Stibnite
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Stibnite
Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2 S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The name is derived from the Greek στίβι ''stibi'' through the Latin ''stibium'' as the former name for the mineral and the element antimony. Structure Stibnite has a structure similar to that of arsenic trisulfide, As2S3. The Sb(III) centers, which are pyramidal and three-coordinate, are linked via bent two-coordinate sulfide ions. However, some studies suggest that the actual coordination polyhedra of antimony are SbS7, with (3+4) coordination at the M1 site and (5+2) at the M2 site. Some of the secondary bonds impart cohesion and are connected with packing. Stibnite is grey when fresh, but can turn superficially black due to oxidation in air. Properties The melting point of Sb2S3 is . The band gap is 1.88 eV at room temperature and it is a photoco ...
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Antimony Trisulfide
Antimony trisulfide (Sb2S3) is found in nature as the crystalline mineral stibnite and the amorphous red mineral (actually a mineraloid) metastibnite. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. It also is used in the production of ruby-colored glass and in plastics as a flame retardant. Historically the stibnite form was used as a grey pigment in paintings produced in the 16th century. In 1817, the dye and fabric chemist, John Mercer discovered the non-stoichiometric compound Antimony Orange (approximate formula2 Sb2S3•Sb2O3), the first good orange pigment available for cotton fabric printing. Antimony trisulfide was also used as the image sensitive photoconductor in vidicon camera tubes. It is a semiconductor with a direct band gap of 1.8–2.5 eV. With suitable doping, p and n type materials can be produced. Preparation and reactions Sb2S3 can be prepared from the elements at temperature 500–900 °C: :2 Sb + 3 S ...
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Stibnite (microscopic Section)
Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2 S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The name is derived from the Greek στίβι ''stibi'' through the Latin ''stibium'' as the former name for the mineral and the element antimony. Structure Stibnite has a structure similar to that of arsenic trisulfide, As2S3. The Sb(III) centers, which are pyramidal and three-coordinate, are linked via bent two-coordinate sulfide ions. However, some studies suggest that the actual coordination polyhedra of antimony are SbS7, with (3+4) coordination at the M1 site and (5+2) at the M2 site. Some of the secondary bonds impart cohesion and are connected with packing. Stibnite is grey when fresh, but can turn superficially black due to oxidation in air. Properties The melting point of Sb2S3 is . The band gap is 1.88 eV at room temperature and it is a photocon ...
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Antimony
Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. The earliest known description of the metal in the West was written in 1540 by Vannoccio Biringuccio. China is the largest producer of antimony and its compounds, with most production coming from the Xikuangshan Mine in Hunan. The industrial methods for refining antimony from stibnite are roasting followed by reduction with carbon, or direct reduction of stibnite with iron. The largest applications for metallic antimony are in alloys with lead and tin, which have improved properties for solders, bullets, and plain bearings. It improves the rigidity of lead-alloy plates in lead–acid batteries. Antimony trioxide is a prominent additive for halo ...
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Kohl (cosmetics)
Kohl ( ar, كُحْل, kuḥl), kajal or kajol is an ancient eye cosmetic, traditionally made by grinding stibnite (Sb2S3) for use similar to that of charcoal in mascara. It is widely used in the Middle East, Caucasus and North Africa, South Asia, West Africa, and the Horn of Africa as eyeliner to contour and/or darken the eyelids and as mascara for the eyelashes. It is worn mostly by women, but also by some men and children. The content of kohl and various ways to prepare it differ based on tradition and country. Several studies have questioned the safety of kohl due to the dangers of lead poisoning. Name The Arabic name formed the Arabic root ''k-ḥ-l, “to apply kohl”''. Transliteration variants of Arabic dialectal pronunciation include ''kohl'' or ''kuhl''. The Arabic word cognates with Syriac-Aramaic word ܟܘܚܠܐ/כוחלא ''kuḥla''. Both words derived from Akkadian 𒎎𒋆𒁉𒍣𒁕 ''guẖlu(m)'' meaning stibium. The English word ''alcohol'' is a loan ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite * Galena * Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Proustite *Tetrahedrite *Tennantite *Enargite *Bournonite * ...
