Remix Fuel
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Remix Fuel
Remix Fuel was developed in Russia to make use of Mixed Recycled Uranium and Plutonium from spent nuclear fuel to manufacture fresh fuel suitable for widespread use in Russian reactor designs. Compared to "conventional" MOX-fuel MOX or Mixed Oxide Fuel as deployed in some western European and East Asian nations generally consists of depleted Uranium mixed with between 4% and 7% reactor grade plutonium. Only a few Generation II and about half of Generation III reactor designs are MOX fuel compliant allowing them to use a 100% MOX fuel load with no safety concerns. Nuclear physics background However all moderated reactors using lightly enriched Uranium fuel produce Plutonium in the course of normal operation as Uranium-238 (typically 94% to 97% of the uranium content in lightly enriched uranium) captures neutrons and undergoes successive beta decays until it is nuclear transmutation, transmuted to plutonium-239. This internally produced Plutonium increases in percentage until it is ...
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Mixed Oxide Fuel
Mixed oxide fuel, commonly referred to as MOX fuel, is nuclear fuel that contains more than one oxide of fissile material, usually consisting of plutonium blended with natural uranium, reprocessed uranium, or depleted uranium. MOX fuel is an alternative to the low-enriched uranium (LEU) fuel used in the light-water reactors that predominate nuclear power generation. For example, a mixture of 7% plutonium and 93% natural uranium reacts similarly, although not identically, to LEU fuel (3 to 5% uranium-235). MOX usually consists of two phases, UO2 and PuO2, and/or a single phase solid solution (U,Pu)O2. The content of PuO2 may vary from 1.5 wt.% to 25–30 wt.% depending on the type of nuclear reactor. One attraction of MOX fuel is that it is a way of utilizing surplus weapons-grade nuclear material, weapons-grade plutonium, an alternative to storage of surplus plutonium, which would need to be secured against the risk of theft for use in nuclear weapons. On the other hand, some st ...
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Neutron Poison
In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable effect. However, neutron-absorbing materials, also called poisons, are intentionally inserted into some types of reactors in order to lower the high reactivity of their initial fresh fuel load. Some of these poisons deplete as they absorb neutrons during reactor operation, while others remain relatively constant. The capture of neutrons by short half-life fission products is known as reactor poisoning; neutron capture by long-lived or stable fission products is called reactor slagging. Transient fission product poisons Some of the fission products generated during nuclear reactions have a high neutron absorption capacity, such as xenon-135 (microscopic cross-section σ = 2,000,000 barns (b); up to 3 million barns in reactor c ...
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Fuels
A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as nuclear energy (via nuclear fission and nuclear fusion). The heat energy released by reactions of fuels can be converted into mechanical energy via a heat engine. Other times, the heat itself is valued for warmth, cooking, or industrial processes, as well as the illumination that accompanies combustion. Fuels are also used in the cells of organisms in a process known as cellular respiration, where organic molecules are oxidized to release usable energy. Hydrocarbons and related organic molecules are by far the most common source of fuel used by humans, but other substances, including radioactive metals, are also utilized. Fuels are contrasted with other substances or de ...
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VVER
The water-water energetic reactor (WWER), or VVER (from russian: водо-водяной энергетический реактор; transliterates as ; ''water-water power reactor'') is a series of pressurized water reactor designs originally developed in the Soviet Union, and now Russia, by OKB Gidropress. The idea of such a reactor was proposed at the Kurchatov Institute by Savely Moiseevich Feinberg. VVER were originally developed before the 1970s, and have been continually updated. As a result, the name VVER is associated with a wide variety of reactor designs spanning from generation I reactors to modern generation III+ reactor designs. Power output ranges from 70 to 1300 MWe, with designs of up to 1700 MWe in development. The first prototype VVER-210 was built at the Novovoronezh Nuclear Power Plant. VVER power stations have mostly been installed in Russia and the former Soviet Union, but also in China, the Czech Republic, Finland, Germany, Hungary, Slovakia, Bulgaria ...
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PUREX
PUREX (plutonium uranium reduction extraction) is a chemical method used to purify fuel for nuclear reactors or nuclear weapons. PUREX is the ''de facto'' standard aqueous nuclear reprocessing method for the recovery of uranium and plutonium from used nuclear fuel (spent nuclear fuel, or irradiated nuclear fuel). It is based on liquid–liquid extraction ion-exchange. PUREX is applied to spent nuclear fuel, which consists primarily of very high atomic-weight ( actinoid or "actinide") elements (e.g. uranium, plutonium, americium) along with smaller amounts of material composed of lighter atoms, notably the fission products produced by reactor operation. The actinoid elements in this case consist primarily of the unconsumed remains of the original fuel (typically U-235, U-238, and/or Pu-239). Chemical process The fuel is first dissolved in nitric acid at a concentration around 7 M. Solids are removed by filtration to avoid the formation of emulsions, referred to ...
