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Symmetry Element
In chemistry and crystallography, a symmetry element is a point, line, or plane about which symmetry operations can take place. In particular, a symmetry element can be a mirror plane, an axis of rotation (either proper and improper), or a center of inversion. For an object such as a molecule or a crystal, a symmetry element corresponds to a set of symmetry operations, which are the rigid transformations employing the symmetry element that leave the object unchanged. The set containing these operations form one of the symmetry groups of the object. The elements of this symmetry group should not to be confused with the "symmetry element" itself. Loosely, a symmetry element is the geometric set of fixed points of a symmetry operation. For example, for rotation about an axis, the points on the axis do not move and in a reflection the points that remain unchanged make up a plane of symmetry. Identity The identity symmetry element is found in all objects and is denoted ''E''. It corre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Symmetry Operation
In group theory, geometry, representation theory and molecular symmetry, a symmetry operation is a transformation of an object that leaves an object looking the same after it has been carried out. For example, as transformations of an object in space, rotations, reflections and inversions are all symmetry operations. Such symmetry operations are performed with respect to symmetry elements (for example, a point, line or plane). In the context of molecular symmetry, a symmetry operation is a permutation of atoms such that the molecule or crystal is transformed into a state indistinguishable from the starting state. Two basic facts follow from this definition, which emphasizes its usefulness. # Physical properties must be invariant with respect to symmetry operations. # Symmetry operations can be collected together in groups which are isomorphic to permutation groups. In the context of molecular symmetry, quantum wavefunctions need not be invariant, because the operation can multiply th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rigid Transformation
In mathematics, a rigid transformation (also called Euclidean transformation or Euclidean isometry) is a geometric transformation of a Euclidean space that preserves the Euclidean distance between every pair of points. The rigid transformations include rotations, translations, reflections, or any sequence of these. Reflections are sometimes excluded from the definition of a rigid transformation by requiring that the transformation also preserve the handedness of objects in the Euclidean space. (A reflection would not preserve handedness; for instance, it would transform a left hand into a right hand.) To avoid ambiguity, a transformation that preserves handedness is known as a proper rigid transformation, or rototranslation. Any proper rigid transformation can be decomposed into a rotation followed by a translation, while any improper rigid transformation can be decomposed into an improper rotation followed by a translation, or into a sequence of reflections. Any object wil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Symmetry Group
In group theory, the symmetry group of a geometric object is the group of all transformations under which the object is invariant, endowed with the group operation of composition. Such a transformation is an invertible mapping of the ambient space which takes the object to itself, and which preserves all the relevant structure of the object. A frequent notation for the symmetry group of an object ''X'' is ''G'' = Sym(''X''). For an object in a metric space, its symmetries form a subgroup of the isometry group of the ambient space. This article mainly considers symmetry groups in Euclidean geometry, but the concept may also be studied for more general types of geometric structure. Introduction We consider the "objects" possessing symmetry to be geometric figures, images, and patterns, such as a wallpaper pattern. For symmetry of physical objects, one may also take their physical composition as part of the pattern. (A pattern may be specified formally as a scalar field, a funct ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fixed Point (mathematics)
A fixed point (sometimes shortened to fixpoint, also known as an invariant point) is a value that does not change under a given transformation. Specifically, in mathematics, a fixed point of a function is an element that is mapped to itself by the function. In physics, the term fixed point can refer to a temperature that can be used as a reproducible reference point, usually defined by a phase change or triple point. Fixed point of a function Formally, is a fixed point of a function if belongs to both the domain and the codomain of , and . For example, if is defined on the real numbers by f(x) = x^2 - 3 x + 4, then 2 is a fixed point of , because . Not all functions have fixed points: for example, , has no fixed points, since is never equal to for any real number. In graphical terms, a fixed point means the point is on the line , or in other words the graph of has a point in common with that line. Fixed-point iteration In numerical analysis, ''fixed-point iter ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
XeF4 Molecule
Xenon tetrafluoride is a chemical compound with chemical formula . It was the first discovered binary compound of a noble gas. It is produced by the chemical reaction of xenon with fluorine: : Xe + 2 → This reaction is exothermic, releasing an energy of 251 kJ/mol. Xenon tetrafluoride is a colorless crystalline solid that sublimes at 117 °C. Its structure was determined by both NMR spectroscopy and X-ray crystallography in 1963. The structure is square planar, as has been confirmed by neutron diffraction studies. According to VSEPR theory, in addition to four fluoride ligands, the xenon center has two lone pairs of electrons. These lone pairs are mutually ''trans''. Synthesis Xenon tetrafluoride is produced by heating a mixture of xenon and fluorine in a 1:5 molar ratio in a nickel container to 400 °C. Some xenon difluoride () and xenon hexafluoride () is also produced, where increased temperature or decreased fluorine concentration in the input ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclic Group
