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Stiff Diagram
A Stiff diagram, or Stiff pattern, is a graphical representation of chemical analyses, first developed by H.A. Stiff in 1951. It is widely used by hydrogeologists and geochemists to display the major ion composition of a water sample. A polygonal shape is created from four parallel horizontal axes extending on either side of a vertical zero axis. Cations are plotted in milliequivalents per liter on the left side of the zero axis, one to each horizontal axis, and anions are plotted on the right side. Stiff patterns are useful in making a rapid visual comparison between water from different sources. An alternative to the Stiff diagram is the Maucha diagram. Stiff diagrams can be used: :1) to help visualize ionically related waters from which a flow path can be determined, or; :2) if the flow path is known, to show how the ionic composition of a water body changes over space and/or time. A typical Stiff diagram is shown in the figure (right). By standard convention, Stiff diagr ...
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Hydrogeology
Hydrogeology (''hydro-'' meaning water, and ''-geology'' meaning the study of the Earth) is the area of geology that deals with the distribution and movement of groundwater in the soil and rocks of the Earth's crust (commonly in aquifers). The terms groundwater hydrology, geohydrology, and hydrogeology are often used interchangeably. Hydrogeology is the study of the laws governing the movement of subterranean water, the mechanical, chemical, and thermal interaction of this water with the porous solid, and the transport of energy, chemical constituents, and particulate matter by flow (Domenico and Schwartz, 1998). Groundwater engineering, another name for hydrogeology, is a branch of engineering which is concerned with groundwater movement and design of wells, pumps, and drains. The main concerns in groundwater engineering include groundwater contamination, conservation of supplies, and water quality.Walton, William C. (November 1990). ''Principles of Groundwater Engin ...
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Geochemistry
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the entire Solar System, and has made important contributions to the understanding of a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology. History The term ''geochemistry'' was first used by the Swiss-German chemist Christian Friedrich Schönbein in 1838: "a comparative geochemistry ought to be launched, before geognosy can become geology, and before the mystery of the genesis of our planets and their inorganic matter may be revealed." However, for the rest of the century the more common term was "chemical geology", and there was little contact between geologists and chemists. Geochemistry emerged as a separate discipline after ...
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Water Quality
Water quality refers to the chemical, physical, and biological characteristics of water based on the standards of its usage. It is most frequently used by reference to a set of standards against which compliance, generally achieved through treatment of the water, can be assessed. The most common standards used to monitor and assess water quality convey the health of ecosystems, safety of human contact, extend of water pollution and condition of drinking water. Water quality has a significant impact on water supply and oftentimes determines supply options. Categories The parameters for water quality are determined by the intended use. Work in the area of water quality tends to be focused on water that is treated for potability, industrial/domestic use, or restoration (of an environment/ecosystem, generally for health of human/aquatic life). Human consumption Contaminants that may be in untreated water include microorganisms such as viruses, protozoa and bacteria; inorganic ...
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Cations
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and ...
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Equivalent Concentration
In chemistry, the equivalent concentration or normality (N) of a solution is defined as the molar concentration ''ci'' divided by an equivalence factor ''f''eq: :Normality = Definition Normality is defined as the number of gramme or mole equivalents of solute present in one litre of solution. The SI unit of normality is Eq/L. Normality formula :Normality (N) = Weight of Solute (in gm) / (Equivalent Weight of Solute × Volume of the Solution (in liters))https://clavick.com/normality/ Usage There are three common types of chemical reaction where normality is used as a measure of reactive species in solution: *In acid-base chemistry, normality is used to express the concentration of hydronium ions (H3O+) or hydroxide ions (OH−) in a solution. Here, is an integer value. Each solute can produce one or more equivalents of reactive species when dissolved. *In redox reactions, the equivalence factor describes the number of electrons that an oxidizing or reducing agent can ...
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Anions
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a ...
