|
Sum Frequency Generation Spectroscopy
Sum frequency generation spectroscopy (SFG) is a nonlinear laser spectroscopy technique used to analyze surfaces and interfaces. It can be expressed as a sum of a series of Lorentz oscillator model, Lorentz oscillators. In a typical SFG setup, two laser beams nonlinear optics, mix at an interface and generate an output beam with a frequency equal to the sum of the two input frequencies, traveling in a direction allegedly given by the sum of the incident beams' wave vector, wavevectors. The technique was developed in 1987 by Yuen-Ron Shen and his students as an extension of Surface second harmonic generation, second harmonic generation spectroscopy and rapidly applied to deduce the composition, orientation distributions, and structural information of molecules at gas–solid, gas–liquid and liquid–solid interfaces.Hunt, J.H.; Guyot-Sionnest, P.; Shen, Y.R.;"Observation of C-H stretch vibrations of monolayers of molecules optical sum-frequency generation". ''Chemical Physics Letter ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lorentz Oscillator Model
The Lorentz oscillator model describes the optical response of bound charges. The model is named after the Dutch physicist Hendrik Antoon Lorentz. It is a classical, phenomenological model for materials with characteristic resonance frequencies (or other characteristic energy scales) for optical absorption, e.g. ionic and molecular vibrations, interband transitions (semiconductors), phonons, and collective excitations. Derivation of electron motion The model is derived by modeling an electron orbiting a massive, stationary nucleus as a spring-mass-damper system. The electron is modeled to be connected to the nucleus via a hypothetical spring and its motion is damped by via a hypothetical damper. The damping force ensures that the oscillator's response is finite at its resonance frequency. For a time-harmonic driving force which originates from the electric field, Newton’s second law can be applied to the electron to obtain the motion of the electron and expressions for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Geraldine L
Geraldine may refer to: People * Geraldine (name), the feminine form of the first name Gerald, with list of people thus named. * The Geraldines, Irish dynasty descended from the Anglo-Norman Gerald FitzWalter de Windsor * Geraldine of Albania, the Queen Consort of Zog I. Places * Geraldine, New Zealand ** Geraldine (New Zealand electorate) * Geraldine, Alabama, United States * Geraldine, Montana, United States Characters * Geraldine, a character in the poem " Christabel" by Samuel Taylor Coleridge * Geraldine McQueen (character), a fictional singer, played by Peter Kay * Geraldine Jones (character), a comedy persona of Flip Wilson * Geraldine Granger, a fictional character in the British sitcom ''The Vicar of Dibley'' * Geraldine Littlejohn, a character in the film ''Cyberbully'' Films * ''Geraldine'' (1929 film), a 1929 American romantic comedy film * ''Geraldine'' (1953 film), a 1953 American comedy film * ''Geraldine'' (2000 film), a 2000 French animated short film Mus ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photomultiplier
A photomultiplier is a device that converts incident photons into an electrical signal. Kinds of photomultiplier include: * Photomultiplier tube, a vacuum tube converting incident photons into an electric signal. Photomultiplier tubes (PMTs for short) are members of the class of vacuum tubes, and more specifically vacuum phototubes, which are extremely sensitive detectors of light in the ultraviolet, visible, and near-infrared ranges of the electromagnetic spectrum. ** Magnetic photomultiplier, developed by the Soviets in the 1930s. ** Electrostatic photomultiplier, a kind of photomultiplier tube demonstrated by Jan Rajchman of RCA Laboratories in Princeton, NJ in the late 1930s which became the standard for all future commercial photomultipliers. The first mass-produced photomultiplier, the Type 931, was of this design and is still commercially produced today. * Silicon photomultiplier, a solid-state device converting incident photons into an electric signal. Silicon photomultiplie ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monochromator
A monochromator is an optical device that transmits a mechanically selectable narrow band of wavelengths of light or other radiation chosen from a wider range of wavelengths available at the input. The name is from the Greek roots ''mono-'', "single", and ''chroma'', "colour", and the Latin suffix ''-ator'', denoting an agent. Uses A device that can produce monochromatic light has many uses in science and in optics because many optical characteristics of a material are dependent on wavelength. Although there are a number of useful ways to select a narrow band of wavelengths (which, in the visible range, is perceived as a pure color), there are not as many other ways to easily select any wavelength band from a wide range. See below for a discussion of some of the uses of monochromators. In hard X-ray and neutron optics, crystal monochromators are used to define wave conditions on the instruments. Techniques A monochromator can use either the phenomenon of optical dispersion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Total Internal Reflection
Total internal reflection (TIR) is the optical phenomenon in which waves arriving at the interface (boundary) from one medium to another (e.g., from water to air) are not refracted into the second ("external") medium, but completely reflected back into the first ("internal") medium. It occurs when the second medium has a higher wave speed (i.e., lower refractive index) than the first, and the waves are incident at a sufficiently oblique angle on the interface. For example, the water-to-air surface in a typical fish tank, when viewed obliquely from below, reflects the underwater scene like a mirror with no loss of brightness (Fig.1). TIR occurs not only with electromagnetic waves such as light and microwaves, but also with other types of waves, including sound and water waves. If the waves are capable of forming a narrow beam (Fig.2), the reflection tends to be described in terms of "rays" rather than waves; in a medium whose properties are independent of direction, such as air, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optical Parametric Amplifier