In group theory, a branch of abstract algebra in pure mathematics, a cyclic group or monogenous group is a group, denoted C''n'', that is generated by a single element. That is, it is a set of invertible elements with a single associative binary operation, and it contains an element ''g'' such that every other element of the group may be obtained by repeatedly applying the group operation to ''g'' or its inverse. Each element can be written as an integer power of ''g'' in multiplicative notation, or as an integer multiple of ''g'' in additive notation. This element ''g'' is called a ''generator'' of the group. Every infinite cyclic group is isomorphic to the additive group of Z, the integers. Every finite cyclic group of order ''n'' is isomorphic to the additive group of Z/''n''Z, the integers modulo ''n''. Every cyclic group is an abelian group (meaning that its group operation is commutative), and every finitely generated abelian group ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Improper Rotation
In geometry, an improper rotation,. also called rotation-reflection, rotoreflection, rotary reflection,. or rotoinversion is an isometry in Euclidean space that is a combination of a rotation about an axis and a reflection in a plane perpendicular to that axis. Reflection and inversion are each special case of improper rotation. Any improper rotation is an affine transformation and, in cases that keep the coordinate origin fixed, a linear transformation.. It is used as a symmetry operation in the context of geometric symmetry, molecular symmetry and crystallography, where an object that is unchanged by a combination of rotation and reflection is said to have ''improper rotation symmetry''. Three dimensions In 3 dimensions, improper rotation is equivalently defined as a combination of rotation about an axis and inversion in a point on the axis. For this reason it is also called a rotoinversion or rotary inversion. The two definitions are equivalent because rotation by an angle ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferrocene
Ferrocene is an organometallic compound with the formula . The molecule is a complex consisting of two cyclopentadienyl rings bound to a central iron atom. It is an orange solid with a camphor-like odor, that sublimes above room temperature, and is soluble in most organic solvents. It is remarkable for its stability: it is unaffected by air, water, strong bases, and can be heated to 400 °C without decomposition. In oxidizing conditions it can reversibly react with strong acids to form the ferrocenium cation . The rapid growth of organometallic chemistry is often attributed to the excitement arising from the discovery of ferrocene and its many analogues, such as metallocenes. History Discovery Ferrocene was discovered by accident thrice. The first known synthesis may have been made in the late 1940s by unknown researchers at Union Carbide, who tried to pass hot cyclopentadiene vapor through an iron pipe. The vapor reacted with the pipe wall, creating a "yellow sludg ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Symmetry
Symmetry (from grc, συμμετρία "agreement in dimensions, due proportion, arrangement") in everyday language refers to a sense of harmonious and beautiful proportion and balance. In mathematics, "symmetry" has a more precise definition, and is usually used to refer to an object that is invariant under some transformations; including translation, reflection, rotation or scaling. Although these two meanings of "symmetry" can sometimes be told apart, they are intricately related, and hence are discussed together in this article. Mathematical symmetry may be observed with respect to the passage of time; as a spatial relationship; through geometric transformations; through other kinds of functional transformations; and as an aspect of abstract objects, including theoretic models, language, and music. This article describes symmetry from three perspectives: in mathematics, including geometry, the most familiar type of symmetry for many people; in science and nature ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Group Theory
In abstract algebra, group theory studies the algebraic structures known as group (mathematics), groups. The concept of a group is central to abstract algebra: other well-known algebraic structures, such as ring (mathematics), rings, field (mathematics), fields, and vector spaces, can all be seen as groups endowed with additional operation (mathematics), operations and axioms. Groups recur throughout mathematics, and the methods of group theory have influenced many parts of algebra. Linear algebraic groups and Lie groups are two branches of group theory that have experienced advances and have become subject areas in their own right. Various physical systems, such as crystals and the hydrogen atom, and Standard Model, three of the four known fundamental forces in the universe, may be modelled by symmetry groups. Thus group theory and the closely related representation theory have many important applications in physics, chemistry, and materials science. Group theory is also ce ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystallography
Crystallography is the experimental science of determining the arrangement of atoms in crystalline solids. Crystallography is a fundamental subject in the fields of materials science and solid-state physics (condensed matter physics). The word "crystallography" is derived from the Greek word κρύσταλλος (''krystallos'') "clear ice, rock-crystal", with its meaning extending to all solids with some degree of transparency, and γράφειν (''graphein'') "to write". In July 2012, the United Nations recognised the importance of the science of crystallography by proclaiming that 2014 would be the International Year of Crystallography. denote a direction vector (in real space). * Coordinates in ''angle brackets'' or ''chevrons'' such as <100> denote a ''family'' of directions which are related by symmetry operations. In the cubic crystal system for example, would mean 00 10 01/nowiki> or the negative of any of those directions. * Miller indices in ''parentheses'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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