Solidification And Stabilization
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Solidification And Stabilization
Remediation of contaminated sites with cement, also called solidification/stabilization with cement (S/S with cement) is a common method for the safe environmental remediation of contaminated land with cement. The cement solidifies the contaminated soil and prevents pollutants from moving, such as rain causing leaching of pollutants into the groundwater or being carried into streams by rain or snowmelt. Developed in the 1950s, the technology is widely used today to treat industrial hazardous waste and contaminated material at brownfield sites i.e. abandoned or underutilized properties that are not being redeveloped because of fears that they may be contaminated with hazardous waste. S/S provides an economically viable means of treating contaminated sites. This technology treats and contains contaminated soil on site thereby reducing the need for landfills. Process The Solidification/Stabilization method utilizes chemically reactive formulations that form stable solids that are ...
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Environmental Remediation
Environmental remediation deals with the removal of pollution or contaminants from environmental media such as soil, groundwater, sediment, or surface water. Remedial action is generally subject to an array of regulatory requirements, and may also be based on assessments of human health and ecological risks where no legislative standards exist, or where standards are advisory. Remediation standards In the United States, the most comprehensive set of Preliminary Remediation Goals (PRGs) is from the Environmental Protection Agency (EPA) ''Regional Screening Levels'' (RSLs). A set of standards used in Europe exists and is often called the Dutch standards. The European Union (EU) is rapidly moving towards Europe-wide standards, although most of the industrialised nations in Europe have their own standards at present. In Canada, most standards for remediation are set by the provinces individually, but the Canadian Council of Ministers of the Environment provides guidance at a federa ...
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Clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay particles, but become hard, brittle and non–plastic upon drying or firing. Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide. Clay is the oldest known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been dated to around 14,000 BC, and clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often ...
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Environmental Remediation
Environmental remediation deals with the removal of pollution or contaminants from environmental media such as soil, groundwater, sediment, or surface water. Remedial action is generally subject to an array of regulatory requirements, and may also be based on assessments of human health and ecological risks where no legislative standards exist, or where standards are advisory. Remediation standards In the United States, the most comprehensive set of Preliminary Remediation Goals (PRGs) is from the Environmental Protection Agency (EPA) ''Regional Screening Levels'' (RSLs). A set of standards used in Europe exists and is often called the Dutch standards. The European Union (EU) is rapidly moving towards Europe-wide standards, although most of the industrialised nations in Europe have their own standards at present. In Canada, most standards for remediation are set by the provinces individually, but the Canadian Council of Ministers of the Environment provides guidance at a federa ...
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Water Pollution
Water pollution (or aquatic pollution) is the contamination of water bodies, usually as a result of human activities, so that it negatively affects its uses. Water bodies include lakes, rivers, oceans, aquifers, reservoirs and groundwater. Water pollution results when contaminants are introduced into these water bodies. Water pollution can be attributed to one of four sources: sewage discharges, industrial activities, agricultural activities, and urban runoff including stormwater. It can be grouped into surface water pollution (either fresh water pollution or marine pollution) or groundwater pollution. For example, releasing inadequately treated wastewater into natural waters can lead to degradation of these aquatic ecosystems. Water pollution can also lead to water-borne diseases for people using polluted water for drinking, bathing, washing or irrigation. Water pollution reduces the ability of the body of water to provide the ecosystem services (such as drinking water) that ...
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Soil Contamination
Soil contamination, soil pollution, or land pollution as a part of land degradation is caused by the presence of xenobiotic (human-made) chemicals or other alteration in the natural soil environment. It is typically caused by industrial activity, agricultural chemicals or improper disposal of waste. The most common chemicals involved are petroleum hydrocarbons, polynuclear aromatic hydrocarbons (such as naphthalene and benzo(a)pyrene), solvents, pesticides, lead, and other heavy metals. Contamination is correlated with the degree of industrialization and intensity of chemical substance. The concern over soil contamination stems primarily from health risks, from direct contact with the contaminated soil, vapour from the contaminants, or from secondary contamination of water supplies within and underlying the soil. Mapping of contaminated soil sites and the resulting cleanups are time-consuming and expensive tasks, and require expertise in geology, hydrology, chemistry, compute ...
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Soil Vapor Extraction
Soil vapor extraction (SVE) is a physical treatment process for in situ remediation of volatile contaminants in vadose zone (unsaturated) soils (EPA, 2012). SVE (also referred to as in situ soil venting or vacuum extraction) is based on mass transfer of contaminant from the solid (sorbed) and liquid (aqueous or non-aqueous) phases into the gas phase, with subsequent collection of the gas phase contamination at extraction wells. Extracted contaminant mass in the gas phase (and any condensed liquid phase) is treated in aboveground systems. In essence, SVE is the vadose zone equivalent of the pump-and-treat technology for groundwater remediation. SVE is particularly amenable to contaminants with higher Henry’s Law constants, including various chlorinated solvents and hydrocarbons. SVE is a well-demonstrated, mature remediation technology and has been identified by the U.S. Environmental Protection Agency (EPA) as presumptive remedy. SVE Configuration The soil vapor extraction ...
