SiC–SiC Matrix Composite
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SiC–SiC Matrix Composite
SiC–SiC matrix composite is a particular type of ceramic matrix composite (CMC) which have been accumulating interest mainly as high temperature materials for use in applications such as gas turbines, as an alternative to metallic alloys. CMCs are generally a system of materials that are made up of ceramic fibers or particles that lie in a ceramic matrix phase. In this case, a SiC/SiC composite is made by having a SiC ( silicon carbide) matrix phase and a fiber phase incorporated together by different processing methods. Outstanding properties of SiC/SiC composites include high thermal, mechanical, and chemical stability while also providing high strength to weight ratio. Processing SiC/SiC composites are mainly processed through three different methods. However, these processing methods are often subjected to variations in order to create the desired structure or property: # Chemical Vapor Infiltration (CVI) – The CVI method uses a gas phase SiC precursor to first grow ...
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Ceramic Matrix Composite
In materials science, ceramic matrix composites (CMCs) are a subgroup of composite materials and a subgroup of ceramics. They consist of ceramic fibers embedded in a ceramic matrix. The fibers and the matrix both can consist of any ceramic material, whereby carbon and carbon fibers can also be regarded as a ceramic material. Introduction The motivation to develop CMCs was to overcome the problems associated with the conventional technical ceramics like alumina, silicon carbide, aluminum nitride, silicon nitride or zirconia – they fracture easily under mechanical or thermo-mechanical loads because of cracks initiated by small defects or scratches. The crack resistance is very low, as in glass. To increase the crack resistance or fracture toughness, particles (so-called monocrystalline ''whiskers'' or ''platelets'') were embedded into the matrix. However, the improvement was limited, and the products have found application only in some ceramic cutting tools. So far only the i ...
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Ceramization
Polymer derived ceramics (PDCs) are ceramic materials formed by the pyrolysis of preceramic polymers, usually under inert atmosphere. The compositions of PDCs most commonly include silicon carbide (SiC), silicon oxycarbide (SiOxCy), silicon nitride(Si3N4), silicon carbonitride (Si3+xN4Cx+y) and silicon oxynitride (SiOxNy). The composition, phase distribution and structure of PDCs depend on the polymer precursor compounds used and the pyrolysis conditions applied. The key advantage of this type of ceramic material is the versatility afforded by the use of polymeric precursors in terms of processing and shaping. Polymer derived ceramics can be additively manufactured (3D printed) my means of stereolithography that uses photopolymerization of preceramic polymers. Such processing of PDCs is used in applications requiring thermally and chemically stable materials in complex shapes that are challenging to achieve through more conventional ceramic processing routes, such as powder sinteri ...
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Ceramic Materials
A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain, and brick. The earliest ceramics made by humans were pottery objects (''pots,'' ''vessels or vases'') or figurines made from clay, either by itself or mixed with other materials like silica, hardened and sintered in fire. Later, ceramics were glazed and fired to create smooth, colored surfaces, decreasing porosity through the use of glassy, amorphous ceramic coatings on top of the crystalline ceramic substrates. Ceramics now include domestic, industrial and building products, as well as a wide range of materials developed for use in advanced ceramic engineering, such as in semiconductors. The word "''ceramic''" comes from the Greek word (), "of pottery" or "for pottery", from (), "potter's clay, tile, pottery". The earliest known m ...
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Grain Size
Grain size (or particle size) is the diameter of individual grains of sediment, or the lithified particles in clastic rocks. The term may also be applied to other granular materials. This is different from the crystallite size, which refers to the size of a single crystal inside a particle or grain. A single grain can be composed of several crystals. Granular material can range from very small colloidal particles, through clay, silt, sand, gravel, and cobbles, to boulders. Krumbein phi scale Size ranges define limits of classes that are given names in the Wentworth scale (or Udden–Wentworth scale) used in the United States. The Krumbein ''phi'' (φ) scale, a modification of the Wentworth scale created by W. C. Krumbein in 1934, is a logarithmic scale computed by the equation :\varphi=-\log_2, where :\varphi is the Krumbein phi scale, :D is the diameter of the particle or grain in millimeters (Krumbein and Monk's equation) and :D_0 is a reference diameter, equal to 1  ...