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Pyroprocessing
Pyroprocessing (from Greek Πυρος = ''fire'') is a process in which materials are subjected to high temperatures (typically over 800 °C) in order to bring about a chemical or physical change. Pyroprocessing includes such terms as ore-roasting, calcination and sintering. Equipment for pyroprocessing includes kilns, electric arc furnaces and reverberatory furnaces. Cement manufacturing is a very common example of pyroprocessing. The raw material mix (raw meal) is fed to a kiln where pyroprocessing takes place. As with most industries, pyroprocessing is the most energy-intensive part of the industrial process. Recycling used nuclear fuel through pyroprocessing Argonne National Laboratory pioneered the development of pyrochemical processing, or pyroprocessing, a high-temperature method of recycling reactor waste into fuel, demonstrating it paired with the EBR-II and then proposed commercializing it in the Integral Fast Reactor. The latter was cancelled by the Clinton Adm ...
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Natural Uranium
Natural uranium (NU or Unat) refers to uranium with the same isotopic ratio as found in nature. It contains 0.711% uranium-235, 99.284% uranium-238, and a trace of uranium-234 by weight (0.0055%). Approximately 2.2% of its radioactivity comes from uranium-235, 48.6% from uranium-238, and 49.2% from uranium-234. Natural uranium can be used to fuel both low- and high-power nuclear reactors. Historically, graphite-moderated reactors and heavy water-moderated reactors have been fueled with natural uranium in the pure metal (U) or uranium dioxide (UO2) ceramic forms. However, experimental fuelings with uranium trioxide (UO3) and triuranium octaoxide (U3O8) have shown promise. The 0.72% uranium-235 is not sufficient to produce a self-sustaining critical chain reaction in light water reactors or nuclear weapons; these applications must use enriched uranium. Nuclear weapons take a concentration of 90% uranium-235, and light water reactors require a concentration of roughly 3% ...
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Uranium-235
Uranium-235 (235U or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exists in nature as a primordial nuclide. Uranium-235 has a half-life of 703.8 million years. It was discovered in 1935 by Arthur Jeffrey Dempster. Its fission cross section for slow thermal neutrons is about 584.3±1 barns. For fast neutrons it is on the order of 1 barn. Most but not all neutron absorptions result in fission; a minority result in neutron capture forming uranium-236. Natural decay chain :\begin \ce \begin \ce \\ \ce \end \ce \\ \ce \begin \ce \\ \ce \end \ce \end Fission properties The fission of one atom of uranium-235 releases () inside the reactor. That corresponds to 19.54 TJ/ mol, or 83.14 TJ/kg.
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Reprocessed Uranium
Reprocessed uranium (RepU) is the uranium recovered from nuclear reprocessing, as done commercially in France, the UK and Japan and by nuclear weapons states' military plutonium production programs. This uranium makes up the bulk of the material separated during reprocessing. Commercial LWR spent nuclear fuel contains on average (excluding cladding) only four percent plutonium, minor actinides and fission products by weight. Despite it often containing more fissile material than natural uranium, reuse of reprocessed uranium has not been common because of low prices in the uranium market of recent decades, and because it contains undesirable isotopes of uranium. Given sufficiently high uranium prices, it is feasible for reprocessed uranium to be re- enriched and reused. A higher enrichment level is required to compensate for the 236U which is lighter than 238U and therefore concentrates in the enriched product. As enrichment concentrates lighter isotopes on the "enriched" side ...
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Nuclear Reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the reprocessed plutonium was recycled back into MOX nuclear fuel for thermal reactors. The reprocessed uranium, also known as the spent fuel material, can in principle also be re-used as fuel, but that is only economical when uranium supply is low and prices are high. A breeder reactor is not restricted to using recycled plutonium and uranium. It can employ all the actinides, closing the nuclear fuel cycle and potentially multiplying the energy extracted from natural uranium by about 60 times. Reprocessing must be highly controlled and carefully executed in advanced facilities by highly specialized personnel. Fuel bundles which arrive at the sites from nuclear power plants (after having cooled down for several years) are completely dis ...
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Fission Product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release of heat energy (kinetic energy of the nuclei), and gamma rays. The two smaller nuclei are the ''fission products''. (See also Fission products (by element)). About 0.2% to 0.4% of fissions are ternary fissions, producing a third light nucleus such as helium-4 (90%) or tritium (7%). The fission products themselves are usually unstable and therefore radioactive. Due to being relatively neutron-rich for their atomic number, many of them quickly undergo beta decay. This releases additional energy in the form of beta particles, antineutrinos, and gamma rays. Thus, fission events normally result in beta and gamma radiation, even though this radiation is not produced directly by the fission event itself. The produced radionuclides have va ...
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Depleted Uranium
Depleted uranium (DU; also referred to in the past as Q-metal, depletalloy or D-38) is uranium with a lower content of the fissile isotope than natural uranium.: "Depleted uranium possesses only 60% of the radioactivity of natural uranium, having been 'depleted' of much of its most highly radioactive U234 and U235 isotopes." Natural uranium contains about , while the DU used by the U.S. Department of Defense contains or less. The less radioactive and non-fissile constitutes the main component of depleted uranium. Uses of DU take advantage of its very high density of ( denser than lead). Civilian uses include counterweights in aircraft, radiation shielding in medical radiation therapy and industrial radiography equipment, and containers for transporting radioactive materials. Military uses include Vehicle armour, armor plating and Armor-piercing shot and shell, armor-piercing projectiles. Most depleted uranium arises as a by-product of the production of enriched uranium f ...
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