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Saltcrete
Saltcrete is a mixture of cement with salts and brine, usually originating from liquid waste treatment plants. Its role is to immobilize hazardous waste and in some cases lower-level radioactive waste in the form of solid material. It is a form of mixed waste. Saltcrete is being replaced by saltstone, which is less permeable and leachable. Saltstone is a mixture of the salt cake (mostly sodium nitrate and other salts) with concrete and fly ash. An example of a saltcrete site in the United States is The Rocky Flats Environmental Technology Site (RFETS) near Denver, Colorado. Between 1952 and 1992, nuclear weapons components consisting of radioactive and otherwise hazardous materials were manufactured there. By 1989, a government investigation had concluded that many of these materials were being improperly stored and handled, leading to the site being added to the National Priorities List for cleanup by the Environmental Protection Agency. Saltcrete-related background of RFETS ...
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Salt-concrete
Salt-concrete (or ''salzbeton'') is a building material that is used to reduce the water inflow in mining shafts in salt mines. It is composed of 16% cement, 39% halite, 16% limestone powder, 14% water and 15% sand. History Salt-concrete was used for the first time in 1984 in the potash mine in Rocanville in Canada. A salt-concrete seal was also installed in the Asse II mine in Lower Saxony in 1995. Filling tunnels Since the end of the repository for radioactive waste Morsleben in 1998, the salt dome stability deteriorated to a state where it could collapse. Since 2003, a volume of m3 of salt-concrete has been pumped into the pit to temporarily stabilize the upper levels. In addition another m3 of salt-concrete will be used to temporarily stabilize the lower levels. See also * Friedel's salt ** synthesized first by Georges Friedel * Sorel cement ** produced first by Stanislas Sorel *Saltcrete Saltcrete is a mixture of cement with salts and brine, usually originating from li ...
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Pondcrete
Pondcrete is a mixture of cement and sludge. Its role is to immobilize hazardous waste and, in some cases, low-level and mixed-level radioactive waste, in the form of solid material. The material was used by the United States Department of Energy and its contractor, Rockwell International, in an attempt to handle the radioactive waste from contaminated ponds in the Rocky Flats Plant for burial in Nevada desert. Portland cement is mixed with sludge to solidify into “pondcrete” blocks and placed into large, plastic lined boxes. The sludge is taken from solar evaporation ponds which are used to remove moisture from waste materials, therefore reducing their weight. To do this, liquid waste is poured into artificial, shallow ponds. The waste is heated by solar radiation and any moisture is evaporated, leaving behind the waste. These ponds contained low level radioactive process waste as well as sanitary sewage sludge and wastes, which categorize them and the Pondcrete as a mixed ...
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Hazardous Waste
Hazardous waste is waste that has substantial or potential threats to public health or the environment. Hazardous waste is a type of dangerous goods. They usually have one or more of the following hazardous traits: ignitability, reactivity, corrosivity, toxicity. Listed hazardous wastes are materials specifically listed by regulatory authorities as hazardous wastes which are from non-specific sources, specific sources, or discarded chemical products. Hazardous wastes may be found in different physical states such as gaseous, liquids, or solids. A hazardous waste is a special type of waste because it cannot be disposed of by common means like other by-products of our everyday lives. Depending on the physical state of the waste, treatment and solidification processes might be required. The Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and Their Disposal was signed by 199 countries and went into force in 1992. Plastic was added to the convention i ...
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Pugmill
A pugmill or pug mill is a machine in which clay or other materials are mixed into a plastic state or a similar machine for the trituration of ore. Industrial applications are found in pottery, bricks, cement and some parts of the concrete and asphalt mixing processes. A pugmill may be a fast continuous mixer. A continuous pugmill can achieve a thoroughly mixed, homogeneous mixture in a few seconds, and the right machines can be matched to the right application by taking into account the factors of agitation, drive assembly, inlet, discharge, cost and maintenance. Mixing materials at optimum moisture content requires the forced mixing action of the pugmill paddles, while soupy materials might be mixed in a drum mixer. A typical pugmill consists of a horizontal boxlike chamber with a top inlet and a bottom discharge at the other end, 2 shafts with opposing paddles, and a drive assembly. Some of the factors affecting mixing and residence time are the number and the size of the paddles ...
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Polycyclic Aromatic Hydrocarbon
A polycyclic aromatic hydrocarbon (PAH) is a class of organic compounds that is composed of multiple aromatic rings. The simplest representative is naphthalene, having two aromatic rings and the three-ring compounds anthracene and phenanthrene. PAHs are uncharged, non-polar and planar. Many are colorless. Many of them are found in coal and in oil deposits, and are also produced by the combustion of organic matter—for example, in engines and incinerators or when biomass burns in forest fires. Polycyclic aromatic hydrocarbons are discussed as possible starting materials for abiotic syntheses of materials required by the earliest forms of life. Nomenclature and structure The terms polyaromatic hydrocarbon or polynuclear aromatic hydrocarbon are also used for this concept. By definition, polycyclic aromatic hydrocarbons have multiple rings, precluding benzene from being considered a PAH. Some sources, such as the US EPA and CDC, consider naphthalene to be the simplest PAH. ...
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