Sanidine
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Sanidine
Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable. Due to the high temperature and rapid quenching, sanidine can contain more sodium in its structure than the two polymorphs that equilibrated at lower temperatures. Sanidine and high albite constitute a solid solution series with intermediate compositions termed anorthoclase. Exsolution of an albite phase does occur; resulting cryptoperthite can best be observed in electron microprobe images. Occurrence In addition to its presence in the groundmass of felsic rocks, sanidine is a common phenocryst in rhyolites and, to a lesser extent, rhyodacites. Trachyte consists largely of fi ...
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Feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspars and the ''alkali'' (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight. Feldspars crystalize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks. Compositions The feldspar group of minerals consists of tectosilicates, silicate minerals in which silicon ions are linked by shared oxygen ions to form a three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three endmembers: * potassium feldspar (K-spar) ...
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Feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspars and the ''alkali'' (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight. Feldspars crystalize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks. Compositions The feldspar group of minerals consists of tectosilicates, silicate minerals in which silicon ions are linked by shared oxygen ions to form a three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three endmembers: * potassium feldspar (K-spar) ...
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Microcline
Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase; it is more stable at lower temperatures than orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline may be clear, white, pale-yellow, brick-red, or green; it is generally characterized by cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline. The chemical compound name is potassium aluminium silicate, and it is known as E number reference E555. Geology Microcline may be chemically the same as monoclinic orthoclase, but because it belongs to the triclinic crystal system, the prism angle is slightly less than right angles; hence the name "microcline" from the Greek "small slope." It is a fully ordered triclin ...
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Orthoclase
Orthoclase, or orthoclase feldspar (endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase. Formation and subtypes Orthoclase is a common constituent of most granites and other felsic igneous rocks and often forms huge crystals and masses in pegmatite. Typically, the pure potassium endmember of orthoclase forms a solid solution with albite, the sodium endmember (NaAlSi3O8), of plagioclase. While slowly cooling within the earth, sodium-rich albite lamellae form by exsolution, enriching the remaining orthoclase with potassium. The resulting intergrowth of the two feldspars is called perthite. The higher-temperature polymorph of KAlSi3O8 is sanidine. Sanidine is common in rapidly ...
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Rhyodacite
Rhyodacite is a volcanic rock intermediate in composition between dacite and rhyolite. It is the extrusive equivalent of those plutonic rocks that are intermediate in composition between monzogranite and granodiorite. Rhyodacites form from rapid cooling of lava relatively rich in silica and low in alkali metal oxides. Description Under IUGS guidelines, rhyodacites are not formally defined in either the QAPF classification, used to classify igneous rocks by their mineral content, or the TAS classification, used to classify volcanic rocks chemically. However, the IUGS allows the use of the term to describe rocks close to the boundary between the rhyolite and dacite fields in each classification scheme. Rhyodacite then describes a fine-grained igneous rock containing between 20% and 60% quartz and in which plagioclase makes up about two-thirds of the total feldspar content. Such a rock will contain between 69% and 72% silica by weight. The U.S. Geological Survey defines rhyodacite ...
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Radiometric Dating
Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares the abundance of a naturally occurring radioactive isotope within the material to the abundance of its decay products, which form at a known constant rate of decay. The use of radiometric dating was first published in 1907 by Bertram Boltwood and is now the principal source of information about the absolute age of rocks and other geological features, including the age of fossilized life forms or the age of Earth itself, and can also be used to date a wide range of natural and man-made materials. Together with stratigraphic principles, radiometric dating methods are used in geochronology to establish the geologic time scale. Among the best-known techniques are radiocarbon dating, potassium–argon dating and uranium–lead dating. By al ...
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X-ray Crystallography
X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles and intensities of these diffracted beams, a crystallographer can produce a three-dimensional picture of the density of electrons within the crystal. From this electron density, the mean positions of the atoms in the crystal can be determined, as well as their chemical bonds, their crystallographic disorder, and various other information. Since many materials can form crystals—such as salts, metals, minerals, semiconductors, as well as various inorganic, organic, and biological molecules—X-ray crystallography has been fundamental in the development of many scientific fields. In its first decades of use, this method determined the size of atoms, the lengths and types of chemical bonds, and the atomic-scale differences among various mat ...
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Ferric
In chemistry, iron(III) refers to the element iron in its +3 oxidation state. In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) denoted by Fe3+. The adjective ferric or the prefix ferri- is often used to specify such compounds — as in "ferric chloride" for iron(III) chloride, . The adjective "ferrous" is used instead for iron(II) salts, containing the cation Fe2+. The word ferric is derived from the Latin word ''ferrum'' for iron. Iron(III) metal centres also occur in coordination complexes, such as in the anion ferrioxalate, , where three bidentate oxalate ions surrounding the metal centre; or, in organometallic compounds, such as the ferrocenium cation , where two cyclopentadienyl anions are bound to the FeIII centre. Iron is almost always encountered in the oxidation states 0 (as in the metal), +2, or +3. Iron(III) is usually the most stable form in air, as illustrated by the pervasiveness of rust, an insoluble iron(III)-containing ...
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Electron Microprobe
An electron microprobe (EMP), also known as an electron probe microanalyzer (EPMA) or electron micro probe analyzer (EMPA), is an analytical tool used to non-destructively determine the chemical composition of small volumes of solid materials. It works similarly to a scanning electron microscope: the sample is bombarded with an electron beam, emitting x-rays at wavelengths characteristic to the elements being analyzed. This enables the abundances of elements present within small sample volumes (typically 10-30 cubic micrometers or less) to be determined,Wittry, David B. (1958). "Electron Probe Microanalyzer"US Patent No 2916621 Washington, DC: U.S. Patent and Trademark Office when a conventional accelerating voltage of 15-20 kV is used. The concentrations of elements from lithium to plutonium may be measured at levels as low as 100 parts per million (ppm), material dependent, although with care, levels below 10 ppm are possible. The ability to quantify lithium by EPMA became a real ...
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Electron Microscope
An electron microscope is a microscope that uses a beam of accelerated electrons as a source of illumination. As the wavelength of an electron can be up to 100,000 times shorter than that of visible light photons, electron microscopes have a higher resolving power than light microscopes and can reveal the structure of smaller objects. A scanning transmission electron microscope has achieved better than 50  pm resolution in annular dark-field imaging mode and magnifications of up to about 10,000,000× whereas most light microscopes are limited by diffraction to about 200  nm resolution and useful magnifications below 2000×. Electron microscopes use shaped magnetic fields to form electron optical lens systems that are analogous to the glass lenses of an optical light microscope. Electron microscopes are used to investigate the ultrastructure of a wide range of biological and inorganic specimens including microorganisms, cells, large molecules, biopsy samples, ...
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