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Strontium Carbonate
Strontium carbonate (SrCO3) is the carbonate salt of strontium that has the appearance of a white or grey powder. It occurs in nature as the mineral strontianite. Chemical properties Strontium carbonate is a white, odorless, tasteless powder. Being a carbonate, it is a weak base and therefore is reactive with acids. It is otherwise stable and safe to work with. It is practically insoluble in water (0.0001 g per 100 ml). The solubility is increased significantly if the water is saturated with carbon dioxide, to 0.1 g per 100 ml. Preparation Other than the natural occurrence as a mineral, strontium carbonate is prepared synthetically in one of two processes, both of which start with naturally occurring celestine, a mineral form of strontium sulfate (SrSO4). In the "black ash" process, celesite is roasted with coke at 1100–1300 °C to form strontium sulfide. The sulfate is reduced, leaving the sulfide: :SrSO4 + 2 C → SrS + 2 CO2 A mixtu ...
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Strontianite
Strontianite ( Sr C O3) is an important raw material for the extraction of strontium. It is a rare carbonate mineral and one of only a few strontium minerals. It is a member of the aragonite group. Aragonite group members: aragonite (CaCO3), witherite (BaCO3), strontianite (SrCO3), cerussite (PbCO3) The ideal formula of strontianite is SrCO3, with molar mass 147.63 g, but calcium (Ca) can substitute for up to 27% of the strontium (Sr) cations, and barium (Ba) up to 3.3%. The mineral was named in 1791 for the locality, Strontian, Argyllshire, Scotland, where the element strontium had been discovered the previous year. Although good mineral specimens of strontianite are rare, strontium is a fairly common element, with abundance in the Earth's crust of 370 parts per million by weight, 87 parts per million by moles, much more common than copper with only 60 parts per million by weight, 19 by moles. Strontium is never found free in nature. The principal strontium ores are ce ...
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Celestine (mineral)
Celestine (the IMA-accepted name) or celestite is a mineral consisting of strontium sulfate ( Sr S O). The mineral is named for its occasional delicate blue color. Celestine and the carbonate mineral strontianite are the principal sources of the element strontium, commonly used in fireworks and in various metal alloys. Etymology Celestine derives its name from the Latin word ''caelestis'' meaning celestial which in turn is derived from the Latin word ''caelum'' meaning sky or heaven. Occurrence Celestine occurs as crystals, and also in compact massive and fibrous forms. It is mostly found in sedimentary rocks, often associated with the minerals gypsum, anhydrite, and halite. On occasion in some localities, it may also be found with sulfur inclusions. The mineral is found worldwide, usually in small quantities. Pale blue crystal specimens are found in Madagascar. White and orange variants also occurred at Yate, Bristol, UK, where it was extracted for commercial purpo ...
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Hygroscopic
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance's molecules, adsorbing substances can become physically changed, e.g., changing in volume, boiling point, viscosity or some other physical characteristic or property of the substance. For example, a finely dispersed hygroscopic powder, such as a salt, may become clumpy over time due to collection of moisture from the surrounding environment. ''Deliquescent'' materials are sufficiently hygroscopic that they absorb so much water that they become liquid and form an aqueous solution. Etymology and pronunciation The word ''hygroscopy'' () uses combining forms of '' hygro-'' and '' -scopy''. Unlike any other ''-scopy'' word, it no longer refers to a viewing or imaging mode. It did begin that way, with the word ''hygroscope'' referring in the ...
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Firework
Fireworks are a class of low explosive pyrotechnic devices used for aesthetic and entertainment purposes. They are most commonly used in fireworks displays (also called a fireworks show or pyrotechnics), combining a large number of devices in an outdoor setting. Such displays are the focal point of many cultural and religious celebrations. Fireworks take many forms to produce four primary effects: noise, light, smoke, and floating materials (confetti most notably). They may be designed to burn with colored flames and sparks including red, orange, yellow, green, blue, purple and silver. They are generally classified by where they perform, either 'ground' or 'aerial'. Aerial fireworks may have their own propulsion (skyrocket) or be shot into the air by a mortar (aerial shell). Most fireworks consist of a paper or pasteboard tube or casing filled with the combustible material, often pyrotechnic stars. A number of these tubes or cases may be combined so as to make when kin ...
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Colorant
A colourant/colour additive (British spelling) or colorant/color additive (American spelling) is a substance that is added or applied in order to change the colour of a material or surface. Colourants can be used for many purposes including printing, painting, and for colouring many types of materials such as foods and plastics. Colourants work by absorbing varying amounts of light at different wavelengths (or frequencies) of its spectrum, transmitting (if translucent) or reflecting the remaining light in straight lines or scattered. Most colourants can be classified as dyes or pigments, or containing some combination of these. Typical dyes are formulated as solutions, while pigments are made up of solid particles suspended and are generally suspended in a vehicle (e.g., linseed oil). The colour a colourant imparts to a substance is mediated by other ingredients it is mixed with such as binders and fillers are added, for example in paints and inks. In addition, some colourants impa ...
