STIRAP Time Evolution
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STIRAP Time Evolution
Stimulated Raman adiabatic passage (STIRAP) is a process that permits transfer of a population between two applicable quantum states via at least two coherent Electromagnetic pulse, electromagnetic (light) pulses. These light pulses drive the transitions of the three level Ʌ atom or multilevel system. The process is a form of state-to-state coherent control. Population transfer in three level Ʌ atom Consider the description of three level Ʌ atom having ground states , g_1\rangle and , g_2\rangle (for simplicity suppose that the energies of the ground states are the same) and excited state , e\rangle . Suppose in the beginning the total population is in the ground state , g_1\rangle . Here the logic for transformation of the population from ground state , g_1\rangle to , g_2\rangle is that initially the unpopulated states , g_2\rangle and , e\rangle couple, afterward superposition of states , g_2\rangle and , e\rangle couple to the state , g_1\rangle . Thereby a state is ...
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STIRAP Time Evolution
Stimulated Raman adiabatic passage (STIRAP) is a process that permits transfer of a population between two applicable quantum states via at least two coherent Electromagnetic pulse, electromagnetic (light) pulses. These light pulses drive the transitions of the three level Ʌ atom or multilevel system. The process is a form of state-to-state coherent control. Population transfer in three level Ʌ atom Consider the description of three level Ʌ atom having ground states , g_1\rangle and , g_2\rangle (for simplicity suppose that the energies of the ground states are the same) and excited state , e\rangle . Suppose in the beginning the total population is in the ground state , g_1\rangle . Here the logic for transformation of the population from ground state , g_1\rangle to , g_2\rangle is that initially the unpopulated states , g_2\rangle and , e\rangle couple, afterward superposition of states , g_2\rangle and , e\rangle couple to the state , g_1\rangle . Thereby a state is ...
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Rabi Frequency
The Rabi frequency is the frequency at which the probability amplitudes of two atomic energy levels fluctuate in an oscillating electromagnetic field. It is proportional to the Transition Dipole Moment of the two levels and to the amplitude (''not'' intensity) of the Electromagnetic field. Population transfer between the levels of such a 2-level system illuminated with light exactly resonant with the difference in energy between the two levels will occur at the Rabi frequency; when the incident light is detuned from this energy difference (detuned from resonance) then the population transfer occurs at the generalized Rabi frequency. The Rabi frequency is a semiclassical concept since it treats the atom as an object with quantized energy levels and the electromagnetic field as a continuous wave. In the context of a nuclear magnetic resonance experiment, the Rabi frequency is the nutation frequency of a sample's net nuclear magnetization vector about a radio-frequency field. (Not ...
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ...
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Dark State
In atomic physics, a dark state refers to a state of an atom or molecule that cannot absorb (or emit) photons. All atoms and molecules are described by quantum states; different states can have different energies and a system can make a transition from one energy level to another by emitting or absorbing one or more photons. However, not all transitions between arbitrary states are allowed. A state that cannot absorb an incident photon is called a dark state. This can occur in experiments using laser light to induce transitions between energy levels, when atoms can spontaneously decay into a state that is not coupled to any other level by the laser light, preventing the atom from absorbing or emitting light from that state. A dark state can also be the result of quantum interference in a three-level system, when an atom is in a coherent superposition of two states, both of which are coupled by lasers at the right frequency to a third state. With the system in a particular superpo ...
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Diagonalization Of A Matrix
In linear algebra, a square matrix A is called diagonalizable or non-defective if it is similar to a diagonal matrix, i.e., if there exists an invertible matrix P and a diagonal matrix D such that or equivalently (Such D are not unique.) For a finite-dimensional vector space a linear map T:V\to V is called diagonalizable if there exists an ordered basis of V consisting of eigenvectors of T. These definitions are equivalent: if T has a matrix representation T = PDP^ as above, then the column vectors of P form a basis consisting of eigenvectors of and the diagonal entries of D are the corresponding eigenvalues of with respect to this eigenvector basis, A is represented by Diagonalization is the process of finding the above P and Diagonalizable matrices and maps are especially easy for computations, once their eigenvalues and eigenvectors are known. One can raise a diagonal matrix D to a power by simply raising the diagonal entries to that power, and the determina ...
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Hamiltonian (quantum Mechanics)
Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian with two-electron nature ** Molecular Hamiltonian, the Hamiltonian operator representing the energy of the electrons and nuclei in a molecule * Hamiltonian (control theory), a function used to solve a problem of optimal control for a dynamical system * Hamiltonian path, a path in a graph that visits each vertex exactly once * Hamiltonian group, a non-abelian group the subgroups of which are all normal * Hamiltonian economic program, the economic policies advocated by Alexander Hamilton, the first United States Secretary of the Treasury See also * Alexander Hamilton (1755 or 1757–1804), American statesman and one of the Founding Fathers of the US * Hamilton (other) Hamilton may refer to: People * Hamilton (name), a common ...
