Stark Effect
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Stark Effect
The Stark effect is the shifting and splitting of spectral lines of atoms and molecules due to the presence of an external electric field. It is the electric-field analogue of the Zeeman effect, where a spectral line is split into several components due to the presence of the magnetic field. Although initially coined for the static case, it is also used in the wider context to describe the effect of time-dependent electric fields. In particular, the Stark effect is responsible for the pressure broadening (Stark broadening) of spectral lines by charged particles in plasmas. For most spectral lines, the Stark effect is either linear (proportional to the applied electric field) or quadratic with a high accuracy. The Stark effect can be observed both for emission and absorption lines. The latter is sometimes called the inverse Stark effect, but this term is no longer used in the modern literature. History The effect is named after the German physicist Johannes Stark, who discov ...
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Hendrik Anthony Kramers
Hendrik Anthony "Hans" Kramers (17 December 1894 – 24 April 1952) was a Dutch physicist who worked with Niels Bohr to understand how electromagnetic waves interact with matter and made important contributions to quantum mechanics and statistical physics. Background and education Hans Kramers was born on 17 December 1894 in Rotterdam. the son of Hendrik Kramers, a physician, and Jeanne Susanne Breukelman. In 1912 Hans finished secondary education ( HBS) in Rotterdam, and studied mathematics and physics at the University of Leiden, where he obtained a master's degree in 1916. Kramers wanted to obtain foreign experience during his doctoral research, but his first choice of supervisor, Max Born in Göttingen, was not reachable because of the First World War. Because Denmark was neutral in this war, as was the Netherlands, he travelled (by ship, overland was impossible) to Copenhagen, where he visited unannounced the then still relatively unknown Niels Bohr. Bohr took him on as a Ph ...
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Electrostatic
Electrostatics is a branch of physics that studies electric charges at rest (static electricity). Since classical times, it has been known that some materials, such as amber, attract lightweight particles after rubbing. The Greek word for amber, (), was thus the source of the word 'electricity'. Electrostatic phenomena arise from the forces that electric charges exert on each other. Such forces are described by Coulomb's law. Even though electrostatically induced forces seem to be rather weak, some electrostatic forces are relatively large. The force between an electron and a proton, which together make up a hydrogen atom, is about 36 orders of magnitude stronger than the gravitational force acting between them. There are many examples of electrostatic phenomena, from those as simple as the attraction of plastic wrap to one's hand after it is removed from a package, to the apparently spontaneous explosion of grain silos, the damage of electronic components during manufacturi ...
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Electric Charge
Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respectively). Like charges repel each other and unlike charges attract each other. An object with an absence of net charge is referred to as neutral. Early knowledge of how charged substances interact is now called classical electrodynamics, and is still accurate for problems that do not require consideration of quantum effects. Electric charge is a conserved property; the net charge of an isolated system, the amount of positive charge minus the amount of negative charge, cannot change. Electric charge is carried by subatomic particles. In ordinary matter, negative charge is carried by electrons, and positive charge is carried by the protons in the nuclei of atoms. If there are more electrons than protons in a piece of matter, it will have ...
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Quantum Superposition
Quantum superposition is a fundamental principle of quantum mechanics. It states that, much like waves in classical physics, any two (or more) quantum states can be added together ("superposed") and the result will be another valid quantum state; and conversely, that every quantum state can be represented as a sum of two or more other distinct states. Mathematically, it refers to a property of solutions to the Schrödinger equation; since the Schrödinger equation is linear, any linear combination of solutions will also be a solution(s) . An example of a physically observable manifestation of the wave nature of quantum systems is the interference peaks from an electron beam in a double-slit experiment. The pattern is very similar to the one obtained by diffraction of classical waves. Another example is a quantum logical qubit state, as used in quantum information processing, which is a quantum superposition of the "basis states" , 0 \rangle and , 1 \rangle . Here , 0 \r ...
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Orbital Hybridisation
In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new ''hybrid orbitals'' (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory. For example, in a carbon atom which forms four single bonds the valence-shell s orbital combines with three valence-shell p orbitals to form four equivalent sp3 mixtures in a tetrahedral arrangement around the carbon to bond to four different atoms. Hybrid orbitals are useful in the explanation of molecular geometry and atomic bonding properties and are symmetrically disposed in space. Usually hybrid orbitals are formed by mixing atomic orbitals of comparable energies. History and uses Chemist Linus Pauling first developed the hybridisation theory in 1931 to explain the structure of simple molecules such as methane (CH4) using atomic orbitals. Pauling pointed out that a carbon atom forms four ...
