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Random Graph Theory Of Gelation
Random graph theory of gelation is a mathematical theory for sol–gel processes. The theory is a collection of results that generalise the Flory–Stockmayer theory, and allow identification of the gel point, gel fraction, size distribution of polymers, molar mass distribution and other characteristics for a set of many polymerising monomers carrying arbitrary numbers and types of reactive functional groups. The theory builds upon the notion of the random graph, introduced by mathematicians Paul Erdős and Alfréd Rényi, and independently by Edgar Gilbert in late 1950's, as well as on the generalisation of this concept known as the random graph with a fixed degree sequence. The theory has been originally developed to explain step-growth polymerisation, and adaptations to other types of polymerisation now exist. Along with providing theoretical results the theory is also constructive. It indicates that the graph-like structures resulting from polymerisation can be sampled with ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sol–gel Process
In materials science, the sol–gel process is a method for producing solid materials from small molecules. The method is used for the fabrication of metal oxides, especially the oxides of silicon (Si) and titanium (Ti). The process involves conversion of monomers into a colloidal solution ('' sol'') that acts as the precursor for an integrated network (or ''gel'') of either discrete particles or network polymers. Typical precursors are metal alkoxides. Sol-gel process is used to produce ceramic nanoparticles. Stages In this chemical procedure, a " sol" (a colloidal solution) is formed that then gradually evolves towards the formation of a gel-like diphasic system containing both a liquid phase and solid phase whose morphologies range from discrete particles to continuous polymer networks. In the case of the colloid, the volume fraction of particles (or particle density) may be so low that a significant amount of fluid may need to be removed initially for the gel-like properti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Step-growth Polymerisation
Step-growth polymerization refers to a type of polymerization mechanism in which bi-functional or multifunctional monomers react to form first dimers, then trimers, longer oligomers and eventually long chain polymers. Many naturally occurring and some synthetic polymers are produced by step-growth polymerization, e.g. polyesters, polyamides, polyurethanes, etc. Due to the nature of the polymerization mechanism, a high extent of reaction is required to achieve high molecular weight. The easiest way to visualize the mechanism of a step-growth polymerization is a group of people reaching out to hold their hands to form a human chain—each person has two hands (= reactive sites). There also is the possibility to have more than two reactive sites on a monomer: In this case branched polymers production take place. IUPAC deprecates the term step-growth polymerization and recommends use of the terms polyaddition, when the propagation steps are addition reactions and no molecules are ev ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymerization Reactions
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many forms of polymerization and different systems exist to categorize them. In chemical compounds, polymerization can occur via a variety of reaction mechanisms that vary in complexity due to the functional groups present in the reactants and their inherent steric effects. In more straightforward polymerizations, alkenes form polymers through relatively simple radical reactions; in contrast, reactions involving substitution at a carbonyl group require more complex synthesis due to the way in which reactants polymerize. Alkanes can also be polymerized, but only with the help of strong acids. As alkenes can polymerize in somewhat straightforward radical reactions, they form useful compounds such as polyethylene and polyvinyl chloride (PVC), whic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molar Mass Distribution
The molar mass distribution (or molecular weight distribution) describes the relationship between the number of moles of each polymer species (Ni) and the molar mass (Mi) of that species. In linear polymers, the individual polymer chains rarely have exactly the same degree of polymerization and molar mass, and there is always a distribution around an average value. The molar mass distribution of a polymer may be modified by polymer fractionation. Definitions of molar mass average Different average values can be defined, depending on the statistical method applied. In practice, four averages are used, representing the weighted mean taken with the mole fraction, the weight fraction, and two other functions which can be related to measured quantities: *''Number average molar mass'' (Mn), also loosely referred to as ''number average molecular weight'' (NAMW). *''Mass average molar mass'' (Mw), where ''w'' stands for weight; also commonly referred to as ''weight average'' or ''weight ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rate Equation
In chemistry, the rate law or rate equation for a reaction is an equation that links the initial or forward reaction rate with the concentrations or pressures of the reactants and constant parameters (normally rate coefficients and partial reaction orders). For many reactions, the initial rate is given by a power law such as :v_0\; =\; k mathrmx mathrmy where and express the concentration of the species and usually in moles per liter (molarity, ). The exponents and are the partial ''orders of reaction'' for and and the ''overall'' reaction order is the sum of the exponents. These are often positive integers, but they may also be zero, fractional, or negative. The constant is the reaction rate constant or ''rate coefficient'' of the reaction. Its value may depend on conditions such as temperature, ionic strength, surface area of an adsorbent, or light irradiation. If the reaction goes to completion, the rate equation for the reaction rate v\; =\; k cex cey applies throug ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Degree Distribution
In the study of graphs and networks, the degree of a node in a network is the number of connections it has to other nodes and the degree distribution is the probability distribution of these degrees over the whole network. Definition The degree of a node in a network (sometimes referred to incorrectly as the connectivity) is the number of connections or edges the node has to other nodes. If a network is directed, meaning that edges point in one direction from one node to another node, then nodes have two different degrees, the in-degree, which is the number of incoming edges, and the out-degree, which is the number of outgoing edges. The degree distribution ''P''(''k'') of a network is then defined to be the fraction of nodes in the network with degree ''k''. Thus if there are ''n'' nodes in total in a network and ''n''''k'' of them have degree ''k'', we have P(k) = \frac. The same information is also sometimes presented in the form of a ''cumulative degree distribution'', the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Step Growth
