Ronald Sydney Nyholm
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Ronald Sydney Nyholm
Sir Ronald Sydney Nyholm (29 January 1917 – 4 December 1971) was an Australian chemist who was a leading figure in inorganic chemistry in the 1950s and 1960s. Education Born on 29 January 1917 as the fourth in a family of six children. Nyholm's father, Eric Edward Nyholm (1878–1932) was a railway guard. Nyholm's paternal grandfather, Erik Nyholm (1850–1887) was a coppersmith born in Nykarleby in the Swedish-speaking part of Finland, who migrated to Adelaide in 1873. Ronald Nyholm valued his Finnish roots and was particularly proud in his election in 1959 as Corresponding Member of the Finnish Chemical Society. Hailing from the small mining town of Broken Hill, New South Wales, he was early exposed to the role of inorganic chemistry. He attended Burke Ward Public School and Broken Hill High School. Nyholm married Maureen Richardson of Epping, a suburb of Sydney, NSW, at the parish church in Kensington, London on 6 August 1948. After graduating from Broken Hill High ...
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Broken Hill
Broken Hill is an inland mining city in the far west of outback New South Wales, Australia. It is near the border with South Australia on the crossing of the Barrier Highway (A32) and the Silver City Highway (B79), in the Barrier Range. It is 315m above sea level, with a hot desert climate, and an average rainfall of 235mm. The closest major city is Adelaide, the capital of South Australia, which is more than 500km to the southwest and linked via route A32. The town is prominent in Australia's mining, industrial relations and economic history after the discovery of silver ore led to the opening of various mines, thus establishing Broken Hill's recognition as a prosperous mining town well into the 1990s. Despite experiencing a slowing economic situation into the late 1990s and 2000s, Broken Hill itself was listed on the National Heritage List in 2015 and remains Australia's longest running mining town. Broken Hill, historically considered one of Australia's boomtowns, has be ...
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Adelaide
Adelaide ( ) is the capital city of South Australia, the state's largest city and the fifth-most populous city in Australia. "Adelaide" may refer to either Greater Adelaide (including the Adelaide Hills) or the Adelaide city centre. The demonym ''Adelaidean'' is used to denote the city and the residents of Adelaide. The Traditional Owners of the Adelaide region are the Kaurna people. The area of the city centre and surrounding parklands is called ' in the Kaurna language. Adelaide is situated on the Adelaide Plains north of the Fleurieu Peninsula, between the Gulf St Vincent in the west and the Mount Lofty Ranges in the east. Its metropolitan area extends from the coast to the foothills of the Mount Lofty Ranges, and stretches from Gawler in the north to Sellicks Beach in the south. Named in honour of Queen Adelaide, the city was founded in 1836 as the planned capital for the only freely-settled British province in Australia. Colonel William Light, one of Adelaide's foun ...
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Nyholm-Rail Reaction
1,2-Bis(dimethylarsino)benzene (diars) is the organoarsenic compound with the formula CH(As(CH)). The molecule consists of two dimethylarsino groups attached to adjacent carbon centers of a benzene ring. It is a chelating ligand in coordination chemistry. This colourless oil is commonly abbreviated "diars." Coordination chemistry Related, but non-chelating organoarsenic ligands include triphenylarsine and trimethylarsine. Work on diars preceded the development of the chelating diphosphine ligands such as dppe, which are now prevalent in homogeneous catalysis. Diars is a bidentate ligand used in coordination chemistry. It was first described in 1939, but was popularized by R. S. Nyholm for its ability to stabilize metal complexes with unusual oxidation states and coordination numbers, e.g. TiCl(diars). High coordination numbers arise because diars is fairly compact and the As-M bonds are long, which relieves crowding at the metal center. In terms of stabilizing unusual oxidation ...
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Osmium
Osmium (from Greek grc, ὀσμή, osme, smell, label=none) is a chemical element with the symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mostly in platinum ores. Osmium is the densest naturally occurring element. When experimentally measured using X-ray crystallography, it has a density of . Manufacturers use its alloys with platinum, iridium, and other platinum-group metals to make fountain pen nib tipping, electrical contacts, and in other applications that require extreme durability and hardness. Osmium is among the rarest elements in the Earth's crust, making up only 50 parts per trillion ( ppt). It is estimated to be about 0.6 parts per billion in the universe and is therefore the rarest precious metal. Characteristics Physical properties Osmium has a blue-gray tint and is the densest stable element; it is approximately twice as dense as lead and narrowly denser tha ...
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Iridium
Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of as defined by experimental X-ray crystallography. It is one of the most corrosion-resistant metals, even at temperatures as high as . However, corrosion-resistance is not quantifiable in absolute terms; although only certain molten salts and halogens are corrosive to solid iridium, finely divided iridium dust is much more reactive and can be flammable, whereas gold dust is not flammable but can be attacked by substances that iridium resists, such as aqua regia. Iridium was discovered in 1803 among insoluble impurities in natural platinum. Smithson Tennant, the primary discoverer, named it after the Greek goddess Iris, personification of the rainbow, because of the striking and diverse colors of its salts. Iridium is one of the rarest ...