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Turbopump
A turbopump is a propellant pump with two main components: a rotodynamic pump and a driving gas turbine, usually both mounted on the same shaft, or sometimes geared together. They were initially developed in Germany in the early 1940s. The purpose of a turbopump is to produce a high-pressure fluid for feeding a combustion chamber or other use. There are two types of turbopumps: a centrifugal pump, where the pumping is done by throwing fluid outward at high speed, or an axial-flow pump, where alternating rotating and static blades progressively raise the pressure of a fluid. Axial-flow pumps have small diameters but give relatively modest pressure increases. Although multiple compression stages are needed, axial flow pumps work well with low-density fluids. Centrifugal pumps are far more powerful for high-density fluids but require large diameters for low-density fluids. History Early development High-pressure pumps for larger missiles had been discussed by rocket pioneers su ...
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Rocket Nozzle
A rocket engine nozzle is a propelling nozzle (usually of the de Laval type) used in a rocket engine to expand and accelerate combustion products to high supersonic velocities. Simply: propellants pressurized by either pumps or high pressure ullage gas to anywhere between two to several hundred atmospheres are injected into a combustion chamber to burn, and the combustion chamber leads into a nozzle which converts the energy contained in high pressure, high temperature combustion products into kinetic energy by accelerating the gas to high velocity and near-ambient pressure. History Simple bell-shaped nozzles were developed in the 1500s. The de Laval nozzle was originally developed in the 19th century by Gustaf de Laval for use in steam turbines. It was first used in an early rocket engine developed by Robert Goddard, one of the fathers of modern rocketry. It has since been used in almost all rocket engines, including Walter Thiel's implementation, which made possible Germa ...
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Thermal Protection System
Atmospheric entry is the movement of an object from outer space into and through the gases of an atmosphere of a planet, dwarf planet, or natural satellite. There are two main types of atmospheric entry: ''uncontrolled entry'', such as the entry of astronomical objects, space debris, or bolides; and ''controlled entry'' (or ''reentry'') of a spacecraft capable of being navigated or following a predetermined course. Technologies and procedures allowing the controlled atmospheric ''entry, descent, and landing'' of spacecraft are collectively termed as ''EDL''. Objects entering an atmosphere experience atmospheric drag, which puts mechanical stress on the object, and aerodynamic heating—caused mostly by compression of the air in front of the object, but also by drag. These forces can cause loss of mass (ablation) or even complete disintegration of smaller objects, and objects with lower compressive strength can explode. Crewed space vehicles must be slowed to subsonic speeds b ...
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Thermal Conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal conductivity. For instance, metals typically have high thermal conductivity and are very efficient at conducting heat, while the opposite is true for insulating materials like Rockwool or Styrofoam. Correspondingly, materials of high thermal conductivity are widely used in heat sink applications, and materials of low thermal conductivity are used as thermal insulation. The reciprocal of thermal conductivity is called thermal resistivity. The defining equation for thermal conductivity is \mathbf = - k \nabla T, where \mathbf is the heat flux, k is the thermal conductivity, and \nabla T is the temperature gradient. This is known as Fourier's Law for heat conduction. Although commonly expressed as a scalar, the most general form of th ...
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Taylor & Francis Online
Taylor & Francis Group is an international company originating in England that publishes books and academic journals. Its parts include Taylor & Francis, Routledge, F1000 Research or Dovepress. It is a division of Informa plc, a United Kingdom–based publisher and conference company. Overview The company was founded in 1852 when William Francis joined Richard Taylor in his publishing business. Taylor had founded his company in 1798. Their subjects covered agriculture, chemistry, education, engineering, geography, law, mathematics, medicine, and social sciences. Francis's son, Richard Taunton Francis (1883–1930), was sole partner in the firm from 1917 to 1930. In 1965, Taylor & Francis launched Wykeham Publications and began book publishing. T&F acquired Hemisphere Publishing in 1988, and the company was renamed Taylor & Francis Group to reflect the growing number of imprints. Taylor & Francis left the printing business in 1990, to concentrate on publishing. In 1998 i ...
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Acta Materialia
''Acta Materialia'' is a peer-reviewed scientific journal published twenty times per year on behalf of Acta Materialia Inc. The current publisher is Elsevier. The coordinating editor is Christopher A. Schuh, Danae and Vasilis Salapatas Professor of Metallurgy at the Massachusetts Institute of Technology. The journal covers research on all aspects of the structure and properties of materials and publishes original papers and commissioned reviews called Overviews. History The journal was established in 1953 as ''Acta Metallurgica'' and renamed to ''Acta Metallurgica et Materialia'' in 1990, before obtaining its current name in 1996. Since 1956, it has been published by Pergamon Press, with the imprint being retained for some time after the acquisition by Elsevier. It incorporates ''Nanostructured Materials'' that was published independently from 1992 to 1999. '' Scripta Materialia'' was established in 1967 as a companion journal, publishing rapid communications as well as opinion ...
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Redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogen ...
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