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Transfer-matrix Method
In statistical mechanics, the transfer-matrix method is a Mathematical physics, mathematical technique which is used to write the Partition function (mathematics), partition function into a simpler form. It was introduced in 1941 by Hans Kramers and Gregory Wannier. In many one dimensional Lattice model (physics), lattice models, the partition function is first written as an ''n''-fold summation over each possible Microstate (statistical mechanics), microstate, and also contains an additional summation of each component's contribution to the energy of the system within each microstate. Overview Higher dimensional models contain even more summations. For systems with more than a few particles, such expressions can quickly become too complex to work out directly, even by computer. Instead, the partition function can be rewritten in an equivalent way. The basic idea is to write the partition function (mathematics), partition function in the form : \mathcal = \mathbf_0 \cdot \left ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ising Model
The Ising model () (or Lenz-Ising model or Ising-Lenz model), named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent magnetic dipole moments of atomic "spins" that can be in one of two states (+1 or −1). The spins are arranged in a graph, usually a lattice (where the local structure repeats periodically in all directions), allowing each spin to interact with its neighbors. Neighboring spins that agree have a lower energy than those that disagree; the system tends to the lowest energy but heat disturbs this tendency, thus creating the possibility of different structural phases. The model allows the identification of phase transitions as a simplified model of reality. The two-dimensional square-lattice Ising model is one of the simplest statistical models to show a phase transition. The Ising model was invented by the physicist , who gave it as a prob ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transfer Operator
Transfer may refer to: Arts and media * ''Transfer'' (2010 film), a German science-fiction movie directed by Damir Lukacevic and starring Zana Marjanović * ''Transfer'' (1966 film), a short film * ''Transfer'' (journal), in management studies * "The Transfer" (''Smash''), a television episode *''The Transfer'', a novel by Silvano Ceccherini Finance * Transfer payment, a redistribution of income and wealth by means of the government making a payment * Balance transfer, transfer of the balance (either of money or credit) in an account to another account * Money transfer (other) ** Wire transfer, an international expedited bank-to-bank funds transfer Science and technology Learning and psychology * Transfer (propaganda), a method of psychological manipulation * Knowledge transfer, within organizations * Language transfer, in which native-language grammar and pronunciation influence the learning and use of a second language * Transfer of learning, in education Mathematic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lars Onsager
Lars Onsager (November 27, 1903 – October 5, 1976) was a Norwegian-born American physical chemist and theoretical physicist. He held the Gibbs Professorship of Theoretical Chemistry at Yale University. He was awarded the Nobel Prize in Chemistry in 1968. Education and early life Lars Onsager was born in Kristiania (now Oslo), Norway. His father was a lawyer. After completing secondary school in Oslo, he attended the Norwegian Institute of Technology (NTH) in Trondheim, graduating as a chemical engineer in 1925. Career and research In 1925 he arrived at a correction to the Debye-Hückel theory of electrolytic solutions, to specify Brownian movement of ions in solution, and during 1926 published it. He traveled to Zürich, where Peter Debye was teaching, and confronted Debye, telling him his theory was wrong. He impressed Debye so much that he was invited to become Debye's assistant at the Eidgenössische Technische Hochschule (ETH), where he remained until 1928. Johns ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lifson–Roig Model
In polymer science, the Lifson–Roig model is a helix-coil transition model applied to the alpha helix-random coil transition of polypeptides; it is a refinement of the Zimm–Bragg model that recognizes that a polypeptide alpha helix is only stabilized by a hydrogen bond only once three consecutive residues have adopted the helical conformation. To consider three consecutive residues each with two states (helix and coil), the Lifson–Roig model uses a 4x4 transfer matrix instead of the 2x2 transfer matrix of the Zimm–Bragg model, which considers only two consecutive residues. However, the simple nature of the coil state allows this to be reduced to a 3x3 matrix for most applications. The Zimm–Bragg and Lifson–Roig models are but the first two in a series of analogous transfer-matrix methods in polymer science that have also been applied to nucleic acids and branched polymers. The transfer-matrix approach is especially elegant for homopolymers, since the statistical mecha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zimm–Bragg Model
