Sulfarsenide Mineral
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Sulfarsenide Mineral
The sulfarsenide minerals are a subgroup of the sulfide minerals which include arsenic replacing sulfur as an anion in the formula.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, p. 290 Antimony and bismuth may occur with or in place of the arsenic as in ullmannite. The chemical formula of a sulfarsenide looks like a sulfosalt, however the structures are distinctly different. In sulfosalts the arsenic replaces a metal ion. The sulfarsenides are grouped with the sulfides in both the Dana and Strunz mineral classification systems. Examples include:Palache, C., H. Berman, and C. Frondel (1944) ''Dana’s system of mineralogy,'' (7th edition), v. I, p. 296 *Arsenopyrite group: **Arsenopyrite **Glaucodot ** Gudmundite **Lautite **Alloclasite *Cobaltite group **Cobaltite **Gersdorffite **Ullmannite Ullmannite is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with coba ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite * Galena * Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Proustite *Tetrahedrite *Tennantite *Enargite *Bournonite * ...
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Arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but only the gray form, which has a metallic appearance, is important to industry. The primary use of arsenic is in alloys of lead (for example, in car batteries and ammunition). Arsenic is a common n-type dopant in semiconductor electronic devices. It is also a component of the III-V compound semiconductor gallium arsenide. Arsenic and its compounds, especially the trioxide, are used in the production of pesticides, treated wood products, herbicides, and insecticides. These applications are declining with the increasing recognition of the toxicity of arsenic and its compounds. A few species of bacteria are able to use arsenic compounds as respiratory metabolites. Trace quantities of arsenic are an essential dietary element in rats, ham ...
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Anion
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and ...
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Antimony
Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. The earliest known description of the metal in the West was written in 1540 by Vannoccio Biringuccio. China is the largest producer of antimony and its compounds, with most production coming from the Xikuangshan Mine in Hunan. The industrial methods for refining antimony from stibnite are roasting followed by reduction with carbon, or direct reduction of stibnite with iron. The largest applications for metallic antimony are in alloys with lead and tin, which have improved properties for solders, bullets, and plain bearings. It improves the rigidity of lead-alloy plates in lead–acid batteries. Antimony trioxide is a prominent additive for halo ...
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Bismuth
Bismuth is a chemical element with the Symbol (chemistry), symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Passivation (chemistry), Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly Iridescence, iridescent appearance due to thin-film interference. Bismuth is both the most Diamagnetism, diamagnetic element and one of the least Thermal conductivity, thermally conductive metals known. Bismuth was long considered the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was discovered to be extremely weakly radioactive. The ...
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Ullmannite
Ullmannite is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite. Physical properties Ullmannite is steel-gray to tin white in color with a metallic luster, has a Mohs hardness of 5 to 5.5 and a specific gravity of 6.65. Initially thought to be of two species, tetrahedral and cubic, it was later confirmed that both samples conformed to the 23 point group of the isometric crystal class and typically exhibits cubic, octahedral, or pyritohedral forms although euhedral crystals are rare. Variance in its chemical composition has been shown to be responsible for loss of symmetry and variations in striation patterns. Ullmannite crystals are usually less than 2 mm, however larger have been identified in especially antimony rich environments. Ullmannite commonly displays interpenetration tw ...
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Sulfosalt Mineral
Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury (element), mercury, zinc, vanadium *B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely germanium, or metals like tin and rarely vanadium *X is sulfur or rarely selenium and/or tellurium. The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the Sulfarsenide mineral, sulfarsenides (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for sulfide anions whereas in the sulfosalts the arsenic substitutes for a metal cation.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York . About 200 sulfosalt minerals are known. Examples include: File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As ...
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Strunz Classification
Strunz can refer to: * Claudio Strunz (born 1966), Argentine drummer * Claus Strunz (born 1966), German journalist * Thomas Strunz, (born 1968), German soccer player * Strunz classification in mineralogy * Strunz & Farah Strunz & Farah is a guitar duo with an eclectic sound that has been described as a cross between world fusion and flamenco. History Jorge Strunz, born in Costa Rica, and Ardeshir Farah, hailing from Iran, met in the United States in 1979. Jo ...
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Arsenopyrite
Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5-6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elemental sulfur. When arsenopyrite is heated, it produces sulfur and arsenic vapor. With 46% arsenic content, arsenopyrite, along with orpiment, is a principal ore of arsenic. When deposits of arsenopyrite become exposed to the atmosphere, the mineral slowly converts into iron arsenates. Arsenopyrite is generally an acid-consuming sulfide mineral, unlike iron pyrite which can lead to acid mine drainage. The crystal habit, hardness, density, and garlic odour when struck are diagnostic. Arsenopyrite in older literature may be referred to as ''mispickel'', a name of German origin. Arsenopyrite also can be associated with significant amounts of gold. Consequently, it serves as an indicator of gold bearing reefs. Many arsenopyrite gold ores ...
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Glaucodot
Glaucodot is a cobalt iron arsenic sulfide mineral with formula . The cobalt:iron(II) ratio is typically 3:1 with minor nickel substituting. It forms a series with arsenopyrite . It is an opaque grey to tin-white typically found as massive forms without external crystal form. It crystallizes in the orthorhombic system. The locality at Håkansboda, Sweden has rare twinned dipyramidal crystals (see photo). It is brittle with a Mohs hardness of 5 and a specific gravity of 5.95. It occurs in high temperature hydrothermal deposits with pyrrhotite and chalcopyrite. Glaucodot is classed as a sulfide in the arsenopyrite löllingite group. Glaucodot was first described in 1849 in Huasco, Valparaíso Province, Chile. Its name originates from the Greek grc, γλανκός ("blue") in reference to its use in the dark blue glass called smalt Cobalt glass—known as "smalt" when ground as a pigment—is a deep blue coloured glass prepared by including a cobalt compound, typically cobalt ...
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Lautite
Lautite is a rare mineral belonging to the class of sulfides and sulfosalts with the general formula CuAsS. It is orthorhombic and is known to form up to 2.3 cm long prismatic or flat crystals. It is also found as grains or masses. First identified by Friedrich August Frenzel in 1880 in the Rudolphschacht mine near Lauta in Saxony, it was named after its type locality.Frenzel, A. (1880). XIX. Mineralogisches. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 3(6), 504-516. Lautite is formed in veins under hydrothermal conditions at medium temperatures. Depending on the locality it is found accompanied by arsenic, tennantite, proustite, chalcopyrite, galenite, and baryte (in the type locality); by kutinaite and paxite (in Nieder-Beerbach); or by arsenic, bismuth, tennantite, loellingite, rammelsbergite, proustite, and quartz (in Sainte-Marie-aux-Mines). Aside from the type locality, the mineral is found in other places in the Ore Mountains, in Sankt ...
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