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Saturate, Aromatic, Resin And Asphaltene
Saturate, Aromatic, Resin and Asphaltene (SARA) is an analysis method that divides crude oil components according to their polarizability and polarity. The saturate fraction consists of nonpolar material including linear, branched, and cyclic saturated hydrocarbons ( paraffins). Aromatics, which contain one or more aromatic rings, are slightly more polarizable. The remaining two fractions, resins and asphaltenes, have polar substituents. The distinction between the two is that asphaltenes are insoluble in an excess of heptane (or pentane) whereas resins are miscible with heptane (or pentane). Method description There are three main methods to obtain SARA results. One has lately emerged as the most popular. That technology is known as the Iatroscan TLC-FID, and it combines thin-layer chromatography (TLC) with flame ionization detection (FID). It is referred to as IP-143. Other analysis giving SARA numbers might not correspond to the numbers obtained in IP-143. It is therefore ...
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Crude Oil
Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude oil and petroleum products that consist of refined crude oil. A fossil fuel, petroleum is formed when large quantities of dead organisms, mostly zooplankton and algae, are buried underneath sedimentary rock and subjected to both prolonged heat and pressure. Petroleum is primarily recovered by oil drilling. Drilling is carried out after studies of structural geology, sedimentary basin analysis, and reservoir characterisation. Recent developments in technologies have also led to exploitation of other Unconventional (oil & gas) reservoir, unconventional reserves such as oil sands and oil shale. Once extracted, oil is refined and separated, most easily by Continuous distillation#Continuous distillation of crude oil, distillation, into innume ...
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Alkane
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula . The alkanes range in complexity from the simplest case of methane (), where ''n'' = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like pentacontane () or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane (). The International Union of Pure and Applied Chemistry (IUPAC) defines alkanes as "acyclic branched or unbranched hydrocarbons having the general formula , and therefore consisting entirely of hydrogen atoms and saturated carbon atoms". However, some sources use the term to denote ''any'' saturated hydrocarbon, including those that are either monocyclic (i.e. the cycloalkanes) or ...
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Aromatics
Aromatic compounds, also known as "mono- and polycyclic aromatic hydrocarbons", are organic compounds containing one or more aromatic rings. The parent member of aromatic compounds is benzene. The word "aromatic" originates from the past grouping of molecules based on smell, before their general chemical properties are understood. The current definition of aromatic compounds does not have any relation with their smell. Heteroarenes are closely related, since at least one carbon atom of CH group is replaced by one of the heteroatoms oxygen, nitrogen, or sulfur. Examples of non-benzene compounds with aromatic properties are furan, a heterocyclic compound with a five-membered ring that includes a single oxygen atom, and pyridine, a heterocyclic compound with a six-membered ring containing one nitrogen atom. Hydrocarbons without an aromatic ring are called aliphatic. Benzene ring model Benzene, C6H6, is the least complex aromatic hydrocarbon, and it was the first one named as such ...
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Asphaltenes
Asphaltenes are molecular substances that are found in crude oil, along with resins, aromatic hydrocarbons, and saturates (i.e. saturated hydrocarbons such as alkanes). The word "asphaltene" was coined by Boussingault in 1837 when he noticed that the distillation residue of some bitumens had asphalt-like properties. Asphaltenes in the form of asphalt or bitumen products from oil refineries are used as paving materials on roads, shingles for roofs, and waterproof coatings on building foundations. Composition Asphaltenes consist primarily of carbon (C4-), hydrogen (H+), nitrogen (N), oxygen (O2-), and sulfur (S2-), as well as trace amounts of vanadium (V) and nickel (Ni). The C:H ratio is approximately 1:1.2, depending on the asphaltene source. Asphaltenes are defined operationally as the n-heptane ()-insoluble, toluene ()-soluble component of a carbonaceous material such as crude oil, bitumen, or coal. Asphaltenes have been shown to have a distribution of molecular masses in ...
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Thin-layer Chromatography
Thin-layer chromatography (TLC) is a chromatography technique used to separate non-volatile mixtures. Thin-layer chromatography is performed on a sheet of an inert substrate such as glass, plastic, or aluminium foil, which is coated with a thin layer of adsorbent material, usually silica gel, aluminium oxide (alumina), or cellulose. This layer of adsorbent is known as the stationary phase. After the sample has been applied on the plate, a solvent or solvent mixture (known as the mobile phase) is drawn up the plate via capillary action. Because different analytes ascend the TLC plate at different rates, separation is achieved. It may be performed on the analytical scale as a means of monitoring the progress of a reaction, or on the preparative scale to purify small amounts of a compound. TLC is an analytical tool widely used because of its simplicity, relative low cost, high sensitivity, and speed of separation. TLC functions on the same principle as all chromatography: a com ...
