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Tetrakis(cyclopentadienyl)uranium(IV)
Tetrakis(cyclopentadienyl)uranium(IV), U(C5H5)4, abbreviated U(Cp)4, is an organouranium compound composed of a uranium atom sandwiched between four cyclopentadienide rings. Synthesis and properties Tetrakis(cyclopentadienyl)uranium(IV) was first prepared in 1962 by Ernst Otto Fischer, who reacted uranium tetrachloride Uranium tetrachloride is an inorganic compound, a salt of uranium and chlorine, with the formula UCl4. It is a hygroscopic olive-green solid. It was used in the electromagnetic isotope separation (EMIS) process of uranium enrichment. It is one o ... with excess potassium cyclopentadienide in benzene and obtained the complex as red crystals at 6% yield: :UCl4 + 4 KCp → U(Cp)4 + 4 KCl Solid crystals of U(Cp)4 are air-stable, but the benzene solution is extremely air-sensitive. Reduction of U(Cp)4 with uranium metal yields tris(cyclopentadienyl)uranium(III), U(Cp)3. References {{Authority control Organouranium compounds Metallocenes Cyclopentadienyl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organouranium Compounds
Organouranium chemistry is the science exploring the properties, structure and reactivity of organouranium compounds, which are organometallic compounds containing a carbon to uranium chemical bond. The field is of some importance to the nuclear industry and of theoretical interest in organometallic chemistry. History The development of organouranium compounds started in World War II when the Manhattan Project required volatile uranium compounds for 235U/238U isotope separation. For example, Henry Gilman attempted to synthesize compounds like tetramethyluranium, and others worked on uranium metal carbonyls, but none of the efforts met success due to organouranium instability. After the discovery of ferrocene in 1951, Todd Reynolds and Geoffrey Wilkinson in 1956 synthesized the uranium metallocene Cp3UCl from sodium cyclopentadienide and uranium tetrachloride as a stable but extremely air-sensitive compound. In it, the U-Cl bond is an ionic bond, while the bonds with ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organouranium Compound
Organouranium chemistry is the science exploring the properties, structure and reactivity of organouranium compounds, which are organometallic compounds containing a carbon to uranium chemical bond. The field is of some importance to the nuclear industry and of theoretical interest in organometallic chemistry. History The development of organouranium compounds started in World War II when the Manhattan Project required volatile uranium compounds for 235U/238U isotope separation. For example, Henry Gilman attempted to synthesize compounds like tetramethyluranium, and others worked on uranium metal carbonyls, but none of the efforts met success due to organouranium instability. After the discovery of ferrocene in 1951, Todd Reynolds and Geoffrey Wilkinson in 1956 synthesized the uranium metallocene Cp3UCl from sodium cyclopentadienide and uranium tetrachloride as a stable but extremely air-sensitive compound. In it, the U-Cl bond is an ionic bond, while the bonds with the three C ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclopentadienyl
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Cyclopentadienyl can refer to *Cyclopentadienyl anion, or cyclopentadienide, **Cyclopentadienyl ligand *Cyclopentadienyl radical, • *Cyclopentadienyl cation, See also *Pentadienyl In organic chemistry, pentadienyl refers to the organic radical, anion, or cation with the formula , where ''z'' = 0, −1, +1, respectively. Organometallic chemistry In organometallic chemistry, the pentadienyl anion is a ligand, the acyclic ana ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ernst Otto Fischer
Ernst Otto Fischer (; 10 November 1918 – 23 July 2007) was a German chemist who won the Nobel Prize for pioneering work in the area of organometallic chemistry. Early life He was born in Solln, a borough of Munich. His parents were Karl T. Fischer, Professor of Physics at the Technical University of Munich (TU), and Valentine née Danzer. He graduated in 1937 with ''Abitur''. Before the completion of two years' compulsory military service, the Second World War broke out, and he served in Poland, France, and Russia. During a period of study leave, towards the end of 1941 he began to study chemistry at the Technical University of Munich. Following the end of the War, he was released by the Americans in the autumn of 1945 and resumed his studies. Training Fischer graduated from TUM in 1949. He then started his doctoral thesis as an assistant to Professor Walter Hieber in the Inorganic Chemistry Institute, His thesis was entitled "The Mechanisms of Carbon Monoxide Reactions of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium Tetrachloride