Step(s) or STEP may refer to: Common meanings * Steps, making a staircase * Walking * Dance move * Military step, or march ** Marching Arts Films and television * ''Steps'' (TV series), Hong Kong * ''Step'' (film), US, 2017 Literature * ''Steps'' (novel), by Jerzy Kosinski * Systematic Training for Effective Parenting, a book series Music * Step (music), pitch change * Steps (pop group), UK * ''Step'' (Kara album), 2011, South Korea ** "Step" (Kara song) * ''Step'' (Meg album), 2007, Japan * "Step" (Vampire Weekend song) * "Step" (ClariS song) Organizations * Society of Trust and Estate Practitioners, international professional body for advisers who specialise in inheritance and succession planning * Board on Science, Technology, and Economic Policy of the U.S. National Academies * Solving the E-waste Problem, a UN organization Science, technology, and mathematics * Step (software), a physics simulator in KDE * Step function, in mathematics * Striatal-enriched prote ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Configuration Model
In network science, the configuration model is a method for generating random networks from a given degree sequence. It is widely used as a reference model for real-life social networks, because it allows the modeler to incorporate arbitrary degree distributions. Rationale for the model In the configuration model, the degree of each vertex is pre-defined, rather than having a probability distribution from which the given degree is chosen. As opposed to the Erdős–Rényi model, the degree sequence of the configuration model is not restricted to have a Poisson distribution, the model allows the user to give the network any desired degree distribution. Algorithm The following algorithm describes the generation of the model: # Take a degree sequence, i. e. assign a degree k_ito each vertex. The degrees of the vertices are represented as half-links or stubs. The sum of stubs must be even in order to be able to construct a graph (\sum k_i = 2m ). The degree sequence can be dr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Edgar Gilbert
Edgar Nelson Gilbert (July 25, 1923 – June 15, 2013) was an American mathematician and coding theorist, a longtime researcher at Bell Laboratories whose accomplishments include the Gilbert–Varshamov bound in coding theory, the Gilbert–Elliott model of bursty errors in signal transmission, and the Erdős–Rényi model for random graphs. Biography Gilbert was born in 1923 in Woodhaven, New York. He did his undergraduate studies in physics at Queens College, City University of New York, graduating in 1943. He taught mathematics briefly at the University of Illinois at Urbana–Champaign but then moved to the Radiation Laboratory at the Massachusetts Institute of Technology, where he designed radar antennas from 1944 to 1946. He finished a Ph.D. in physics at MIT in 1948, with a dissertation entitled ''Asymptotic Solution of Relaxation Oscillation Problems'' under the supervision of Norman Levinson, and took a job at Bell Laboratories where he remained for the rest of his caree ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flory–Stockmayer Theory
Flory–Stockmayer theory is a theory governing the cross-linking and gelation of step-growth polymers.Flory, P.J. (1941). "Molecular Size Distribution in Three Dimensional Polymers I. Gelation". ''J. Am. Chem. Soc.'' 63, 3083 The Flory-Stockmayer theory represents an advancement from the Carothers equation, allowing for the identification of the gel point for polymer synthesis not at stoichiometric balance. The theory was initially conceptualized by Paul Flory in 1941 and then was further developed by Walter Stockmayer in 1944 to include cross-linking with an arbitrary initial size distribution.Stockmayer, Walter H.(1944). "Theory of Molecular Size Distribution and Gel Formation in Branched Polymers II. General Cross Linking". ''Journal of Chemical Physics.'' 12,4, 125 The Flory-Stockmayer theory was the first theory investigating percolation processes. Flory–Stockmayer theory is a special case of random graph theory of gelation. History Gelation occurs when a polymer form ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alfréd Rényi
Alfréd Rényi (20 March 1921 – 1 February 1970) was a Hungarian mathematician known for his work in probability theory, though he also made contributions in combinatorics, graph theory, and number theory. Life Rényi was born in Budapest to Artúr Rényi and Borbála Alexander; his father was a mechanical engineer, while his mother was the daughter of philosopher and literary critic Bernhard Alexander; his uncle was Franz Alexander, a Hungarian-American psychoanalyst and physician. He was prevented from enrolling in university in 1939 due to the anti-Jewish laws then in force, but enrolled at the University of Budapest in 1940 and finished his studies in 1944. At this point, he was drafted to forced labour service, from which he escaped. He then completed his PhD in 1947 at the University of Szeged, under the advisement of Frigyes Riesz. He married Katalin Schulhof (who used Kató Rényi as her married name), herself a mathematician, in 1946; their daughter Zsuzsanna was bor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Paul Erdős
Paul Erdős ( hu, Erdős Pál ; 26 March 1913 – 20 September 1996) was a Hungarian mathematician. He was one of the most prolific mathematicians and producers of mathematical conjectures of the 20th century. pursued and proposed problems in discrete mathematics, graph theory, number theory, mathematical analysis, approximation theory, set theory, and probability theory. Much of his work centered around discrete mathematics, cracking many previously unsolved problems in the field. He championed and contributed to Ramsey theory, which studies the conditions in which order necessarily appears. Overall, his work leaned towards solving previously open problems, rather than developing or exploring new areas of mathematics. Erdős published around 1,500 mathematical papers during his lifetime, a figure that remains unsurpassed. He firmly believed mathematics to be a social activity, living an itinerant lifestyle with the sole purpose of writing mathematical papers with other mathem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