In statistical mechanics, the Zimm–Bragg model is a helix-coil transition model that describes helix-coil transitions of macromolecules, usually polymer chains. Most models provide a reasonable approximation of the fractional helicity of a given polypeptide; the Zimm–Bragg model differs by incorporating the ease of propagation (self-replication) with respect to nucleation. It is named for co-discoverers Bruno H. Zimm and J. K. Bragg. Helix-coil transition models Helix-coil transition models assume that polypeptides are linear chains composed of interconnected segments. Further, models group these sections into two broad categories: ''coils'', random conglomerations of disparate unbound pieces, are represented by the letter 'C', and ''helices'', ordered states where the chain has assumed a structure stabilized by hydrogen bonding, are represented by the letter 'H'. Thus, it is possible to loosely represent a macromolecule as a string such as CCCCHCCHCHHHHHCHCCC and so forth. T ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Weight
In statistical mechanics, multiplicity (also called statistical weight) refers to the number of microstates corresponding to a particular macrostate of a thermodynamic system. Commonly denoted \Omega, it is related to the configuration entropy of an isolated system via Boltzmann's entropy formula S = k_\text \log \Omega, where S is the entropy and k_\text = 1.38\cdot 10^ \, \mathrm is Boltzmann's constant The Boltzmann constant ( or ) is the proportionality factor that relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin and the gas constant .... Example: the two-state paramagnet A simplified model of the two-state paramagnet provides an example of the process of calculating the multiplicity of particular macrostate. This model consists of a system of N microscopic dipoles \mu which may either be aligned or anti-aligned with an externally applied magnetic field B. Let ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin (physics)
Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nucleus, atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbital angular momentum operator is the quantum-mechanical counterpart to the classical angular momentum of orbital revolution and appears when there is periodic structure to its wavefunction as the angle varies. For photons, spin is the quantum-mechanical counterpart of the Polarization (waves), polarization of light; for electrons, the spin has no classical counterpart. The existence of electron spin angular momentum is inferred from experiments, such as the Stern–Gerlach experiment, in which silver atoms were observed to possess two possible discrete angular momenta despite having no orbital angular momentum. The existence of the electron spin can also be inferred theoretically from the spin–statistics theorem and from th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mathematical Physics
Mathematical physics refers to the development of mathematics, mathematical methods for application to problems in physics. The ''Journal of Mathematical Physics'' defines the field as "the application of mathematics to problems in physics and the development of mathematical methods suitable for such applications and for the formulation of physical theories". An alternative definition would also include those mathematics that are inspired by physics (also known as physical mathematics). Scope There are several distinct branches of mathematical physics, and these roughly correspond to particular historical periods. Classical mechanics The rigorous, abstract and advanced reformulation of Newtonian mechanics adopting the Lagrangian mechanics and the Hamiltonian mechanics even in the presence of constraints. Both formulations are embodied in analytical mechanics and lead to understanding the deep interplay of the notions of symmetry (physics), symmetry and conservation law, con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eigenanalysis
In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denoted by \lambda, is the factor by which the eigenvector is scaled. Geometrically, an eigenvector, corresponding to a real nonzero eigenvalue, points in a direction in which it is stretched by the transformation and the eigenvalue is the factor by which it is stretched. If the eigenvalue is negative, the direction is reversed. Loosely speaking, in a multidimensional vector space, the eigenvector is not rotated. Formal definition If is a linear transformation from a vector space over a field into itself and is a nonzero vector in , then is an eigenvector of if is a scalar multiple of . This can be written as T(\mathbf) = \lambda \mathbf, where is a scalar in , known as the eigenvalue, characteristic value, or characteristic root ass ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