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Maucha Diagram
A Maucha diagram, or Maucha symbol, is a graphical representation of the major cations and anions in a chemical sample. R. Maucha published the symbol in 1932. It is mainly used by biologists and chemists for quickly recognising samples by their chemical composition. The symbol is similar in concept to the Stiff diagram. It conveys similar ionic information to the Piper diagram, though in a more compact format that is suitable as a map symbol or for showing changes with time. The Maucha diagram is a special case of the Radar chart and overcomes some of the limitations of the Pie chart by having equal angles for all variables and consistently showing each variable in the same position. The star shape comprises eight kite-shaped polygons, the area of each of which is proportional to the concentration of an ion in milliequivalents An equivalent (symbol: officially equiv; unofficially but often Eq) is the amount of a substance that reacts with (or is ''equivalent'' to) an arbitra ...
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Example Stiff Diagram
Example may refer to: * '' exempli gratia'' (e.g.), usually read out in English as "for example" * .example, reserved as a domain name that may not be installed as a top-level domain of the Internet ** example.com, example.net, example.org, example.edu, second-level domain names reserved for use in documentation as examples * HMS ''Example'' (P165), an Archer-class patrol and training vessel of the Royal Navy Arts * ''The Example'', a 1634 play by James Shirley * ''The Example'' (comics), a 2009 graphic novel by Tom Taylor and Colin Wilson * Example (musician), the British dance musician Elliot John Gleave (born 1982) * ''Example'' (album), a 1995 album by American rock band For Squirrels See also * * Exemplar (other), a prototype or model which others can use to understand a topic better * Exemplum, medieval collections of short stories to be told in sermons * Eixample The Eixample (; ) is a district of Barcelona between the old city (Ciutat Vella) and ...
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The Geochemist's Workbench
The Geochemist's Workbench (GWB) is an integrated set of interactive software tools for solving a range of problems in aqueous chemistry. The graphical user interface simplifies the use of the geochemical code. History The GWB package was originally developed at the Department of Geology of the University of Illinois at Urbana-Champaign over a period of more than twenty years,Bethke, C.M., B. Farrell, and M. Sharifi, 2021, ''The Geochemist’s Workbench® Release 15 (five volumes)''. https://www.gwb.com/documentation.php under the sponsorship initially of a consortium of companies and government laboratories, and later through license fees paid by a community of users. In 2011, the GWB development team moved to the Research Park at the University of Illinois, and subsequently off campus in Champaign, IL, where they operate as an independent company named Aqueous Solutions LLC. Since its release, many thousands of licensed copies have been installed in more than 90 countries. ...
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Rockworks
First developed in 1985 by RockWare Inc, RockWorks is used by the mining, petroleum, and environmental industry for subsurface visualization, borehole database management as well as the creation of grids, solid models, calculating volumetric analysis, etc. RockWorks background Computer modeling in RockWorks provides a means for tailoring a mine, environmental, petroleum, etc. plan based on the end-user specifications. The basic strategy involves the creation of a borehole database that includes analytical results for various physical and chemical properties as a function of depth. Once the database has been created, visualizations such as cross-sections, fence diagrams, and block diagrams are generated to check the validity and geological reasonability of the modeling. The next steps can involve the calculation of volumetrics and optimal pit-designs for example, in mining, based on a series of user-defined parameters. The foundation of these analyses involve the creation of im ...
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Python (programming Language)
Python is a high-level, general-purpose programming language. Its design philosophy emphasizes code readability with the use of significant indentation. Python is dynamically-typed and garbage-collected. It supports multiple programming paradigms, including structured (particularly procedural), object-oriented and functional programming. It is often described as a "batteries included" language due to its comprehensive standard library. Guido van Rossum began working on Python in the late 1980s as a successor to the ABC programming language and first released it in 1991 as Python 0.9.0. Python 2.0 was released in 2000 and introduced new features such as list comprehensions, cycle-detecting garbage collection, reference counting, and Unicode support. Python 3.0, released in 2008, was a major revision that is not completely backward-compatible with earlier versions. Python 2 was discontinued with version 2.7.18 in 2020. Python consistently ranks as ...
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