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Bohr Model
In atomic physics, the Bohr model or Rutherford–Bohr model, presented by Niels Bohr and Ernest Rutherford in 1913, is a system consisting of a small, dense nucleus surrounded by orbiting electrons—similar to the structure of the Solar System, but with attraction provided by electrostatic forces in place of gravity. It came after the solar system Joseph Larmor model (1897), the solar system Jean Perrin model (1901), the cubical model (1902), the Hantaro Nagaoka Saturnian model (1904), the plum pudding model (1904), the quantum Arthur Haas model (1910), the Rutherford model (1911), and the nuclear quantum John William Nicholson model (1912). The improvement over the 1911 Rutherford model mainly concerned the new quantum physical interpretation introduced by Haas and Nicholson, but forsaking any attempt to align with classical physics radiation. The model's key success lay in explaining the Rydberg formula for the spectral emission lines of atomic hydrogen. While the Rydberg ...
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Degenerate Energy Level
Degeneracy, degenerate, or degeneration may refer to: Arts and entertainment * ''Degenerate'' (album), a 2010 album by the British band Trigger the Bloodshed * Degenerate art, a term adopted in the 1920s by the Nazi Party in Germany to describe modern art ** Decadent movement, often associated with degeneracy * Dégénération, a single by Mylène Farmer * ''Degeneration'' (Nordau), an 1892 book by Max Nordau * '' Resident Evil: Degeneration'', a 2008 film * "Degenerate", a song by Blink-182 from the album '' Dude Ranch'' * "Degenerates", a song by A Day to Remember from the album ''You're Welcome'' Science, mathematics, and medicine Mathematics * Degeneracy (mathematics), a limiting case in which a class of object changes its nature so as to belong to another, usually simpler, class * Degeneracy (graph theory), a measure of the sparseness of a graph * Degeneration (algebraic geometry), the act of taking a limit of a family of varieties * Degenerate form, bilinear form ' ...
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Electron Shell
In chemistry and atomic physics, an electron shell may be thought of as an orbit followed by electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on farther and farther from the nucleus. The shells correspond to the principal quantum numbers (''n'' = 1, 2, 3, 4 ...) or are labeled alphabetically with the letters used in X-ray notation (K, L, M, ...). A useful guide when understanding electron shells in atoms is to note that each row on the conventional periodic table of elements represents an electron shell. Each shell can contain only a fixed number of electrons: the first shell can hold up to two electrons, the second shell can hold up to eight (2 + 6) electrons, the third shell can hold up to 18 (2 + 6 + 10) and so on. The general formula is that the ''n''th shell can in principle hold up to 2( ''n''2) electrons.
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ...
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Erwin Schrödinger
Erwin Rudolf Josef Alexander Schrödinger (, ; ; 12 August 1887 – 4 January 1961), sometimes written as or , was a Nobel Prize-winning Austrian physicist with Irish citizenship who developed a number of fundamental results in quantum theory: the Schrödinger equation provides a way to calculate the wave function of a system and how it changes dynamically in time. In addition, he wrote many works on various aspects of physics: statistical mechanics and thermodynamics, physics of dielectrics, colour theory, electrodynamics, general relativity, and cosmology, and he made several attempts to construct a unified field theory. In his book ''What Is Life?'' Schrödinger addressed the problems of genetics, looking at the phenomenon of life from the point of view of physics. He also paid great attention to the philosophical aspects of science, ancient, and oriental philosophical concepts, ethics, and religion. He also wrote on philosophy and theoretical biology. In popular culture, ...
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Wolfgang Pauli
Wolfgang Ernst Pauli (; ; 25 April 1900 – 15 December 1958) was an Austrian theoretical physicist and one of the pioneers of quantum physics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics for his "decisive contribution through his discovery of a new law of Nature, the exclusion principle or Pauli principle". The discovery involved spin theory, which is the basis of a theory of the structure of matter. Early years Pauli was born in Vienna to a chemist, Wolfgang Joseph Pauli (''né'' Wolf Pascheles, 1869–1955), and his wife, Bertha Camilla Schütz; his sister was Hertha Pauli, a writer and actress. Pauli's middle name was given in honor of his godfather, physicist Ernst Mach. Pauli's paternal grandparents were from prominent families of Prague; his great-grandfather was the publisher Wolf Pascheles. Pauli's mother, Bertha Schütz, was raised in her mother's Roman Catholic religion; Pauli was raised as a Roman Catholic, ...
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