An optical parametric amplifier, abbreviated OPA, is a laser light source that emits light of variable wavelengths by an optical parametric amplifier, parametric amplification process. It is essentially the same as an optical parametric oscillator, but without the optical cavity (i.e., the light beams pass through the apparatus just once or twice, rather than many many times). Optical parametric generation (OPG) Optical parametric generation (OPG) (also called "optical parametric fluorescence", or "spontaneous parametric down conversion") often precedes optical parametric amplification. In optical parametric generation, the input is one light beam of frequency ωp, and the output is two light beams of lower frequencies ωs and ωi, with the requirement ωp=ωs+ωi. These two lower-frequency beams are called the "signal" and "idler", respectively. This light emission is based on the nonlinear optics, nonlinear optical principle. The photon of an incident laser pulse (pump) is, by a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optical Parametric Oscillator
An optical parametric oscillator (OPO) is a parametric oscillator that oscillates at optical frequencies. It converts an input laser wave (called "pump") with frequency \omega_p into two output waves of lower frequency (\omega_s, \omega_i) by means of second- order nonlinear optical interaction. The sum of the output waves' frequencies is equal to the input wave frequency: \omega_s + \omega_i=\omega_p. For historical reasons, the two output waves are called "signal" and "idler", where the output wave with higher frequency is the "signal". A special case is the degenerate OPO, when the output frequency is one-half the pump frequency, \omega_s=\omega_i=\omega_p/2, which can result in half-harmonic generation when signal and idler have the same polarization. The first optical parametric oscillator was demonstrated by Joseph A. Giordmaine and Robert C. Miller in 1965, five years after the invention of the laser, at Bell Labs. Optical parametric oscillators are used as coherent light s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Azimuthal
An azimuth (; from ar, اَلسُّمُوت, as-sumūt, the directions) is an angular measurement in a spherical coordinate system. More specifically, it is the horizontal angle from a cardinal direction, most commonly north. Mathematically, the relative position vector from an observer (origin) to a point of interest is projected perpendicularly onto a reference plane (the horizontal plane); the angle between the projected vector and a reference vector on the reference plane is called the azimuth. When used as a celestial coordinate, the azimuth is the horizontal direction of a star or other astronomical object in the sky. The star is the point of interest, the reference plane is the local area (e.g. a circular area with a 5 km radius at sea level) around an observer on Earth's surface, and the reference vector points to true north. The azimuth is the angle between the north vector and the star's vector on the horizontal plane. Azimuth is usually measured in degrees ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mathematical Induction
Mathematical induction is a method for proving that a statement ''P''(''n'') is true for every natural number ''n'', that is, that the infinitely many cases ''P''(0), ''P''(1), ''P''(2), ''P''(3), ... all hold. Informal metaphors help to explain this technique, such as falling dominoes or climbing a ladder: A proof by induction consists of two cases. The first, the base case, proves the statement for ''n'' = 0 without assuming any knowledge of other cases. The second case, the induction step, proves that ''if'' the statement holds for any given case ''n'' = ''k'', ''then'' it must also hold for the next case ''n'' = ''k'' + 1. These two steps establish that the statement holds for every natural number ''n''. The base case does not necessarily begin with ''n'' = 0, but often with ''n'' = 1, and possibly with any fixed natural number ''n'' = ''N'', establishing the truth of the statement for all natu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nonlinear Optics
Nonlinear optics (NLO) is the branch of optics that describes the behaviour of light in ''nonlinear media'', that is, media in which the polarization density P responds non-linearly to the electric field E of the light. The non-linearity is typically observed only at very high light intensities (when the electric field of the light is >108 V/m and thus comparable to the atomic electric field of ~1011 V/m) such as those provided by lasers. Above the Schwinger limit, the vacuum itself is expected to become nonlinear. In nonlinear optics, the superposition principle no longer holds. History The first nonlinear optical effect to be predicted was two-photon absorption, by Maria Goeppert Mayer for her PhD in 1931, but it remained an unexplored theoretical curiosity until 1961 and the almost simultaneous observation of two-photon absorption at Bell Labs and the discovery of second-harmonic generation by Peter Franken ''et al.'' at University of Michigan, both shortly after the constru ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Centrosymmetric
In crystallography, a centrosymmetric point group contains an inversion center as one of its symmetry elements. In such a point group, for every point (x, y, z) in the unit cell there is an indistinguishable point (-x, -y, -z). Such point groups are also said to have ''inversion'' symmetry. Point reflection is a similar term used in geometry. Crystals with an inversion center cannot display certain properties, such as the piezoelectric effect. The following space groups have inversion symmetry: the triclinic space group 2, the monoclinic 10-15, the orthorhombic 47-74, the tetragonal 83-88 and 123-142, the trigonal 147, 148 and 162-167, the hexagonal 175, 176 and 191-194, the cubic 200-206 and 221-230. Point groups lacking an inversion center (non-centrosymmetric) can be ''polar'', ''chiral'', both, or neither. A ''polar'' point group is one whose symmetry operations leave more than one common point unmoved. A polar point group has no unique origin because each of those unmoved ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Raman Spectroscopy
Raman spectroscopy () (named after Indian physicist C. V. Raman) is a spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. Raman spectroscopy is commonly used in chemistry to provide a structural fingerprint by which molecules can be identified. Raman spectroscopy relies upon inelastic scattering of photons, known as Raman scattering. A source of monochromatic light, usually from a laser in the visible, near infrared, or near ultraviolet range is used, although X-rays can also be used. The laser light interacts with molecular vibrations, phonons or other excitations in the system, resulting in the energy of the laser photons being shifted up or down. The shift in energy gives information about the vibrational modes in the system. Infrared spectroscopy typically yields similar yet complementary information. Typically, a sample is illuminated with a laser beam. Electr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
.svg "Click for more on -> Optical Parametric Amplifier")
