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Thallium
Thallium is a chemical element with the symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes and Claude-Auguste Lamy discovered thallium independently in 1861, in residues of sulfuric acid production. Both used the newly developed method of flame spectroscopy, in which thallium produces a notable green spectral line. Thallium, from Greek , , meaning "green shoot" or "twig", was named by Crookes. It was isolated by both Lamy and Crookes in 1862; Lamy by electrolysis, and Crookes by precipitation and melting of the resultant powder. Crookes exhibited it as a powder precipitated by zinc at the international exhibition, which opened on 1 May that year. Thallium tends to form the +3 and +1 oxidation states. The +3 state resembles that of the other elements in group 13 ( boron, aluminium, gallium, indium). However, the +1 state, which ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boron Group
The boron group are the chemical elements in group 13 of the periodic table, comprising boron (B), aluminium (Al), gallium (Ga), indium (In), thallium (Tl), and nihonium (Nh). The elements in the boron group are characterized by having three valence electrons. These elements have also been referred to as the triels. Boron is commonly classified as a (metalloid) while the rest, with the possible exception of nihonium, are considered post-transition metals. Boron occurs sparsely, probably because bombardment by the subatomic particles produced from natural radioactivity disrupts its nuclei. Aluminium occurs widely on earth, and indeed is the third most abundant element in the Earth's crust (8.3%). Gallium is found in the earth with an abundance of 13 ppm. Indium is the 61st most abundant element in the earth's crust, and thallium is found in moderate amounts throughout the planet. Nihonium is not known to occur in nature and therefore is termed a synthetic element. Several gro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Post-transition Metal
The metallic elements in the periodic table located between the transition metals and the chemically weak nonmetallic metalloids have received many names in the literature, such as ''post-transition metals'', ''poor metals'', ''other metals'', ''p-block metals'' and ''chemically weak metals''; none have been recommended by IUPAC. The most common name, ''post-transition metals'', is generally used in this article. Depending on where the adjacent sets of transition metals and metalloids are judged to begin and end, there are at least five competing proposals for which elements to count as post-transition metals: the three most common contain six, ten and thirteen elements, respectively (see image). All proposals include gallium, indium, tin, thallium, lead, and bismuth. Physically, these metals are soft (or brittle), have poor mechanical strength, and usually have melting points lower than those of the transition metals. Being close to the metal-nonmetal border, their crysta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
William Crookes
Sir William Crookes (; 17 June 1832 – 4 April 1919) was a British chemist and physicist who attended the Royal College of Chemistry, now part of Imperial College London, and worked on spectroscopy. He was a pioneer of vacuum tubes, inventing the Crookes tube which was made in 1875. This was a foundational discovery that eventually changed the whole of chemistry and physics. He is credited with discovering the element thallium, announced in 1861, with the help of spectroscopy. He was also the first to describe the spectrum of terrestrial helium, in 1865. Crookes was the inventor of the Crookes radiometer but did not discern the true explanation of the phenomenon he detected. Crookes also invented a 100% ultraviolet blocking sunglass lens. For a time, he was interested in spiritualism and became president of the Society for Psychical Research. Biography Crookes' life was one of unbroken scientific activity that extended over sixty-seven years. He was considered remarkabl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkali Metal
The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names for the elements in some languages, such as German and Russian. rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterised homologous behaviour. This family of elements is also known as the lithium family after its leading element. The alkali metals are all shiny, soft, highly reactive metals at standard temperature and pressure and readil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminium
Aluminium (aluminum in AmE, American and CanE, Canadian English) is a chemical element with the Symbol (chemistry), symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and Passivation (chemistry), forms a protective layer of Aluminium oxide, oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, Magnetism, non-magnetic and ductility, ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of Aluminum-26, 26Al is used in Radiometric dating, radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and h ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Indium
Indium is a chemical element with the symbol In and atomic number 49. Indium is the softest metal that is not an alkali metal. It is a silvery-white metal that resembles tin in appearance. It is a post-transition metal that makes up 0.21 parts per million of the Earth's crust. Indium has a melting point higher than sodium and gallium, but lower than lithium and tin. Chemically, indium is similar to gallium and thallium, and it is largely intermediate between the two in terms of its properties. Indium was discovered in 1863 by Ferdinand Reich and Hieronymous Theodor Richter by spectroscopic methods. They named it for the indigo blue line in its spectrum. Indium was isolated the next year. Indium is a minor component in zinc sulfide ores and is produced as a byproduct of zinc refinement. It is most notably used in the semiconductor industry, in low-melting-point metal alloys such as solders, in soft-metal high-vacuum seals, and in the production of transparent conduct ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rat Poison
