Tauc–Lorentz Model
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Tauc–Lorentz Model
The Tauc–Lorentz model is a mathematical formula for the frequency dependence of the complex-valued relative permittivity, sometimes referred to as the dielectric function. The model has been used to fit the complex refractive index of amorphous semiconductor materials at frequencies greater than their optical band gap. The dispersion relation bears the names of Jan Tauc and Hendrik Lorentz, whose previous works were combined by G. E. Jellison and F. A. Modine to create the model. The model was inspired, in part, by shortcomings of the Forouhi–Bloomer model, which is aphysical due to its incorrect asymptotic behavior and non-Hermitian character. Despite the inspiration, the Tauc–Lorentz model is itself aphysical due to being non-Hermitian and non-analytic in the upper half-plane. Further researchers have modified the model to address these shortcomings. Mathematical formulation The general form of the model is given by :\varepsilon(E) = \varepsilon_ + \chi^(E) where ...
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Photon Energy
Photon energy is the energy carried by a single photon. The amount of energy is directly proportional to the photon's electromagnetic frequency and thus, equivalently, is inversely proportional to the wavelength. The higher the photon's frequency, the higher its energy. Equivalently, the longer the photon's wavelength, the lower its energy. Photon energy can be expressed using any unit of energy. Among the units commonly used to denote photon energy are the electronvolt (eV) and the joule (as well as its multiples, such as the microjoule). As one joule equals 6.24 × 1018 eV, the larger units may be more useful in denoting the energy of photons with higher frequency and higher energy, such as gamma rays, as opposed to lower energy photons as in the optical and radio frequency regions of the electromagnetic spectrum. Formulas Physics Photon energy is directly proportional to frequency. E = hf where *E is energy *h is the Planck constant * f is frequency This equation is known ...
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Condensed Matter Physics
Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the subject deals with "condensed" phases of matter: systems of many constituents with strong interactions between them. More exotic condensed phases include the superconducting phase exhibited by certain materials at low temperature, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, and the Bose–Einstein condensate found in ultracold atomic systems. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other theories to develop mathematical models. The diversity of systems and phenomena available for study makes condensed matter phy ...
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Brendel–Bormann Oscillator Model
The Brendel–Bormann oscillator model is a mathematical formula for the frequency dependence of the complex-valued relative permittivity, sometimes referred to as the dielectric function. The model has been used to fit to the complex refractive index of materials with absorption lineshapes exhibiting non-Lorentzian broadening, such as metals and amorphous insulators, across broad spectral ranges, typically near- ultraviolet, visible, and infrared frequencies. The dispersion relation bears the names of R. Brendel and D. Bormann, who derived the model in 1992, despite first being applied to optical constants in the literature by Andrei M. Efimov and E. G. Makarova in 1983. Around that time, several other researchers also independently discovered the model. The Brendel-Bormann oscillator model is aphysical because it does not satisfy the Kramers–Kronig relations. The model is non-causal, due to a singularity at zero frequency, and non-Hermitian. These drawbacks inspired J. Or ...
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Sellmeier Equation
The Sellmeier equation is an empirical relationship between refractive index and wavelength for a particular transparent medium. The equation is used to determine the dispersion of light in the medium. It was first proposed in 1872 by Wolfgang Sellmeier and was a development of the work of Augustin Cauchy on Cauchy's equation for modelling dispersion. The equation In its original and the most general form, the Sellmeier equation is given as : n^2(\lambda) = 1 + \sum_i \frac , where ''n'' is the refractive index, ''λ'' is the wavelength, and ''B''i and ''C''i are experimentally determined ''Sellmeier coefficients''. These coefficients are usually quoted for λ in micrometres. Note that this λ is the vacuum wavelength, not that in the material itself, which is λ/n. A different form of the equation is sometimes used for certain types of materials, e.g. crystals. Each term of the sum representing an absorption resonance of strength ''B''i at a wavelength . For example, the coe ...
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Cauchy's Equation
In optics, Cauchy's transmission equation is an empirical relationship between the refractive index and wavelength of light for a particular transparent material. It is named for the mathematician Augustin-Louis Cauchy, who defined it in 1837. The equation The most general form of Cauchy's equation is : n(\lambda) = A + \frac + \frac + \cdots, where ''n'' is the refractive index, λ is the wavelength, ''A'', ''B'', ''C'', etc., are coefficients that can be determined for a material by fitting the equation to measured refractive indices at known wavelengths. The coefficients are usually quoted for λ as the vacuum wavelength in micrometres. Usually, it is sufficient to use a two-term form of the equation: : n(\lambda) = A + \frac, where the coefficients ''A'' and ''B'' are determined specifically for this form of the equation. A table of coefficients for common optical materials is shown below: The theory of light-matter interaction on which Cauchy based this equation ...
