Surface Phonon
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Surface Phonon
In solid state physics, a surface phonon is the quantum of a lattice vibration mode associated with a solid surface. Similar to the ordinary lattice vibrations in a bulk solid (whose quanta are simply called phonons), the nature of surface vibrations depends on details of periodicity and symmetry of a crystal structure. Surface vibrations are however distinct from the bulk vibrations, as they arise from the abrupt termination of a crystal structure at the surface of a solid. Knowledge of surface phonon dispersion gives important information related to the amount of surface relaxation, the existence and distance between an adsorbate and the surface, and information regarding presence, quantity, and type of defects existing on the surface.J. Szeftel, "Surface phonon dispersion, using electron energy loss spectroscopy," ''Surface Science'', 152/153 (1985) 797–810, In modern semiconductor research, surface vibrations are of interest as they can couple with electrons and thereby ...
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Lattice Wave
Lattice may refer to: Arts and design * Latticework, an ornamental criss-crossed framework, an arrangement of crossing laths or other thin strips of material * Lattice (music), an organized grid model of pitch ratios * Lattice (pastry), an ornamental pattern of crossing strips of pastry Companies * Lattice Engines, a technology company specializing in business applications for marketing and sales * Lattice Group, a former British gas transmission business * Lattice Semiconductor, a US-based integrated circuit manufacturer Science, technology, and mathematics Mathematics * Lattice (group), a repeating arrangement of points ** Lattice (discrete subgroup), a discrete subgroup of a topological group whose quotient carries an invariant finite Borel measure ** Lattice (module), a module over a ring which is embedded in a vector space over a field ** Lattice graph, a graph that can be drawn within a repeating arrangement of points ** Lattice-based cryptography, encryption systems ...
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CdSe
Cadmium selenide is an inorganic compound with the formula Cd Se. It is a black to red-black solid that is classified as a II-VI semiconductor of the n-type. Much of the current research on this compound is focused on its nanoparticles. Structure Three crystalline forms of CdSe are known which follow the structures of: wurtzite (hexagonal), sphalerite (cubic) and rock-salt (cubic). The sphalerite CdSe structure is unstable and converts to the wurtzite form upon moderate heating. The transition starts at about 130 °C, and at 700 °C it completes within a day. The rock-salt structure is only observed under high pressure. Production The production of cadmium selenide has been carried out in two different ways. The preparation of bulk crystalline CdSe is done by the High-Pressure Vertical Bridgman method or High-Pressure Vertical Zone Melting. Cadmium selenide may also be produced in the form of nanoparticles. (see applications for explanation) Several methods for th ...
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Helium Atom Scattering
Helium atom scattering (HAS) is a surface analysis technique used in materials science. HAS provides information about the surface structure and lattice dynamics of a material by measuring the diffracted atoms from a monochromatic helium beam incident on the sample. History The first recorded He diffraction experiment was completed in 1930 by Estermann and Stern on the (100) crystal face of lithium fluoride. This experimentally established the feasibility of atom diffraction when the de Broglie wavelength, λ, of the impinging atoms is on the order of the interatomic spacing of the material. At the time, the major limit to the experimental resolution of this method was due to the large velocity spread of the helium beam. It wasn't until the development of high pressure nozzle sources capable of producing intense and strongly monochromatic beams in the 1970s that HAS gained popularity for probing surface structure. Interest in studying the collision of rarefied gases with soli ...
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Electron Energy Loss Spectroscopy
In electron energy loss spectroscopy (EELS) a material is exposed to a beam of electrons with a known, narrow range of kinetic energies. Some of the electrons will undergo inelastic scattering, which means that they lose energy and have their paths slightly and randomly deflected. The amount of energy loss can be measured via an electron spectrometer and interpreted in terms of what caused the energy loss. Inelastic interactions include phonon excitations, inter- and intra-band transitions, plasmon excitations, inner shell ionizations, and Cherenkov radiation. The inner-shell ionizations are particularly useful for detecting the elemental components of a material. For example, one might find that a larger-than-expected number of electrons comes through the material with 285  eV less energy than they had when they entered the material. This is approximately the amount of energy needed to remove an inner-shell electron from a carbon atom, which can be taken as evidence ...
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Perturbation Theory
In mathematics and applied mathematics, perturbation theory comprises methods for finding an approximate solution to a problem, by starting from the exact solution of a related, simpler problem. A critical feature of the technique is a middle step that breaks the problem into "solvable" and "perturbative" parts. In perturbation theory, the solution is expressed as a power series in a small parameter The first term is the known solution to the solvable problem. Successive terms in the series at higher powers of \varepsilon usually become smaller. An approximate 'perturbation solution' is obtained by truncating the series, usually by keeping only the first two terms, the solution to the known problem and the 'first order' perturbation correction. Perturbation theory is used in a wide range of fields, and reaches its most sophisticated and advanced forms in quantum field theory. Perturbation theory (quantum mechanics) describes the use of this method in quantum mechanics. The ...
