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Tetramethyl Bisphenol F
Tetramethyl bisphenol F (TMBPF) is a new coating intended as a safer replacement for bisphenol A and bisphenol F to use in epoxy linings of aluminium cans and steel can A steel can, tin can, tin (especially in British English, Australian English, Canadian English and South African English), steel packaging, or can is a container for the distribution or storage of goods, made of thin metal. Many cans re ...s. It was previously suggested as an insulator in electronic circuit boards. Polymerisation of tetramethyl bisphenol F occurs with epichlorohydrin when heated between 40 and 70 °C using an alkali as a catalyst to form the resin used as a coating. Health and Environmental Effects Causes serious eye irritation. May cause respiratory and skin irritation. Very toxic to aquatic life. Human Endocrine Effects According to tests TMBPF does not have any effect on the endocrine system; it does not leach out of cans because unlike BPA it is fully polymerized when dep ...
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Coating
A coating is a covering that is applied to the surface of an object, usually referred to as the Substrate (materials science), substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquids, gases or solids e.g. Powder coatings. Paints and lacquers are coatings that mostly have dual uses of protecting the substrate and being decorative, although some artists paints are only for decoration, and the paint on large industrial pipes is for preventing corrosion and identification e.g. blue for process water, red for fire-fighting control etc. Functional coatings may be applied to change the surface properties of the substrate, such as adhesion, Wetting, wettability, corrosion resistance, or wear resistance. In other cases, e.g. semiconductor device fabrication (where the substrate is a wafer (electronics), wafer), the coating adds a completely new property, such as a magnetic response or electrical conductivity, and forms an e ...
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Bisphenol A
Bisphenol A (BPA) is a chemical compound primarily used in the manufacturing of various plastics. It is a colourless solid which is soluble in most common organic solvents, but has very poor solubility in water. BPA is produced on an industrial scale by the condensation of phenol and acetone, and has a global production scale which is expected to reach 10 million tonnes in 2022. BPA's largest single application is as a co-monomer in the production of polycarbonates, which accounts for 65–70% of all BPA production. The manufacturing of epoxy resins and vinyl ester resins account for 25–30% of BPA use. The remaining 5% is used as a major component of several high-performance plastics, and as a minor additive in PVC, polyurethane, thermal paper, and several other materials. It is not a plasticizer, although it is often wrongly labelled as such. The health effects of BPA have been the subject of prolonged public and scientific debate. BPA is a xenoestrogen, exhibiting hormone ...
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Bisphenol F
Bisphenol F (BPF; 4,4′-dihydroxydiphenylmethane) is an organic compound with the chemical formula . It is structurally related to bisphenol A (BPA), a popular precursor for forming plastics, as both belong to the category of molecules known as bisphenols, which feature two phenol groups connected via a linking group. In BPF, the two aromatic rings are linked by a methylene connecting group. In response to concern about the health effects of BPA, BPF is increasingly used as a substitute for BPA. Uses BPF is used in the manufacture of plastics and epoxy resins. It is used in the production of tank and pipe linings, industrial flooring, road and bridge deck toppings, structural adhesives, grouts, coatings and electrical varnishes. BPF is also utilized in liners, lacquers, adhesives, plastics, and the coating of drinks and food cans. BPF is found in dental materials, such as restorative materials, liners, adhesives, oral prosthetic devices and tissue substitutes. Biological effec ...
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Aluminium Can
An Aluminum can (British English: Tin can) is a single-use container for packaging made primarily of aluminum. It is commonly used for food and beverages such as milk and soup but also for products such as oil, chemicals, and other liquids. Global production is 180 billion annually and constitutes the largest single use of aluminum globally. Usage Use of aluminum in cans began in 1957. Aluminum offers greater malleability, resulting in ease of manufacture; this gave rise to the two-piece can, where all but the top of the can is simply stamped out of a single piece of aluminum, rather than constructed from two pieces of steel. The inside of the can is lined by spray coating an epoxy lacquer or polymer to protect the aluminum from being corroded by acidic contents such as carbonated beverages and imparting a metallic taste to the beverage. The epoxy may contain bisphenol A. A label is either printed directly on the side of the can or will be glued to the outside of the curved surfa ...