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Strontium Carbonate And Nitric Acid
Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors in the periodic table, calcium and barium. It occurs naturally mainly in the minerals celestine and strontianite, and is mostly mined from these. Both strontium and strontianite are named after Strontian, a village in Scotland near which the mineral was discovered in 1790 by Adair Crawford and William Cruickshank; it was identified as a new element the next year from its crimson-red flame test color. Strontium was first isolated as a metal in 1808 by Humphry Davy using the then newly discovered process of electrolysis. During the 19th century, strontium was mostly used in the production of sugar from sugar beets (see strontian pro ...
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Strontium Chloride
Strontium chloride (SrCl2) is a salt of strontium and chlorine. It is a 'typical' salt, forming neutral aqueous solutions. As with all compounds of strontium, this salt emits a bright red colour in flame, and is commonly used in fireworks to that effect. Its chemical properties are intermediate between those for barium chloride, which is more toxic, and calcium chloride. Preparation Strontium chloride can be prepared by treating aqueous strontium hydroxide or strontium carbonate with hydrochloric acid: : Sr(OH)2 + 2 HCl → SrCl2 + 2 H2O Crystallization from cold aqueous solution gives the hexahydrate, SrCl2·6H2O. Dehydration of this salt occurs in stages, commencing above . Full dehydration occurs at .J. Paul MacMillan, Jai Won Park, Rolf Gerstenberg, Heinz Wagner, Karl Köhler, Peter Wallbrecht "Strontium and Strontium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2005, Wiley-VCH: Weinheim. DOI 10.1002/14356007.a25 321 Structure The crystalline solid adopt ...
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Hydrochloric Acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical. History In the early tenth century, the Persian physician and alchemist Abu Bakr al-Razi ( 865–925, Latin: Rhazes) conducted experiments with sal ammoniac ( ammonium chloride) and vitriol (hydrated sulfates of various metals), which he distilled together, thus producing the gas hydrogen chloride. In doing so, al-Razi may have stumbled upon a primitive method for producing hydrochloric acid, as perhaps manifested in the following recipe from his ("The Book of Secrets"): However, it appears that in most of his experiments al-Razi disregarded the gaseous products, concentrating instead on the color cha ...
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Precipitate
In an aqueous solution, precipitation is the process of transforming a dissolved substance into an insoluble solid from a super-saturated solution. The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the ''precipitant''. The clear liquid remaining above the precipitated or the centrifuged solid phase is also called the 'supernate' or 'supernatant'. The notion of precipitation can also be extended to other domains of chemistry (organic chemistry and biochemistry) and even be applied to the solid phases (''e.g.'', metallurgy and alloys) when solid impurities segregate from a solid phase. Supersaturation The precipitation of a compound may occur when its concentration exceeds its solubility. This can be due to temperature changes, solvent evaporation, or by mixing solvents. Precipitation occurs more rapidly from a strongly supersaturated solution. The formati ...
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Sodium Carbonate
Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions in water. Historically, it was extracted from the ashes of plants growing in sodium-rich soils. Because the ashes of these sodium-rich plants were noticeably different from ashes of wood (once used to produce potash), sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process. Hydrates Sodium carbonate is obtained as three hydrates and as the anhydrous salt: * sodium carbonate decahydrate ( natron), Na2CO3·10H2O, which readily effloresces to form the monohydrate. * sodium carbonate heptahydrate (not known in mineral form), Na2CO3·7H2O. * sodium carbonate monohydrate ( thermonatrite), Na2CO3·H2O. Also known as crystal carbonate. * anhydrous sodium carbonate ...
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Reduction Reaction
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ar ...
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Strontium Sulfide
Strontium sulfide is the inorganic compound with the formula Sr S. It is a white solid. The compound is an intermediate in the conversion of strontium sulfate, the main strontium ore called celestite (or, more correctly, celestine), to other more useful compounds.J. Paul MacMillan, Jai Won Park, Rolf Gerstenberg, Heinz Wagner, Karl Köhler, Peter Wallbrecht “Strontium and Strontium Compounds” in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. . Production and reactions Strontium sulfide is produced by roasting celestine with coke at 1100–1300 °C. The sulfate is reduced, leaving the sulfide: :SrSO4 + 2 C → SrS + 2 CO2 About 300,000 tons are processed in this way annually. Both luminous and nonluminous sulfide phases are known, impurities, defects, and dopants being important.R. Ward, R. K. Osterheld, R. D. Rosenstein "Strontium Sulfide and Selenide Phosphors" Inorganic Syntheses, 1950, vol. III, pp. 11–24. As expected for a s ...
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