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Kramers–Kronig Relations
The Kramers–Kronig relations are bidirectional mathematical relations, connecting the real and imaginary parts of any complex function that is analytic in the upper half-plane. The relations are often used to compute the real part from the imaginary part (or vice versa) of response functions in physical systems, because for stable systems, causality implies the condition of analyticity, and conversely, analyticity implies causality of the corresponding stable physical system. The relation is named in honor of Ralph Kronig and Hans Kramers. In mathematics, these relations are known by the names Sokhotski–Plemelj theorem and Hilbert transform. Formulation Let \chi(\omega) = \chi_1(\omega) + i \chi_2(\omega) be a complex function of the complex variable \omega , where \chi_1(\omega) and \chi_2(\omega) are real. Suppose this function is analytic in the closed upper half-plane of \omega and vanishes faster than 1/, \omega, as , \omega, \to \infty. Slightly weaker conditi ...
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Lorentz Oscillator Model
The Lorentz oscillator model describes the optical response of bound charges. The model is named after the Dutch physicist Hendrik Antoon Lorentz. It is a classical, phenomenological model for materials with characteristic resonance frequencies (or other characteristic energy scales) for optical absorption, e.g. ionic and molecular vibrations, interband transitions (semiconductors), phonons, and collective excitations. Derivation of electron motion The model is derived by modeling an electron orbiting a massive, stationary nucleus as a spring-mass-damper system. The electron is modeled to be connected to the nucleus via a hypothetical spring and its motion is damped by via a hypothetical damper. The damping force ensures that the oscillator's response is finite at its resonance frequency. For a time-harmonic driving force which originates from the electric field, Newton’s second law can be applied to the electron to obtain the motion of the electron and expressions for t ...
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Electric Susceptibility
In electricity (electromagnetism), the electric susceptibility (\chi_; Latin: ''susceptibilis'' "receptive") is a dimensionless proportionality constant that indicates the degree of polarization of a dielectric material in response to an applied electric field. The greater the electric susceptibility, the greater the ability of a material to polarize in response to the field, and thereby reduce the total electric field inside the material(and store energy). It is in this way that the electric susceptibility influences the electric permittivity of the material and thus influences many other phenomena in that medium, from the capacitance of capacitors to the speed of light. Definition for linear dielectrics If a dielectric material is a linear dielectric, then electric susceptibility is defined as the constant of proportionality (which may be a matrix) relating an electric field E to the induced dielectric polarization density P such that \mathbf P =\varepsilon_0 \chi_, wher ...
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Angular Frequency
In physics, angular frequency "''ω''" (also referred to by the terms angular speed, circular frequency, orbital frequency, radian frequency, and pulsatance) is a scalar measure of rotation rate. It refers to the angular displacement per unit time (for example, in rotation) or the rate of change of the phase of a sinusoidal waveform (for example, in oscillations and waves), or as the rate of change of the argument of the sine function. Angular frequency (or angular speed) is the magnitude of the pseudovector quantity angular velocity.(UP1) One turn is equal to 2''π'' radians, hence \omega = \frac = , where: *''ω'' is the angular frequency (unit: radians per second), *''T'' is the period (unit: seconds), *''f'' is the ordinary frequency (unit: hertz) (sometimes ''ν''). Units In SI units, angular frequency is normally presented in radians per second, even when it does not express a rotational value. The unit hertz (Hz) is dimensionally equivalent, but by convention it ...
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Upper Half-plane
In mathematics, the upper half-plane, \,\mathcal\,, is the set of points in the Cartesian plane with > 0. Complex plane Mathematicians sometimes identify the Cartesian plane with the complex plane, and then the upper half-plane corresponds to the set of complex numbers with positive imaginary part: :\mathcal \equiv \ ~. The term arises from a common visualization of the complex number as the point in the plane endowed with Cartesian coordinates. When the  axis is oriented vertically, the "upper half-plane" corresponds to the region above the  axis and thus complex numbers for which  > 0. It is the domain of many functions of interest in complex analysis, especially modular forms. The lower half-plane, defined by   0. Proposition: Let ''A'' and ''B'' be semicircles in the upper half-plane with centers on the boundary. Then there is an affine mapping that takes ''A'' to ''B''. :Proof: First shift the center of ''A'' to (0,0). Then take λ = (diame ...
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Relative Permittivity
The relative permittivity (in older texts, dielectric constant) is the permittivity of a material expressed as a ratio with the electric permittivity of a vacuum. A dielectric is an insulating material, and the dielectric constant of an insulator measures the ability of the insulator to store electric energy in an electrical field. Permittivity is a material's property that affects the Coulomb force between two point charges in the material. Relative permittivity is the factor by which the electric field between the charges is decreased relative to vacuum. Likewise, relative permittivity is the ratio of the capacitance of a capacitor using that material as a dielectric, compared with a similar capacitor that has vacuum as its dielectric. Relative permittivity is also commonly known as the dielectric constant, a term still used but deprecated by standards organizations in engineering as well as in chemistry. Definition Relative permittivity is typically denoted as (sometimes ...
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