Spinor Spherical Harmonics
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Spinor Spherical Harmonics
In quantum mechanics, the spinor spherical harmonics (also known as spin spherical harmonics, spinor harmonics and Pauli spinors) are special functions defined over the sphere. The spinor spherical harmonics are the natural spinor analog of the vector spherical harmonics. While the standard spherical harmonics are a basis for the angular momentum operator, the spinor spherical harmonics are a basis for the total angular momentum operator (angular momentum plus spin). These functions are used in analytical solutions to Dirac equation in a radial potential. The spinor spherical harmonics are sometimes called Pauli central field spinors, in honor to Wolfgang Pauli who employed them in the solution of the hydrogen atom with spin–orbit interaction. Properties The spinor spherical harmonics are the spinors eigenstates of the total angular momentum operator squared: : \begin \mathbf j^2 Y_ &= j (j + 1) Y_ \\ \mathrm j_ Y_ &= m Y_\;;\;m=-j,-(j-1),\cdots,j-1,j\\ \mathbf l^2 Y_ & ...
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ...
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Spin–orbit Interaction
In quantum physics, the spin–orbit interaction (also called spin–orbit effect or spin–orbit coupling) is a relativistic interaction of a particle's spin with its motion inside a potential. A key example of this phenomenon is the spin–orbit interaction leading to shifts in an electron's atomic energy levels, due to electromagnetic interaction between the electron's magnetic dipole, its orbital motion, and the electrostatic field of the positively charged nucleus. This phenomenon is detectable as a splitting of spectral lines, which can be thought of as a Zeeman effect product of two relativistic effects: the apparent magnetic field seen from the electron perspective and the magnetic moment of the electron associated with its intrinsic spin. A similar effect, due to the relationship between angular momentum and the strong nuclear force, occurs for protons and neutrons moving inside the nucleus, leading to a shift in their energy levels in the nucleus shell model. In the fi ...
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Spinors
In geometry and physics, spinors are elements of a complex vector space that can be associated with Euclidean space. Like geometric vectors and more general tensors, spinors transform linearly when the Euclidean space is subjected to a slight (infinitesimal) rotation. Unlike vectors and tensors, a spinor transforms to its negative when the space is continuously rotated through a complete turn from 0° to 360° (see picture). This property characterizes spinors: spinors can be viewed as the "square roots" of vectors (although this is inaccurate and may be misleading; they are better viewed as "square roots" of sections of vector bundles – in the case of the exterior algebra bundle of the cotangent bundle, they thus become "square roots" of differential forms). It is also possible to associate a substantially similar notion of spinor to Minkowski space, in which case the Lorentz transformations of special relativity play the role of rotations. Spinors were introduced in geome ...
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Addison-Wesley
Addison-Wesley is an American publisher of textbooks and computer literature. It is an imprint of Pearson PLC, a global publishing and education company. In addition to publishing books, Addison-Wesley also distributes its technical titles through the O'Reilly Online Learning e-reference service. Addison-Wesley's majority of sales derive from the United States (55%) and Europe (22%). The Addison-Wesley Professional Imprint produces content including books, eBooks, and video for the professional IT worker including developers, programmers, managers, system administrators. Classic titles include ''The Art of Computer Programming'', ''The C++ Programming Language'', ''The Mythical Man-Month'', and ''Design Patterns''. History Lew Addison Cummings and Melbourne Wesley Cummings founded Addison-Wesley in 1942, with the first book published by Addison-Wesley being Massachusetts Institute of Technology professor Francis Weston Sears' ''Mechanics''. Its first computer book was ''Progra ...
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Spin-½
In quantum mechanics, spin is an intrinsic property of all elementary particles. All known fermions, the particles that constitute ordinary matter, have a spin of . The spin number describes how many symmetrical facets a particle has in one full rotation; a spin of means that the particle must be rotated by two full turns (through 720°) before it has the same configuration as when it started. Particles having net spin include the proton, neutron, electron, neutrino, and quarks. The dynamics of spin- objects cannot be accurately described using classical physics; they are among the simplest systems which require quantum mechanics to describe them. As such, the study of the behavior of spin- systems forms a central part of quantum mechanics. Stern–Gerlach experiment The necessity of introducing half-integer spin goes back experimentally to the results of the Stern–Gerlach experiment. A beam of atoms is run through a strong heterogeneous magnetic field, which then sp ...
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Parity (physics)
In physics, a parity transformation (also called parity inversion) is the flip in the sign of ''one'' spatial coordinate. In three dimensions, it can also refer to the simultaneous flip in the sign of all three spatial coordinates (a point reflection): :\mathbf: \beginx\\y\\z\end \mapsto \begin-x\\-y\\-z\end. It can also be thought of as a test for chirality of a physical phenomenon, in that a parity inversion transforms a phenomenon into its mirror image. All fundamental interactions of elementary particles, with the exception of the weak interaction, are symmetric under parity. The weak interaction is chiral and thus provides a means for probing chirality in physics. In interactions that are symmetric under parity, such as electromagnetism in atomic and molecular physics, parity serves as a powerful controlling principle underlying quantum transitions. A matrix representation of P (in any number of dimensions) has determinant equal to −1, and hence is distinct from a rotat ...
