Sanidine
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Sanidine
Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable. Due to the high temperature and rapid quenching, sanidine can contain more sodium in its structure than the two polymorphs that equilibrated at lower temperatures. Sanidine and high albite constitute a solid solution series with intermediate compositions termed anorthoclase. Exsolution of an albite phase does occur; resulting cryptoperthite can best be observed in electron microprobe images. Occurrence In addition to its presence in the groundmass of felsic rocks, sanidine is a common phenocryst in rhyolites and, to a lesser extent, rhyodacites. Trachyte consists largely of ...
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Feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspars and the ''alkali'' (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight. Feldspars crystalize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks. Compositions The feldspar group of minerals consists of tectosilicates, silicate minerals in which silicon ions are linked by shared oxygen ions to form a three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three endmembers: * potassium feldspar ...
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Feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspars and the ''alkali'' (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight. Feldspars crystalize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks. Compositions The feldspar group of minerals consists of tectosilicates, silicate minerals in which silicon ions are linked by shared oxygen ions to form a three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three endmembers: * potassium feldspar ...
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Trachyte
Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and alkali metals. It is the volcanic equivalent of syenite. Trachyte is common wherever alkali magma is erupted, including in late stages of ocean island volcanismMacDonald 1983, pp. 51-52 and in continental rift valleys, above mantle plumes,Philpotts and Ague 2009, pp. 390-394 and in areas of back-arc extension. Trachyte has also been found in Gale crater on Mars. Trachyte has been used as decorative building stone and was extensively used as dimension stone in the Roman Empire and the Republic of Venice. Chemical composition Trachyte has a silica content of 60 to 65% and an alkali oxide content of over 7%. This gives it less SiO2 than rhyolite and more (Na2O plus K2O) than dacite. These chemical differences are consistent with the posi ...
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Anorthoclase
The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and between 64 and 90 percent of NaAlSi3O8.Deere, Howie and Zussman, ''Rock Forming Minerals,'' Vol. 4 ''Framework Silicates,'' Wiley, pp. 2 - 5, Fig. 1 Structure and stability Anorthoclase is an intermediate member of the high albite – sanidine alkali feldspar solid solution series. Intermediate members of this series, high albite, anorthoclase and high sodium sanidine are stable at temperatures of and above. Below 400 to 600 °C only very limited solution exists (less than about 5% on both the low albite and microcline ends).Klein, Cornelis and Cornelius S. Hurlbut, Jr. ''Handbook of Mineralogy,'' Wiley, pp. 446-449 (Fig. 11-95 Anorthoclase and high albite exhibit triclinic symmetry, whereas sanidine and the low temperature orthoc ...
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Rhyolite
Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained ( aphanitic) in texture, but may be porphyritic, containing larger mineral crystals ( phenocrysts) in an otherwise fine-grained groundmass. The mineral assemblage is predominantly quartz, sanidine, and plagioclase. It is the extrusive equivalent to granite. Rhyolitic magma is extremely viscous, due to its high silica content. This favors explosive eruptions over effusive eruptions, so this type of magma is more often erupted as pyroclastic rock than as lava flows. Rhyolitic ash-flow tuffs are among the most voluminous of continental igneous rock formations. Rhyolitic tuff has been extensively used for construction. Obsidian, which is rhyolitic volcanic glass, has been used for tools from prehistoric times to the present day because it can be shaped to an extremely sharp edge. Rhyolitic pumice finds use as an abrasive, in concrete, and as a soil amendment. Description R ...
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Orthoclase
Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase. Formation and subtypes Orthoclase is a common constituent of most granites and other felsic igneous rocks and often forms huge crystals and masses in pegmatite. Typically, the pure potassium endmember of orthoclase forms a solid solution with albite, the sodium endmember (NaAlSi3O8), of plagioclase. While slowly cooling within the earth, sodium-rich albite lamellae form by exsolution, enriching the remaining orthoclase with potassium. The resulting intergrowth of the two feldspars is called perthite. The higher-temperature polymorph of KAlSi3O8 is sanidine. Sanidine is commo ...
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Rhyodacite
Rhyodacite is a volcanic rock intermediate in composition between dacite and rhyolite. It is the extrusive equivalent of those plutonic rocks that are intermediate in composition between monzogranite and granodiorite. Rhyodacites form from rapid cooling of lava relatively rich in silica and low in alkali metal oxides. Description Under IUGS guidelines, rhyodacites are not formally defined in either the QAPF classification, used to classify igneous rocks by their mineral content, or the TAS classification, used to classify volcanic rocks chemically. However, the IUGS allows the use of the term to describe rocks close to the boundary between the rhyolite and dacite fields in each classification scheme. Rhyodacite then describes a fine-grained igneous rock containing between 20% and 60% quartz and in which plagioclase makes up about two-thirds of the total feldspar content. Such a rock will contain between 69% and 72% silica by weight. The U.S. Geological Survey defin ...
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Tridymite
Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O2. Tridymite was first described in 1868 and the type location is in Hidalgo, Mexico. The name is from the Greek ''tridymos'' for ''triplet'' as tridymite commonly occurs as twinned crystal '' trillings'' (compound crystals comprising three twinned crystal components). Structure Tridymite can occur in seven crystalline forms. Two of the most common at standard pressure are known as α and β. The α-tridymite phase is favored at elevated temperatures (>870 °C) and it converts to β- cristobalite at 1470 °C. However, tridymite does usually not form from pure β-quartz, one needs to add trace amounts of certain compounds to achieve this. Otherwise the β-quartz-tridymite transition is skipped and β-quartz transitions directly to cristobalite at 1050 ° ...
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Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear molecule. The starkly different structures of th ...
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Leucite
Leucite is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra but, as first observed by Sir David Brewster in 1821, they are not optically isotropic, and are therefore pseudo-cubic. Goniometric measurements made by Gerhard vom Rath in 1873 led him to refer the crystals to the tetragonal system. Optical investigations have since proved the crystals to be still more complex in character, and to consist of several orthorhombic or monoclinic individuals, which are optically biaxial and repeatedly twinned, giving rise to twin-lamellae and to striations on the faces. When the crystals are raised to a temperature of about 500 °C they become optically isotropic and the twin-lamellae and striations disappear, although they reappear when the crystals are cooled again. This pseudo-cubic character of leucite is very similar to that of the mineral ...
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Electron Microscope
An electron microscope is a microscope that uses a beam of accelerated electrons as a source of illumination. As the wavelength of an electron can be up to 100,000 times shorter than that of visible light photons, electron microscopes have a higher resolving power than light microscopes and can reveal the structure of smaller objects. A scanning transmission electron microscope has achieved better than 50  pm resolution in annular dark-field imaging mode and magnifications of up to about 10,000,000× whereas most light microscopes are limited by diffraction to about 200  nm resolution and useful magnifications below 2000×. Electron microscopes use shaped magnetic fields to form electron optical lens systems that are analogous to the glass lenses of an optical light microscope. Electron microscopes are used to investigate the ultrastructure of a wide range of biological and inorganic specimens including microorganisms, cells, large molecules, biopsy samples, ...
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