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Steel Can
A steel can, tin can, tin (especially in British English, Australian English, Canadian English and South African English), steel packaging, or can is a container for the distribution or storage of goods, made of thin metal. Many cans require opening by cutting the "end" open; others have removable covers. They can store a broad variety of contents: food, beverages, oil, chemicals, etc. Steel cans are made of tinplate (tin-coated steel) or of tin-free steel. In some dialects, even aluminium cans are called "tin cans". Steel cans are highly recyclable, unlike materials like plastic, with around 65% of steel cans being recycled. History The tin canning process was conceived by the Frenchman Philippe de Girard, who got a British merchant Peter Durand to patent the idea in 1810. The canning concept was based on experimental food preservation work in glass containers the year before by the French inventor Nicholas Appert. Durand did not pursue food canning, but, in 1812, ...
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Epichlorohydrin
Epichlorohydrin (abbreviated ECH) is an organochlorine compound and an epoxide. Despite its name, it is not a halohydrin. It is a colorless liquid with a pungent, garlic-like odor, moderately soluble in water, but miscible with most polar organic solvents. It is a chiral molecule generally existing as a racemic mixture of right-handed and left-handed enantiomers. Epichlorohydrin is a highly reactive electrophilic compound and is used in the production of glycerol, plastics, epoxy glues and resins, epoxy diluents and elastomers. Production Epichlorohydrin is traditionally manufactured from allyl chloride in two steps, beginning with the addition of hypochlorous acid, which affords a mixture of two isomeric alcohols: : In the second step, this mixture is treated with base to give the epoxide: : In this way, more than 800,000 tons (1997) of epichlorohydrin are produced annually. Glycerol routes Epichlorohydrin was first described in 1848 by Marcellin Berthelot. The comp ...
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Google Patents
Google Patents is a search engine from Google that indexes patents and patent applications. Contents Google Patents indexes more than 87 million patents and patent applications with full text from 17 patent offices, including: * United States Patent and Trademark Office (USPTO), * European Patent Office (EPO), * China's National Intellectual Property Administration (CNIPA), * Japan Patent Office (JPO), * Korean Intellectual Property Office (KIPO), * World Intellectual Property Organization (WIPO), * Deutsches Patent- und Markenamt (DPMA), * Canadian Intellectual Property Office (CIPO), * Rospatent, * Intellectual Property Office (United Kingdom), * National Institute of Industrial Property (France), * the Netherlands Patent Office, * offices of Spain, Belgium, Denmark, Finland, and Luxembourg. These documents include the entire collection of granted patents and published patent applications from each database (which belong to the public domain). US patent documents date back to ...
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Commodity Chemicals
Commodity chemicals (or bulk commodities or bulk chemicals) are a group of chemicals that are made on a very large scale to satisfy global markets. The average prices of commodity chemicals are regularly published in the chemical trade magazines and web sites such aChemical WeekanICIS There have been several studies of the scale and complexity of this market for example in the USA. Commodity chemicals are a sub-sector of the chemical industry (other sub sectors are fine chemicals, specialty chemicals, inorganic chemicals, petrochemicals, pharmaceuticals, renewable energy (e.g. biofuels) and materials (e.g. biopolymers)) Commodity chemicals are differentiated primarily by the bulk of their manufacture. Types Chemical compounds are often classified into two classes, inorganic and organic. Inorganic chemicals * aluminium sulfate * ammonia * ammonium nitrate * ammonium sulfate * carbon black * chlorine * diammonium phosphate * monoammonium phosphate * hydrochloric acid * hydrogen fl ...
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Coatings
A coating is a covering that is applied to the surface of an object, usually referred to as the substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquids, gases or solids e.g. Powder coatings. Paints and lacquers are coatings that mostly have dual uses of protecting the substrate and being decorative, although some artists paints are only for decoration, and the paint on large industrial pipes is for preventing corrosion and identification e.g. blue for process water, red for fire-fighting control etc. Functional coatings may be applied to change the surface properties of the substrate, such as adhesion, wettability, corrosion resistance, or wear resistance. In other cases, e.g. semiconductor device fabrication (where the substrate is a wafer), the coating adds a completely new property, such as a magnetic response or electrical conductivity, and forms an essential part of the finished product. A major consideratio ...
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