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Magnetic Quantum Number
In atomic physics, the magnetic quantum number () is one of the four quantum numbers (the other three being the principal, azimuthal, and spin) which describe the unique quantum state of an electron. The magnetic quantum number distinguishes the orbitals available within a subshell, and is used to calculate the azimuthal component of the orientation of orbital in space. Electrons in a particular subshell (such as s, p, d, or f) are defined by values of (0, 1, 2, or 3). The value of can range from to , including zero. Thus the s, p, d, and f subshells contain 1, 3, 5, and 7 orbitals each, with values of within the ranges 0, ±1, ±2, ±3 respectively. Each of these orbitals can accommodate up to two electrons (with opposite spins), forming the basis of the periodic table. Derivation There is a set of quantum numbers associated with the energy states of the atom. The four quantum numbers n, \ell, m_\ell, and s specify the complete quantum state of a single electron in a ...
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Azimuthal Quantum Number
The azimuthal quantum number is a quantum number for an atomic orbital that determines its orbital angular momentum and describes the shape of the orbital. The azimuthal quantum number is the second of a set of quantum numbers that describe the unique quantum state of an electron (the others being the principal quantum number, the magnetic quantum number, and the spin quantum number). It is also known as the orbital angular momentum quantum number, orbital quantum number or second quantum number, and is symbolized as ℓ (pronounced ''ell''). Derivation Connected with the energy states of the atom's electrons are four quantum numbers: ''n'', ''ℓ'', ''m''''ℓ'', and ''m''''s''. These specify the complete, unique quantum state of a single electron in an atom, and make up its wavefunction or ''orbital''. When solving to obtain the wave function, the Schrödinger equation reduces to three equations that lead to the first three quantum numbers. Therefore, the equations for t ...
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Eigenstate
In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in time exhausts all that can be predicted about the system's behavior. A mixture of quantum states is again a quantum state. Quantum states that cannot be written as a mixture of other states are called pure quantum states, while all other states are called mixed quantum states. A pure quantum state can be represented by a ray in a Hilbert space over the complex numbers, while mixed states are represented by density matrices, which are positive semidefinite operators that act on Hilbert spaces. Pure states are also known as state vectors or wave functions, the latter term applying particularly when they are represented as functions of position or momentum. For example, when dealing with the energy spectrum of the electron in a hydrogen ato ...
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Spinor
In geometry and physics, spinors are elements of a complex vector space that can be associated with Euclidean space. Like geometric vectors and more general tensors, spinors transform linearly when the Euclidean space is subjected to a slight (infinitesimal) rotation. Unlike vectors and tensors, a spinor transforms to its negative when the space is continuously rotated through a complete turn from 0° to 360° (see picture). This property characterizes spinors: spinors can be viewed as the "square roots" of vectors (although this is inaccurate and may be misleading; they are better viewed as "square roots" of sections of vector bundles – in the case of the exterior algebra bundle of the cotangent bundle, they thus become "square roots" of differential forms). It is also possible to associate a substantially similar notion of spinor to Minkowski space, in which case the Lorentz transformations of special relativity play the role of rotations. Spinors were introduced in geome ...
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Hydrogen Atom
A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe. In everyday life on Earth, isolated hydrogen atoms (called "atomic hydrogen") are extremely rare. Instead, a hydrogen atom tends to combine with other atoms in compounds, or with another hydrogen atom to form ordinary ( diatomic) hydrogen gas, H2. "Atomic hydrogen" and "hydrogen atom" in ordinary English use have overlapping, yet distinct, meanings. For example, a water molecule contains two hydrogen atoms, but does not contain atomic hydrogen (which would refer to isolated hydrogen atoms). Atomic spectroscopy shows that there is a discrete infinite set of states in which a hydrogen (or any) atom can exist, contrary to the predictions of classical physics. Attempts to develop a theore ...
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Princeton University Press
Princeton University Press is an independent publisher with close connections to Princeton University. Its mission is to disseminate scholarship within academia and society at large. The press was founded by Whitney Darrow, with the financial support of Charles Scribner, as a printing press to serve the Princeton community in 1905. Its distinctive building was constructed in 1911 on William Street in Princeton. Its first book was a new 1912 edition of John Witherspoon's ''Lectures on Moral Philosophy.'' History Princeton University Press was founded in 1905 by a recent Princeton graduate, Whitney Darrow, with financial support from another Princetonian, Charles Scribner II. Darrow and Scribner purchased the equipment and assumed the operations of two already existing local publishers, that of the ''Princeton Alumni Weekly'' and the Princeton Press. The new press printed both local newspapers, university documents, ''The Daily Princetonian'', and later added book publishing to it ...
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