Stability of Elastica in a Plane and Space", winning the university's Philosophy Faculty Prize. In 1905, he began researching special relativity with Minkowski, and subsequently wrote his habilitation thesis on the Thomson model of the atom. A chance meeting with Fritz Haber in Berlin in 1918 led to discussion of how an ionic compound is ...
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Frederick Lindemann, 1st Viscount Cherwell
Frederick Alexander Lindemann, 1st Viscount Cherwell, ( ; 5 April 18863 July 1957) was a British physicist who was prime scientific adviser to Winston Churchill in World War II. Lindemann was a brilliant intellectual, who cut through bureaucratic red tape that was hampering vital defence preparations against a German invasion. This caused sharp disagreements with many of the permanent bureaucracy. His contribution to Allied victory lay chiefly in embracing the art of the possible. He was particularly adept at converting data into clear charts to promote a strategy. His approach to technology focused on rapid experiments and fast failures, to come up with the proper answer; this made him at target for bureaucratic ire and accusations. He was involved in the development of radar and infra-red guidance systems. He was skeptical of the first reports of the enemy's V-weapons programme. He pressed the case for the strategic area bombing of cities. His abiding influence on Churc ...
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Helium-4
Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consists of two protons and two neutrons. Alpha decay of heavy elements in the Earth's crust is the source of most naturally occurring helium-4 on Earth, produced after the planet cooled and solidified. While it is also produced by nuclear fusion in stars, most helium-4 in the Sun and in the universe is thought to have been produced by the Big Bang, and is referred to as " primordial helium". However, primordial helium-4 is largely absent from the Earth, having escaped during the high-temperature phase of Earth's formation. Helium-4 makes up about one quarter of the ordinary matter in the universe by mass, with almost all of the rest being hydrogen. When liquid helium-4 is cooled to below , it becomes a superfluid, with properties that are ver ...
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Helium-3
Helium-3 (3He see also helion) is a light, stable isotope of helium with two protons and one neutron (the most common isotope, helium-4, having two protons and two neutrons in contrast). Other than protium (ordinary hydrogen), helium-3 is the only stable isotope of any element with more protons than neutrons. Helium-3 was discovered in 1939. Helium-3 occurs as a primordial nuclide, escaping from Earth's crust into its atmosphere and into outer space over millions of years. Helium-3 is also thought to be a natural nucleogenic and cosmogenic nuclide, one produced when lithium is bombarded by natural neutrons, which can be released by spontaneous fission and by nuclear reactions with cosmic rays. Some of the helium-3 found in the terrestrial atmosphere is also an artifact of atmospheric and underwater nuclear weapons testing. Much speculation has been made over the possibility of helium-3 as a future energy source. Unlike most nuclear fusion reactions, the fusion of helium-3 ...
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Helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling and melting point are the lowest among all the elements. It is the second lightest and second most abundant element in the observable universe (hydrogen is the lightest and most abundant). It is present at about 24% of the total elemental mass, which is more than 12 times the mass of all the heavier elements combined. Its abundance is similar to this in both the Sun and in Jupiter, due to the very high nuclear binding energy (per nucleon) of helium-4, with respect to the next three elements after helium. This helium-4 binding energy also accounts for why it is a product of both nuclear fusion and radioactive decay. The most common isotope of helium in the universe is helium-4, the vast majority of which was formed during t ...
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Phase Transition
In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point. Types of phase transition At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identic ...
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Entropy Of Fusion
In thermodynamics, the entropy of fusion is the increase in entropy when melting a solid substance. This is almost always positive since the degree of disorder increases in the transition from an organized crystalline solid to the disorganized structure of a liquid; the only known exception is helium. It is denoted as \Delta S_ and normally expressed in joules per mole-kelvin, J/(mol·K). A natural process such as a phase transition will occur when the associated change in the Gibbs free energy is negative. :\Delta G_ = \Delta H_ - T \times \Delta S_ < 0, where is the . Since this is a thermodynamic equation, the symbol refers to the absolute , measure ...
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Latent Heat
Latent heat (also known as latent energy or heat of transformation) is energy released or absorbed, by a body or a thermodynamic system, during a constant-temperature process — usually a first-order phase transition. Latent heat can be understood as energy in hidden form which is supplied or extracted to change the state of a substance without changing its temperature. Examples are latent heat of fusion and latent heat of vaporization involved in phase changes, i.e. a substance condensing or vaporizing at a specified temperature and pressure. The term was introduced around 1762 by Scottish chemist Joseph Black. It is derived from the Latin ''latere'' (''to lie hidden''). Black used the term in the context of calorimetry where a heat transfer caused a volume change in a body while its temperature was constant. In contrast to latent heat, sensible heat is energy transferred as heat, with a resultant temperature change in a body. Usage The terms ″sensible heat″ and ″laten ...
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