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Flame Ionization Detection
A flame ionization detector (FID) is a scientific instrument that measures analytes in a gas stream. It is frequently used as a detector in gas chromatography. The measurement of ion per unit time make this a mass sensitive instrument. Standalone FIDs can also be used in applications such as landfill gas monitoring, fugitive emissions monitoring and internal combustion engine emissions measurement in stationary or portable instruments. History The first flame ionization detectors were developed simultaneously and independently in 1957 by McWilliam and Dewar at Imperial Chemical Industries of Australia and New Zealand (ICIANZ, see Orica history) Central Research Laboratory, Ascot Vale, Melbourne, Australia. and by Harley and Pretorius at the University of Pretoria in Pretoria, South Africa. In 1959, Perkin Elmer Corp. included a flame ionization detector in its Vapor Fractometer. Operating principle The operation of the FID is based on the detection of ions formed during comb ...
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Crude Oil Assay
A crude oil assay is the chemical evaluation of crude oil feedstocks by petroleum testing laboratories. Each crude oil type has unique molecular and chemical characteristics. No two crude oil types are identical and there are crucial differences in crude oil quality. The results of crude oil assay testing provide extensive detailed hydrocarbon analysis data for refiners, oil traders and producers. Assay data help refineries determine if a crude oil feedstock is compatible for a particular petroleum refinery or if the crude oil could cause yield, quality, production, environmental and other problems. The assay can be an inspection assay or comprehensive assay. Testing can include crude oil characterization of whole crude oils and the various boiling range fractions produced from physical or simulated distillation by various procedures. Information obtained from the petroleum assay is used for detailed refinery engineering and client marketing purposes. Feedstock assay data are an i ...
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PONA Number
The PONA number is an index for oil components. It is used to determine the paraffins (P), olefins (O), naphthenes (N) and aromatics (A) content of FCC (fluid catalytic cracking) and coker (visbreaker) gasoline. The PONA number is significant in determining the quality of naphtha. There are various grades of naphtha produced depending on the PONA specifications, such as 60/15, 65/12, 70/10, etc. The first number is the minimum allowable total parafins percentage and the second number specifies the maximum allowable aromatics percentage. It also determines the price of naphtha in international markets. See also *Crude oil assay * SARA Sara may refer to: Arts, media and entertainment Film and television * ''Sara'' (1992 film), 1992 Iranian film by Dariush Merhjui * ''Sara'' (1997 film), 1997 Polish film starring Bogusław Linda * ''Sara'' (2010 film), 2010 Sri Lankan Sinhal ... References {{DEFAULTSORT:Pona Number Petroleum ...
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PIONA
Colico ( Comasque: or ; la, Colicum) is a city in the province of Lecco, Lombardy, Italy. It is situated on the northern arm of Lake Como, where the river Adda enters the lake. Colico is the most important city in the northern part of Lake Como, which is often identified as its Colico branch. Colico is a local transport hub, with boats to Como and Lecco, as well as trains and roads to Milan (via the eastern shore of the lake, Lecco and Brianza), to Chiavenna, and eastwards to Bolzano, via Passo dello Stelvio. The Piona Abbey is located in the communal territory, in the Olgiasca peninsula. Geography Colico is dominated by Monte Legnone, at above sea level, and high foothills. Near Colico is an important natural reserve, the migration corridor of the Pian di Spagna (in the province of Como). The two main waterways of Colico are Inganna and Perlino; the river Adda is a natural boundary between the provinces of Como and Lecco. Main sights Forts * Fort Montecchio, a fort ...
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PNA Analysis
PNA or Pna has a variety of meanings: Science and engineering * abbreviation for orchid genus ''Paphinia'' * Pacific–North American teleconnection pattern, a climatic phenomenon * Parisiensia Nomina Anatomica, the revision of anatomic nomenclature * Peanut agglutinin, a lectin specific for Gal-β(1-3)-GalNAc * Peptide nucleic acid, an artificially synthesized polymer similar to DNA or RNA. * Plastic neutral axis, an engineering value used in plastic section modulus * Pottery Neolithic A, a division of the Pottery Neolithic period in archaeology Organizations * Pakistan National Alliance * Palestinian National Authority, an administrative autonomous government in parts of the West Bank and the Gaza Strip * Project for Nuclear Awareness, a non-profit organization that advocates for the abolition of nuclear weapons, co-founded by John C. Haas * Polish National Alliance, a non-profit organization, the largest Polish – American Fraternal Benefit Society in USA offering life insuranc ...
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