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Rhodium
Rhodium is a chemical element with the symbol Rh and atomic number 45. It is a very rare, silvery-white, hard, corrosion-resistant transition metal. It is a noble metal and a member of the platinum group. It has only one naturally occurring isotope: 103Rh. Naturally occurring rhodium is usually found as a free metal or as an alloy with similar metals and rarely as a chemical compound in minerals such as bowieite and rhodplumsite. It is one of the rarest and most valuable precious metals. Rhodium is found in platinum or nickel ores with the other members of the platinum group metals. It was discovered in 1803 by William Hyde Wollaston in one such ore, and named for the rose color of one of its chlorine compounds. The element's major use (consuming about 80% of world rhodium production) is as one of the catalysts in the three-way catalytic converters in automobiles. Because rhodium metal is inert against corrosion and most aggressive chemicals, and because of its rarity, rhodium ...
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1,2-Bis(dimethylarsino)benzene
1,2-Bis(dimethylarsino)benzene (diars) is the organoarsenic compound with the formula CH(As(CH)). The molecule consists of two di methylarsino groups attached to adjacent carbon centers of a benzene ring. It is a chelating ligand in coordination chemistry. This colourless oil is commonly abbreviated "diars." Coordination chemistry Related, but non-chelating organoarsenic ligands include triphenylarsine and trimethylarsine. Work on diars preceded the development of the chelating diphosphine ligands such as dppe, which are now prevalent in homogeneous catalysis. Diars is a bidentate ligand used in coordination chemistry. It was first described in 1939, but was popularized by R. S. Nyholm for its ability to stabilize metal complexes with unusual oxidation states and coordination numbers, e.g. TiCl(diars). High coordination numbers arise because diars is fairly compact and the As-M bonds are long, which relieves crowding at the metal center. In terms of stabilizing unusual oxidati ...
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Organoarsenic Chemistry
Organoarsenic chemistry is the chemistry of compounds containing a chemical bond between arsenic and carbon. A few organoarsenic compounds, also called "organoarsenicals," are produced industrially with uses as insecticides, herbicides, and fungicides. In general these applications are declining in step with growing concerns about their impact on the environment and human health. The parent compounds are arsane and arsenic acid. Despite their toxicity, organoarsenic biomolecules are well known. History 140px, Cacodyl (tetramethyldiarsine) was one of the first organoarsenic compounds. Surprising for an area now considered of minor importance, organoarsenic chemistry played a prominent role in the history of the field of chemistry. The oldest known organoarsenic compound, the foul smelling cacodyl was reported in "cacodyl" (1760) and is sometimes classified as the first synthetic organometallic compound. The compound Salvarsan was one of the first pharmaceuticals, earning a Nobel ...
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Transition Metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can use d orbitals as valence orbitals to form chemical bonds. The lanthanide and actinide elements (the f-block) are called inner transition metals and are sometimes considered to be transition metals as well. Since they are metals, they are lustrous and have good electrical and thermal conductivity. Most (with the exception of group 11 and group 12) are hard and strong, and have high melting and boiling temperatures. They form compounds in any of two or more different oxidation states and bind to a variety of ligands to form coordination complexes that are often coloured. They form many useful alloys and are often employed as catalysts in elemental form or in compounds such as coordination complexes and oxides. Most are strongly param ...
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Royal Society Of New South Wales
The Royal Society of New South Wales is a learned society based in Sydney, Australia. The Governor of New South Wales is the vice-regal patron of the Society. The Society was established as the Philosophical Society of Australasia on 27 June 1821. In 1850, after a period of informal activity, the Society was revived and its name became the Australian Philosophical Society and, in 1856, the Philosophical Society of New South Wales. The Society was granted Royal Assent on 12 December 1866 and at that time was renamed the Royal Society of New South Wales. Membership is open to any person interested in the promotion of studies in Science, Art, Literature and Philosophy. Fellowship and Distinguished Fellowship are by election, and may be conferred on leaders in their fields. The Society is based in Sydney and has an active branches in Mittagong in the Southern Highlands of NSW. Regular monthly meetings and public lectures are well attended by both members and visitors. The Society ...
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Battle Of Broken Hill
The Battle of Broken Hill was a fatal incident which took place in Australia near Broken Hill, New South Wales, on 1 January 1915. Two men shot dead four people and wounded seven more, before being killed by police and military officers. Though politically and religiously motivated, the men were not members of any sanctioned armed force and the attacks were criminal. The two men were later identified as Muslim "Ghans" from colonial India (some sources incorrectly identify them as Turkish).e.g"Battle of Broken Hill", '' George Negus Tonight'', ABC-TV, 23 February 2004 The assailants The attackers were both former camel-drivers working at Broken Hill. They were Badsha Mahommed Gool (born c. 1874), an ice-cream vendor, and Mullah Abdullah (born c. 1854), a local imam and halal butcher. Gool's ice-cream cart was well known in town and was used to transport the men to the attack site. They also fashioned a home-made Ottoman flag which they flew. There appears to have been ...
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Silverton Tramway
The Silverton Tramway was a 58-kilometre-long railway line running from Cockburn on the South Australian state border to Broken Hill in New South Wales. Operating between 1888 and 1970, it served the mines in Broken Hill, and formed the link between the New South Wales Government Railways and the narrow gauge South Australian Railways lines. It was owned and operated by the Silverton Tramway Company (STC). The Silverton Tramway was one of only two privately-owned railways in New South Wales, originally founded to transport ore from local mines in the Broken Hill and Silverton region into South Australia. The company soon branched out, not only carrying ore from the mines but freighted other goods and offered a passenger service which eventually accounted for a third of their business. Text was copied from this source, which is available under Creative Commons Attribution 4.0 International License From 1888 to 1970 it was critical to the economic functioning of Broken ...
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