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Rotating Wave Approximation
The rotating-wave approximation is an approximation used in atom optics and magnetic resonance. In this approximation, terms in a Hamiltonian that oscillate rapidly are neglected. This is a valid approximation when the applied electromagnetic radiation is near resonance with an atomic transition, and the intensity is low. Explicitly, terms in the Hamiltonians that oscillate with frequencies \omega_L + \omega_0 are neglected, while terms that oscillate with frequencies \omega_L - \omega_0 are kept, where \omega_L is the light frequency, and \omega_0 is a transition frequency. The name of the approximation stems from the form of the Hamiltonian in the interaction picture, as shown below. By switching to this picture the evolution of an atom due to the corresponding atomic Hamiltonian is absorbed into the system ket, leaving only the evolution due to the interaction of the atom with the light field to consider. It is in this picture that the rapidly oscillating terms mentioned previ ...
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Laser Detuning
In optical physics, laser detuning is the tuning of a laser to a frequency that is slightly off from a quantum system's resonant frequency. When used as a noun, the laser detuning is the difference between the resonance frequency of the system and the laser's optical frequency (or wavelength). Lasers tuned to a frequency below the resonant frequency are called ''red-detuned'', and lasers tuned above resonance are called ''blue-detuned''. Illustration Consider a system with a resonance frequency \omega_0 in the optical frequency range of the electromagnetic spectrum, i.e. with frequency of a few THz to a few PHz, or equivalently with a wavelength in the range of 10 nm to 100 μm. If this system is excited by a laser with a frequency \omega_L close to this value, the laser detuning is then defined as:\Delta \omega\ \overset \ \omega_L - \omega_0 The most common examples of such resonant systems in the optical frequency range are optical cavities (free-space, fiber or microcavities) ...
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Selection Rule
In physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules, in atoms, in atomic nuclei, and so on. The selection rules may differ according to the technique used to observe the transition. The selection rule also plays a role in chemical reactions, where some are formally spin-forbidden reactions, that is, reactions where the spin state changes at least once from reactants to products. In the following, mainly atomic and molecular transitions are considered. Overview In quantum mechanics the basis for a spectroscopic selection rule is the value of the ''transition moment integral''  :\int \psi_1^* \, \mu \, \psi_2 \, \mathrm\tau\,, where \psi_1 and \psi_2 are the wave functions of the two states, "state 1" and "state 2", involved in the transition, and is the transition moment operator. This ...
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Quantum State
In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in time exhausts all that can be predicted about the system's behavior. A mixture of quantum states is again a quantum state. Quantum states that cannot be written as a mixture of other states are called pure quantum states, while all other states are called mixed quantum states. A pure quantum state can be represented by a ray in a Hilbert space over the complex numbers, while mixed states are represented by density matrices, which are positive semidefinite operators that act on Hilbert spaces. Pure states are also known as state vectors or wave functions, the latter term applying particularly when they are represented as functions of position or momentum. For example, when dealing with the energy spectrum of the electron in a hydrogen at ...
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Chandrasekhara Venkata Raman
Sir Chandrasekhara Venkata Raman (; 7 November 188821 November 1970) was an Indian physicist known for his work in the field of light scattering. Using a spectrograph that he developed, he and his student K. S. Krishnan discovered that when light traverses a transparent material, the deflected light changes its wavelength and frequency. This phenomenon, a hitherto unknown type of scattering of light, which they called "modified scattering" was subsequently termed the Raman effect or Raman scattering. Raman received the 1930 Nobel Prize in Physics for the discovery and was the first Asian to receive a Nobel Prize in any branch of science. Born to Tamil Brahmin parents, Raman was a precocious child, completing his secondary and higher secondary education from St Aloysius' Anglo-Indian High School at the ages of 11 and 13, respectively. He topped the bachelor's degree examination of the University of Madras with honours in physics from Presidency College at age 16. His first r ...
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Excited State
In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to an increase in energy level above a chosen starting point, usually the ground state, but sometimes an already excited state. The temperature of a group of particles is indicative of the level of excitation (with the notable exception of systems that exhibit negative temperature). The lifetime of a system in an excited state is usually short: spontaneous or induced emission of a quantum of energy (such as a photon or a phonon) usually occurs shortly after the system is promoted to the excited state, returning the system to a state with lower energy (a less excited state or the ground state). This return to a lower energy level is often loosely described as decay and is the inverse of excitation. Long-lived excited states are often called ...
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