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Hooke's Law
In physics, Hooke's law is an empirical law which states that the force () needed to extend or compress a spring (device), spring by some distance () Proportionality (mathematics)#Direct_proportionality, scales linearly with respect to that distance—that is, where is a constant factor characteristic of the spring (i.e., its stiffness), and is small compared to the total possible deformation of the spring. The law is named after 17th-century British physicist Robert Hooke. He first stated the law in 1676 as a Latin anagram. He published the solution of his anagram in 1678 as: ("as the extension, so the force" or "the extension is proportional to the force"). Hooke states in the 1678 work that he was aware of the law since 1660. Hooke's equation holds (to some extent) in many other situations where an elasticity (physics), elastic body is Deformation (physics), deformed, such as wind blowing on a tall building, and a musician plucking a string (music), string of a guitar ...
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Face-centered Cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc, and alternatively called ''cubic close-packed'' or ccp) Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive unit cells often are not. Bravais lattices The three Bravais lattices in the cubic crystal system are: The primitive cubic lattice (cP) consists of one lattice point on each corner of the cube; this means each simple cubic unit cell has in total one lattice point. Each atom at a lattice point is then shared equally between eight adjacent cubes, ...
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Brillouin Zone
In mathematics and solid state physics, the first Brillouin zone is a uniquely defined primitive cell in reciprocal space. In the same way the Bravais lattice is divided up into Wigner–Seitz cells in the real lattice, the reciprocal lattice is broken up into Brillouin zones. The boundaries of this cell are given by planes related to points on the reciprocal lattice. The importance of the Brillouin zone stems from the description of waves in a periodic medium given by Bloch's theorem, in which it is found that the solutions can be completely characterized by their behavior in a single Brillouin zone. The first Brillouin zone is the locus of points in reciprocal space that are closer to the origin of the reciprocal lattice than they are to any other reciprocal lattice points (see the derivation of the Wigner–Seitz cell). Another definition is as the set of points in ''k''-space that can be reached from the origin without crossing any Bragg plane. Equivalently, this is the Vor ...
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Wave Vector
In physics, a wave vector (or wavevector) is a vector used in describing a wave, with a typical unit being cycle per metre. It has a magnitude and direction. Its magnitude is the wavenumber of the wave (inversely proportional to the wavelength), and its direction is perpendicular to the wavefront. In isotropic media, this is also the direction of wave propagation. A closely related vector is the angular wave vector (or angular wavevector), with a typical unit being radian per metre. The wave vector and angular wave vector are related by a fixed constant of proportionality, 2π radians per cycle. It is common in several fields of physics to refer to the angular wave vector simply as the ''wave vector'', in contrast to, for example, crystallography. It is also common to use the symbol ''k'' for whichever is in use. In the context of special relativity, ''wave vector'' can refer to a four-vector, in which the (angular) wave vector and (angular) frequency are combined. Def ...
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Green's Function
In mathematics, a Green's function is the impulse response of an inhomogeneous linear differential operator defined on a domain with specified initial conditions or boundary conditions. This means that if \operatorname is the linear differential operator, then * the Green's function G is the solution of the equation \operatorname G = \delta, where \delta is Dirac's delta function; * the solution of the initial-value problem \operatorname y = f is the convolution (G \ast f). Through the superposition principle, given a linear ordinary differential equation (ODE), \operatorname y = f, one can first solve \operatorname G = \delta_s, for each , and realizing that, since the source is a sum of delta functions, the solution is a sum of Green's functions as well, by linearity of . Green's functions are named after the British mathematician George Green, who first developed the concept in the 1820s. In the modern study of linear partial differential equations, Green's functions are s ...
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Quantum Dot
Quantum dots (QDs) are semiconductor particles a few nanometres in size, having light, optical and electronics, electronic properties that differ from those of larger particles as a result of quantum mechanics. They are a central topic in nanotechnology. When the quantum dots are illuminated by UV light, an electron in the quantum dot can be excited to a state of higher energy. In the case of a semiconductor, semiconducting quantum dot, this process corresponds to the transition of an electron from the valence band to the conductance band. The excited electron can drop back into the valence band releasing its energy as light. This light emission (photoluminescence) is illustrated in the figure on the right. The color of that light depends on the energy difference between the conductance band and the valence band, or the transition between discrete energy states when band structure is no longer a good definition in QDs. In the language of materials science, nanoscale semiconductor ...
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Solid State Physics
Solid-state physics is the study of rigid matter, or solids, through methods such as quantum mechanics, crystallography, electromagnetism, and metallurgy. It is the largest branch of condensed matter physics. Solid-state physics studies how the large-scale properties of solid materials result from their atomic-scale properties. Thus, solid-state physics forms a theoretical basis of materials science. It also has direct applications, for example in the technology of transistors and semiconductors. Background Solid materials are formed from densely packed atoms, which interact intensely. These interactions produce the mechanical (e.g. hardness and elasticity), thermal, electrical, magnetic and optical properties of solids. Depending on the material involved and the conditions in which it was formed, the atoms may be arranged in a regular, geometric pattern ( crystalline solids, which include metals and ordinary water ice) or irregularly (an amorphous solid such as common ...
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