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Metalloid
A metalloid is a type of chemical element which has a preponderance of material property, properties in between, or that are a mixture of, those of metals and nonmetals. There is no standard definition of a metalloid and no complete agreement on which elements are metalloids. Despite the lack of specificity, the term remains in use in the literature of chemistry. The six commonly recognised metalloids are boron, silicon, germanium, arsenic, antimony, and tellurium. Five elements are less frequently so classified: carbon, aluminium, selenium, polonium, and astatine. On a standard periodic table, all eleven elements are in a diagonal region of the p-block extending from boron at the upper left to astatine at lower right. Some periodic tables include a dividing line between metals and nonmetals, and the metalloids may be found close to this line. Typical metalloids have a metallic appearance, but they are brittle and only fair electrical conductor, conductors of electricity. Chemica ...
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Sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere The greatest commercial use of the element is the production o ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite * Galena * Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Proustite *Tetrahedrite *Tennantite *Enargite *Bournonite * ...
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Collyrium
In eye care, collyrium is an antique term for a lotion or liquid wash used as a cleanser for the eyes, particularly in diseases of the eye. The word ''collyrium'' comes from the Greek , eye-salve. The same name was also given to unguents used for the same purpose, such as unguent of tutty (Sanskrit ''tuttha'' meaning variously zinc oxide or blue vitriol). Lastly, the name was given, though improperly, to some liquid medicines used against venereal diseases. Pre-modern medicine distinguished two kinds of collyriums: the one liquid, the other dry. Liquid collyriums were composed of ophthalmic powders, or waters, such as rose-water, plantain-water, that of fennel, eyebright, etc., in which was dissolved tutty, white vitriol, or some other proper powder. Dry collyriums were pastilles of Rhasis, sugar-candy, iris, tutty prepared and blown into the eye with a little pipe. The 2nd century Mishnah mentioncollyrium The Sunan Abu Dawood reports, "Prophet Muhammad said: 'Among the best ty ...
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Flash Powder
Flash powder is a pyrotechnic composition, a mixture of oxidizer and metallic fuel, which burns quickly and produces a loud noise regardless of confinement. It is widely used in theatrical pyrotechnics and fireworks (namely salutes, e.g., cherry bombs, M-80s, firecrackers, and cap gun shots) and was once used for flashes in photography. Different varieties of flash powder are made from different compositions; most common are potassium perchlorate and aluminium powder. Sometimes, sulfur is included in the mixture to increase the sensitivity. Early formulations used potassium chlorate instead of potassium perchlorate. Flash powder compositions are also used in military pyrotechnics when production of large amount of noise, light, or infrared radiation is required, e.g., missile decoy flares and stun grenades. History Lycopodium powder is a yellow-tan dust-like powder historically used as a flash powder. Today, the principal use of the powder is to create flashes or flames t ...
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Sunan Abi Dawood
''Sunan Abu Dawood'' ( ar-at, سنن أبي داود, Sunan Abī Dāwūd) is one of the ''Kutub al-Sittah'' (six major hadith collections), collected by Abu Dawud al-Sijistani (d.889). Introduction Abu Dawood compiled twenty-one books related to Hadith and preferred those (plural of "Hadith") which were supported by the example of the companions of Muhammad. As for the contradictory , he states under the heading of 'Meat acquired by hunting for a pilgrim': "if there are two contradictory reports from the Prophet (SAW), an investigation should be made to establish what his companions have adopted". He wrote in his letter to the people of Mecca: "I have disclosed wherever there was too much weakness in regard to any tradition in my collection. But if I happen to leave a Hadith without any comment, it should be considered as sound, albeit some of them are more authentic than others". The Mursal Hadith (a tradition in which a companion is omitted and a successor narrates directly fr ...
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George Starkey (alchemist)
George Starkey (1628–1665) was a Colonial American alchemist, medical practitioner, and writer of numerous commentaries and chemical treatises that were widely circulated in Western Europe and influenced prominent men of science, including Robert Boyle and Isaac Newton. After relocating from New England to London, England, in 1650, Starkey began writing under the pseudonym Eirenaeus Philalethes. Starkey remained in England and continued his career in medicine and alchemy until his death in the Great Plague of London in 1665. Early life Starkey was born in Bermuda, the first of at least five children of George Stirk, a Scottish minister and devoted Calvinist, and Elizabeth Painter. During his early years in Bermuda, Starkey displayed interest in natural history, as evidenced by his written entomological observations of various insects indigenous to Bermuda. After the death of his father in 1637, Starkey was sent to New England, where he continued his early education before enroll ...
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