Rodenticides are chemicals made and sold for the purpose of killing rodents. While commonly referred to as "rat poison", rodenticides are also used to kill mice, squirrels, woodchucks, chipmunks, porcupines, nutria, beavers, and voles. Despite the crucial roles that rodents play in nature, there are times when they need to be controlled. Some rodenticides are lethal after one exposure while others require more than one. Rodents are disinclined to gorge on an unknown food (perhaps reflecting an adaptation to their inability to vomit), preferring to sample, wait and observe whether it makes them or other rats sick. This phenomenon of poison shyness is the rationale for poisons that kill only after multiple doses. Besides being directly toxic to the mammals that ingest them, including dogs, cats, and humans, many rodenticides present a secondary poisoning risk to animals that hunt or scavenge the dead corpses of rats. Classes of rodenticides Anticoagulants Anticoagulants are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Claude-Auguste Lamy
Claude Auguste Lamy (; 15 June 1820 – 20 March 1878) was a French chemist who discovered the element thallium independently from William Crookes in 1862. Life Lamy was born in the commune of Ney in the department of Jura, France in 1820. He studied at the École Normale Supérieure, Paris. After he graduated from University in 1842 he became a teacher at Lille then at Limoges and again in Lille. In 1851 he received his Ph.D. In 1854 he became professor at the faculty of sciences of Lille (Université Lille Nord de France The Community of Universities and Institutions (COMUE) Lille Nord de France (formerly Université Lille Nord de France) was a French Groups of Universities and Institutions (COMUE) spread over multiple campuses and centered in Lille (North - Hauts- ...) and taught at École des arts industriels et des mines ( École centrale de Lille). In 1866 he changed to the École Centrale des Arts et Manufactures (École centrale de Paris). Lamy died in 1878. Re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inert Pair Effect
The inert-pair effect is the tendency of the two electrons in the outermost atomic ''s''-orbital to remain unshared in compounds of post-transition metals. The term ''inert-pair effect'' is often used in relation to the increasing stability of oxidation states that are two less than the group valency for the heavier elements of groups 13, 14, 15 and 16. The term "inert pair" was first proposed by Nevil Sidgwick in 1927. The name suggests that the outermost ''s'' electron pairs are more tightly bound to the nucleus in these atoms, and therefore more difficult to ionize or share. For example, the p-block elements of the 4th, 5th and 6th period come after d-block elements, but the electrons present in the intervening d- (and f-) orbitals do not effectively shield the s-electrons of the valence shell. As a result, the ''inert pair'' of ''n''s electrons remains more tightly held by the nucleus and hence participates less in bond formation. Description Consider as an example thalli ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Symbol (chemistry)
Chemical symbols are the abbreviations used in chemistry for chemical elements, functional groups and chemical compounds. Element symbols for chemical elements normally consist of one or two letters from the Latin alphabet and are written with the first letter capitalised. History Earlier symbols for chemical elements stem from classical Latin and Greek vocabulary. For some elements, this is because the material was known in ancient times, while for others, the name is a more recent invention. For example, Pb is the symbol for lead (''plumbum'' in Latin); Hg is the symbol for mercury (''hydrargyrum'' in Greek); and He is the symbol for helium (a new Latin name) because helium was not known in ancient Roman times. Some symbols come from other sources, like W for tungsten (''Wolfram'' in German) which was not known in Roman times. A three-letter temporary symbol may be assigned to a newly synthesized (or not yet synthesized) element. For example, "Uno" was the temporary symbol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gallium
Gallium is a chemical element with the symbol Ga and atomic number 31. Discovered by French chemist Paul-Émile Lecoq de Boisbaudran in 1875, Gallium is in group 13 of the periodic table and is similar to the other metals of the group ( aluminium, indium, and thallium). Elemental gallium is a soft, silvery metal in standard temperature and pressure. In its liquid state, it becomes silvery white. If too much force is applied, the gallium may fracture conchoidally. Since its discovery in 1875, gallium has widely been used to make alloys with low melting points. It is also used in semiconductors, as a dopant in semiconductor substrates. The melting point of gallium is used as a temperature reference point. Gallium alloys are used in thermometers as a non-toxic and environmentally friendly alternative to mercury, and can withstand higher temperatures than mercury. An even lower melting point of , well below the freezing point of water, is claimed for the alloy galinstan ( ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a nat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
