Rhodinol
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Rhodinol
Rhodinol is the chemical compound 3,7-dimethyloct-7-en-1-ol. As the (3S) isomer it is CAS 6812-78-8, and as the racemate it is CAS 141-25-3. In the field of perfumery materials, the term may refer to L-citronellol, to mixtures comprising mostly L- or racemic citronellol and geraniol, or to mixtures comprising mostly racemic 3,7-dimethyloct-7-en-1-ol and racemic citronellol. Two example synthetic Rhodinol products are Rhodinol 70, a racemic mixture comprising 40-60% 3,7-dimethyloct-7-en-1-ol and 40-60% citronellol, and Sigma-Aldrich Rhodinol, which consists of L-citronellol and geraniol. Rhodinol is also provided in perfumery in natural grades as materials extracted from geranium or citronella, comprising principally citronellol and geraniol. Rhodinol products are used in cosmetics and perfumery to impart flowery odors, particularly but not limited to being a component of rosy odor. 3,7-Dimethyloct-7-en-1-ol does not appear substantively in nature.
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Citronellol
Citronellol, or dihydrogeraniol, is a natural acyclic monoterpenoid. Both enantiomers occur in nature. (+)-Citronellol, which is found in citronella oils, including ''Cymbopogon nardus'' (50%), is the more common isomer. (−)-Citronellol is widespread, but particularly abundant in the oils of rose (18–55%) and ''Pelargonium'' geraniums. Preparation Several million kilograms of citronellol are produced annually. It is mainly obtained by hydrogenation of geraniol or nerol over copper chromite catalyst. Homogeneous catalysts are used for the production of enantiomers. Citronellene is also a precursor. Uses Citronellol is used in perfumes and as a fragrance in cleaning products. In many applications, one of the enantiomers is preferred. It is a component of citronella oil, an insect repellant. Citronellol is used as a raw material for the production of rose oxide. It is also a precursor to many commercial and potential fragrances such as citronellol acetate, citronellyl ...
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Geraniol
Geraniol is a monoterpenoid and an alcohol. It is the primary component of citronella oil and is a primary component of rose oil, palmarosa oil. It is a colorless oil, although commercial samples can appear yellow. It has low solubility in water, but it is soluble in common organic solvents. The functional group derived from geraniol (in essence, geraniol lacking the terminal −OH) is called geranyl. Uses and occurrence In addition to rose oil, palmarosa oil, and citronella oil, it also occurs in small quantities in geranium, lemon, and many other essential oils. With a rose-like scent, it is commonly used in perfumes. It is used in flavors such as peach, raspberry, grapefruit, red apple, plum, lime, orange, lemon, watermelon, pineapple, and blueberry. Geraniol is produced by the scent glands of honeybees to mark nectar-bearing flowers and locate the entrances to their hives. It is also commonly used as an insect repellent, especially for mosquitoes. The scent of geraniol ...
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Pelargonium
''Pelargonium'' () is a genus of flowering plants that includes about 280 species of perennials, succulents, and shrubs, commonly called geraniums, pelargoniums, or storksbills. '' Geranium'' is also the botanical name and common name of a separate genus of related plants, also known as cranesbills. Both genera belong to the family Geraniaceae. Carl Linnaeus originally included all the species in one genus, ''Geranium'', and they were later separated into two genera by Charles Louis L'Héritier de Brutelle in 1789. While ''Geranium'' species are mostly temperate herbaceous plants, dying down in winter, ''Pelargonium'' species are evergreen perennials indigenous to warm temperate and tropical regions of the world, with many species in southern Africa. They are drought and heat tolerant, but can tolerate only minor frosts. Some species are extremely popular garden plants, grown as houseplants and bedding plants in temperate regions. They have a long flowering period, with flowers m ...
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Citronella Oil
Citronella oil Citronella oil is an essential oil obtained from the leaves and stems of different species of '' Cymbopogon'' (lemongrass). The oil is used extensively as a source of perfumery chemicals such as citronellal, citronellol, and geraniol. These chemicals find extensive use in soap, candles and incense, perfumery, cosmetic, and flavouring industries throughout the world. Citronella oil is also a plant-based insect repellent and has been registered for this use in the United States since 1948. The United States Environmental Protection Agency considers oil of citronella as a biopesticide with a non-toxic mode of action. Citronella oil has strong antifungal properties. Types Citronella oil is classified in trade into two chemotypes:Chang, Yu Shyun, 2007, ''8 Map species from Malaysia for ICS,'' Forest Research Institute Malaysia, Workshop on NFP, 28–29 May 2007, Nanchang, PR China Ceylon type * CAS: 89998-15-2 * CAS: 8000-29-1 * EINECS: 289-753-6 * FEMA: 2308 * Co ...
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Perfume Allergy
Perfume intolerance or perfume allergy is a condition wherein people exhibit sensitivity or allergic reactions to ingredients in some perfumes and some other fragrances. It is a form of multiple chemical sensitivity, a more general phenomenon for this diagnosis. Symptoms Symptoms depend on each person's allergies and each perfume's or fragrance's ingredients. Symptoms may include allergic contact dermatitis, asthma attacks, headaches, and others. The most common allergic reactions to perfume or fragrances added to products is contact dermatitis, though other symptoms may occur, including allergic conjunctivitis. The diagnosis of the causal allergen is made by patch testing with a mixture of fragrance ingredients, the fragrance mix. This gives a positive patch-test reaction in about 10% of tested patients with eczema, and the most recent estimates show that 1.7–4.1% of the general population are sensitized to ingredients of the fragrance mix. Two studies show that inhalant- ...
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Monoterpenes
Monoterpenes are a class of terpenes that consist of two isoprene units and have the molecular formula C10H16. Monoterpenes may be linear (acyclic) or contain rings (monocyclic and bicyclic). Modified terpenes, such as those containing oxygen functionality or missing a methyl group, are called monoterpenoids. Monoterpenes and monoterpenoids are diverse. They have relevance to the pharmaceutical, cosmetic, agricultural, and food industries. Biosynthesis Monoterpenes are derived biosynthetically from units of isopentenyl pyrophosphate, which is formed from acetyl-CoA via the intermediacy of mevalonic acid in the HMG-CoA reductase pathway. An alternative, unrelated biosynthesis pathway of IPP is known in some bacterial groups and the plastids of plants, the so-called MEP-(2-methyl-D-erythritol-4-phosphate) pathway, which is initiated from Pentose, C5 sugars. In both pathways, IPP is isomerized to DMAPP by the enzyme isopentenyl pyrophosphate isomerase. Geranyl pyrophosphate is the pr ...
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