Uranium tetrachloride is an inorganic compound, a salt of uranium and chlorine, with the formula UCl4. It is a hygroscopic olive-green solid. It was used in the electromagnetic isotope separation (EMIS) process of uranium enrichment. It is one of the main starting materials for organouranium chemistry. Synthesis and structure Uranium tetrachloride is synthesised generally by the reaction of uranium trioxide (UO3) and hexachloropropene. Solvent UCl4 adducts can be formed by a simpler reaction of UI4 with hydrogen chloride in organic solvents. According to X-ray crystallography the uranium centers are eight-coordinate, being surrounded by eight chlorine atoms, four at 264 pm and the other four at 287pm. Chemical properties Dissolution in protic solvents is more complicated. When UCl4 is added to water the uranium aqua ion is formed. :UCl4 + H2O → (H2O)sup>4+ + 4Cl− The aqua ion (H2O)sup>4+, (x is 8 or 9) is strongly hydrolyzed. : (H2O)sup>4+ (H2O)(OH)sup>3+ + H+ T ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organometallics
''Organometallics'' is a biweekly journal published by the American Chemical Society. Its area of focus is organometallic and organometalloid chemistry. This peer-reviewed journal has an impact factor of 3.837 as reported by the 2021 Journal Citation Reports by Thomson Reuters. Since 2015 Paul Chirik is the editor-in-chief of ''Organometallics''. He is an American chemist and the Edwards S. Sanford Professor of Chemistry at Princeton University, and associate director for external partnerships of the Andlinger Center for Energy and the Environment. He writes about the catalysis of hydrocarbons. Past editors-in-chief are Dietmar Seyferth and John Gladysz. Retrieved on 2014-07-30. This journal is indexed in |
Zeitschrift Für Naturforschung B
The ''Zeitschrift für Naturforschung B: A Journal of Chemical Sciences'' is a monthly peer-reviewed scientific journal. The journal publishes "fundamental studies in all areas of inorganic chemistry, organic chemistry, and analytical chemistry" in both English and German. Articles in German are required to be accompanied by an English-language title and abstract. According to the ''Journal Citation Reports'', the journal has a 2014 impact factor of 0.744. The editors-in-chief are Gerhard Müller (University of Konstanz) and Annette Schier (Technical University Munich). History The ''Zeitschrift für Naturforschung'' (English: ''Journal for Nature Research'') was established in 1946 by the Max Planck Institute Max or MAX may refer to: Animals * Max (dog) (1983–2013), at one time purported to be the world's oldest living dog * Max (English Springer Spaniel), the first pet dog to win the PDSA Order of Merit (animal equivalent of OBE) * Max (gorilla) (1 ... and the physical scie ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metallocenes
A metallocene is a compound typically consisting of two cyclopentadienyl anions (, abbreviated Cp) bound to a metal center (M) in the oxidation state II, with the resulting general formula Closely related to the metallocenes are the metallocene derivatives, e.g. titanocene dichloride, vanadocene dichloride. Certain metallocenes and their derivatives exhibit catalytic properties, although metallocenes are rarely used industrially. Cationic group 4 metallocene derivatives related to p2ZrCH3sup>+ catalyze olefin polymerization. Some metallocenes consist of metal plus two cyclooctatetraenide anions (, abbreviated cot2−), namely the lanthanocenes and the actinocenes (uranocene and others). Metallocenes are a subset of a broader class of compounds called sandwich compounds. In the structure shown at right, the two pentagons are the cyclopentadienyl anions with circles inside them indicating they are aromatically stabilized. Here they are shown in a staggered conformation. Hist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclopentadienyl Complexes
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Cyclopentadienyl can refer to *Cyclopentadienyl anion, or cyclopentadienide, **Cyclopentadienyl ligand *Cyclopentadienyl radical, • *Cyclopentadienyl cation, See also *Pentadienyl In organic chemistry, pentadienyl refers to the organic radical, anion, or cation with the formula , where ''z'' = 0, −1, +1, respectively. Organometallic chemistry In organometallic chemistry, the pentadienyl anion is a ligand, the acyclic ana ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium(IV) Compounds
Uranous is the chemical term for the reduced tetrapositive cation of uranium that exhibits the valence U4+. It is one of the two common ionic states of uranium found in nature, the other being the oxidised hexapositive ion called uranyl. Uranous compounds are usually unstable; they revert to the oxidised form on exposure to air. Examples of these compounds include uranium tetrachloride () and uranium tetrafluoride (), which are important in molten salt reactor applications, and uranium dioxide (), a common form of nuclear fuel. The solvated ion is normally not present in water. Most of the compounds like are better described with the covalent bond than an ionic bond. Minerals containing the uranous ion are more subdued in colour, typically brown or black, and occur in reducing environments. Common uranous minerals include uraninite and coffinite Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x. It occurs as black incrustations, dark to pale-br ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
