Thaumasite
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Thaumasite
Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca3 Si(O H)6( C O3)( SO4)·12 H2O, also sometimes more simply written as CaSiO3·CaCO3·CaSO4·15H2O. It occurs as colorless to white prismatic hexagonal crystals, typically as acicular radiating groups. It also occurs as fibrous masses. Its Mohs hardness is 3.5 and it has a specific gravity of 1.88 to 1.90. Optically it is uniaxial negative with indices of refraction of nω = 1.507 and nε = 1.468. It occurs as a hydrothermal alteration mineral in sulfide ore deposits and geothermal alteration of basalt and tuff. It occurs with zeolites, apophyllite, analcime, calcite, gypsum and pyrite. Thaumasite can also be formed in man-made concrete structures at the detriment of calcium silicate hydrates (C-S-H, with dashes denoting the non- stoichiometry of this hydrated cement phase acting as the "glue" in hardened cement paste) during cement alteration, especiall ...
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Sulfate Minerals
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal Vein (geology), veins and as secondary minerals in the Redox, oxidizing zone of sulfide mineral deposits. The Chromate ion, chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 **Anglesite PbSO4 **Anhydrite CaSO4 **Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O **Kieserite MgSO4·H2O **Starkeyite MgSO4·4H2O **Hexahydrite MgSO4·6H2O **Epsomite MgSO4·7H2O **Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O **Antlerite ...
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Calcium Silicate Hydrate
Calcium silicate hydrate (or C-S-H) is the main product of the hydration of Portland cement and is primarily responsible for the strength in cement based materials (e.g. concrete). Preparation When water is added to cement, each of the compounds undergoes hydration and contributes to the final state of the concrete. Only calcium silicates contribute to the strength. Tricalcium silicate is responsible for most of the early strength (first 7 days). Dicalcium silicate, which reacts more slowly, only contributes to late strength. Calcium silicate hydrate (also shown as C-S-H) is a result of the reaction between the silicate phases of Portland cement and water. This reaction typically is expressed as: : Tricalcium silicate + water -> Calcium silicate hydrate + Calcium hydroxide + heat The stoichiometry of C-S-H in cement paste is variable and the state of chemically and physically bound water in its structure is not transparent, which is why "-" is used between C, S, and H. Synthet ...
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Cement
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource. Cements used in construction are usually inorganic, often lime or calcium silicate based, which can be characterized as hydraulic or the less common non-hydraulic, depending on the ability of the cement to set in the presence of water (see hydraulic and non-hydraulic lime plaster). Hydraulic cements (e.g., Portland cement) set and become adhesive through a chemical reaction between the dry ingredients and water. The chemical reaction results in mineral hydrates that are not very water-soluble and so are quite durable in wa ...
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Stoichiometry
Stoichiometry refers to the relationship between the quantities of reactants and products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated. This is illustrated in the image here, where the balanced equation is: : Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water. This particular chemical equation is an example of complete combustion. St ...
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Concrete
Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminum combined. Globally, the ready-mix concrete industry, the largest segment of the concrete market, is projected to exceed $600 billion in revenue by 2025. This widespread use results in a number of environmental impacts. Most notably, the production process for cement produces large volumes of greenhouse gas emissions, leading to net 8% of global emissions. Other environmental concerns include widespread illegal sand mining, impacts on the surrounding environment such as increased surface runoff or urban heat island effect, and potential public health implications from toxic ingredients. Significant research and development is ...
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Pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), luster and pale brass-yellow hue give it a superficial resemblance to gold, hence the well-known nickname of ''fool's gold''. The color has also led to the nicknames ''brass'', ''brazzle'', and ''Brazil'', primarily used to refer to pyrite found in coal. The name ''pyrite'' is derived from the Greek language, Greek (), 'stone or mineral which strikes fire', in turn from (), 'fire'. In ancient Roman times, this name was applied to several types of stone that would create sparks when struck against steel; Pliny the Elder described one of them as being brassy, almost certainly a reference to what we now call pyrite. By Georgius Agricola's time, , the term had become a generic term for all of the pyrite group, sulfide minerals. Pyrite is usua ...
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Gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. Alabaster, a fine-grained white or lightly tinted variety of gypsum, has been used for sculpture by many cultures including Ancient Egypt, Mesopotamia, Ancient Rome, the Byzantine Empire, and the Nottingham alabasters of Medieval England. Gypsum also crystallizes as translucent crystals of selenite. It forms as an evaporite mineral and as a hydration product of anhydrite. The Mohs scale of mineral hardness defines gypsum as hardness value 2 based on scratch hardness comparison. Etymology and history The word ''gypsum'' is derived from the Greek word (), "plaster". Because the quarries of the Montmartre district of Paris have long furnished burnt gypsum (calcined gypsum) used for various purposes, this dehydrated gypsum became known ...
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Calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German ''Calcit'', a term from the 19th century that came from the Latin word for Lime (material), lime, ''calx'' (genitive calcis) with the suffix "-ite" used to name minerals. It is thus etymologically related to chalk. When applied by archaeology, archaeologists and stone trade pr ...
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Analcime
Analcime (; ) or analcite is a white, gray, or colorless tectosilicate mineral. Analcime consists of hydrated sodium aluminium silicate in cubic crystalline form. Its chemical formula is Na Al Si2 O6· H2O. Minor amounts of potassium and calcium substitute for sodium. A silver-bearing synthetic variety also exists (Ag-analcite). Analcime is usually classified as a zeolite mineral, but structurally and chemically it is more similar to the feldspathoids. Analcime occurs as a primary mineral in analcime basalt and other alkaline igneous rocks. It also occurs as cavity and vesicle fillings associated with prehnite, calcite, and zeolites. Locations Well known locations for sourcing analcime include Croft Quarry in Leicestershire, UK; the Cyclopean Islands east off Sicily and near Trentino in northern Italy; Victoria in Australia; Kerguelen Island in the Indian Ocean; in the Lake Superior copper district of Michigan, Bergen Hill, New Jersey, Golden, Colorado, and at Searles Lake, C ...
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Apophyllite
The name apophyllite refers to a specific group of phyllosilicates, a class of minerals. Originally, the group name referred to a specific mineral, but was redefined in 1978 to stand for a class of minerals of similar chemical makeup that comprise a solid solution series, and includes the members fluorapophyllite-(K), fluorapophyllite-(Na), hydroxyapophyllite-(K). The name apophyllite is derived from the Greek ἀποφυλλίζω ''apophylliso,'' meaning "it flakes off", a reference to this class's tendency to flake apart when heated, due to water loss. Exfoliation of apophyllite is also possible by treating it with acids or simply by rubbing it. These minerals are typically found as secondary minerals in vesicles in basalt or other volcanic rocks. A recent change (2008) in the nomenclature system used for this group was approved by the International Mineralogical Association, removing the prefixes from the species names and using suffixes to designate the species.Burke, E.A.J. ...
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Zeolite
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These positive ions can be exchanged for others in a contacting electrolyte solution. exchanged zeolites are particularly useful as solid acid catalysts. The term ''zeolite'' was originally coined in 1756 by Swedish mineralogist Axel Fredrik Cronstedt, who observed that rapidly heating a material, believed to have been stilbite, produced large amounts of steam from water that had been adsorbed by the material. Based on this, he called the material ''zeolite'', from the Greek , meaning "to boil" and , meaning "stone". Zeolites occur naturally but are also produced industrially on a large scale. , 253 unique zeolite frameworks have been identified, and over 40 naturally occurring zeolite frameworks are known. Every new zeolite structure that is ob ...
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