R-407A
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R-407A
R-407A is a mixture of gasses used as a refrigerant. It is a zeotropic blend of difluoromethane (HFC-32), pentafluoroethane (HFC-125) and 1,1,1,2-tetrafluoroethane (HFC-134a). R-407A was developed as a close match to R-22's capacities and flow rates, making it well suited as an energy efficient retrofit for R-22 in medium and low temperature refrigeration systems for supermarket and food storage applications, but not for air conditioning systems or those with flooded evaporators. It must be used with synthetic oils. Its global warming potential Global warming potential (GWP) is the heat absorbed by any greenhouse gas in the atmosphere, as a multiple of the heat that would be absorbed by the same mass of carbon dioxide (). GWP is 1 for . For other gases it depends on the gas and the time f ... is 2107. References {{Reflist Refrigerants ...
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Refrigerant
A refrigerant is a working fluid used in the heat pump and refrigeration cycle, refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are heavily regulated due to their toxicity, flammability and the contribution of CFC and HCFC refrigerants to ozone depletion and that of HFC refrigerants to climate change. Refrigerants are used in a Direct Expansion (DX) system to transfer energy from one environment to another, typically from inside a building to outside (or vice versa) commonly known as an "air conditioner" or "heat pump". Refrigerants can carry per kg 10 times more energy than water and 50 times more than air. Refrigerants are controlled substances due to 1) High Pressures (100-145 psi), 2) Extreme temperatures (-50°C to 145°C), 3) Flammability A1 class non-flammable, A2/A2L class flammable & A3 class extremely flammable/explosive and 4) Toxicity B1-low ...
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Difluoromethane
Difluoromethane, also called difluoromethylene, HFC-32 Methylene Fluoride or R-32, is an organic compound of the dihalogenoalkane variety. It has the formula of CH2F2. It is a colorless gas in the ambient atmosphere and is slightly soluble in the water, with a high thermal stability. Due to the low melting and boiling point, (-136.0 °C and -51.6 °C respectively) contact with this compound may result in frostbite. In the United States, the Clean Air Act Section 111 on Volatile Organic Compounds (VOC) has listed difluoromethane as an exception (since 1997) from the definition of VOC due to its low production of tropospheric ozone. Difluoromethane is commonly used in endothermic processes such as refrigeration or air conditioning. Synthesis Difluoromethane is primarily synthesized via batch processes, by the reaction of dichloromethane and hydrogen fluoride (HF), in the liquid phase using SbCl5 as a catalyst. Due to hydrogen fluoride's hazardous properties, a new synt ...
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Chlorodifluoromethane
Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon (HCFC). This colorless gas is better known as HCFC-22, or R-22, or . It was commonly used as a propellant and refrigerant. These applications were phased out under the Montreal Protocol in developed countries in 2020 due to the compound's ozone depletion potential (ODP) and high global warming potential (GWP), and in developing countries this process will be completed by 2030. R-22 is a versatile intermediate in industrial organofluorine chemistry, e.g. as a precursor to tetrafluoroethylene. Production and current applications Worldwide production of R-22 in 2008 was about 800Gg per year, up from about 450Gg per year in 1998, with most production in developing countries. R-22 use is being phased out in developing countries, where it is largely used for air conditioning applications. Air conditioning sales are growing 20% annually in India and China. R-22 is prepared from chloroform: :HCCl3 + 2 HF ...
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Zeotropic Mixture
A zeotropic mixture, or non-azeotropic mixture, is a mixture with liquid components that have different boiling points. For example, nitrogen, methane, ethane, propane, and isobutane constitute a zeotropic mixture. Individual substances within the mixture do not evaporate or condense at the same temperature as one substance. In other words, the mixture has a temperature glide, as the phase change occurs in a temperature range of about four to seven degrees Celsius, rather than at a constant temperature. On temperature-composition graphs, this temperature glide can be seen as the temperature difference between the bubble point and dew point. For zeotropic mixtures, the temperatures on the bubble (boiling) curve are between the individual component's boiling temperatures. When a zeotropic mixture is boiled or condensed, the composition of the liquid and the vapor changes according to the mixtures's temperature-composition diagram. Zeotropic mixtures have different characteristics in ...
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Pentafluoroethane
Pentafluoroethane is a fluorocarbon with the formula CF3CHF2. Pentafluoroethane is currently used as a refrigerant (known as R-125) and also used as a fire suppression agent in fire suppression systems. Pentafluoroethane does not deplete ozone so it has replaced earlier fluorinated chemicals that did. However while it has zero ozone depletion potential, it has high global warming potential, reported by the United States Environmental Protection Agency (EPA) as 3450 times that of carbon dioxide. Refrigerant Pentafluoroethane in a near azeotropic mixture with difluoromethane is known as R-410A, a common replacement for various chlorofluorocarbons (commonly known as ''Freon'') in new refrigerant systems. Fire suppression systems HFC-125 (ECARO-25 / FE-25 / NAF S 125) is a gaseous fire suppression agent which can be used in clean agent fire suppression systems. In addition, HFC-125 leaves no residue on valuable equipment and material after discharge. It is generally used in situati ...
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1,1,1,2-Tetrafluoroethane
1,1,1,2-Tetrafluoroethane (also known as norflurane (INN), R-134a, Freon 134a, Forane 134a, Genetron 134a, Green Gas, Florasol 134a, Suva 134a, or HFC-134a) is a hydrofluorocarbon (HFC) and haloalkane refrigerant with thermodynamic properties similar to R-12 (dichlorodifluoromethane) but with insignificant ozone depletion potential and a lower 100-year global warming potential (1,430, compared to R-12's GWP of 10,900). It has the formula CFCHF and a boiling point of −26.3 °C (−15.34 °F) at atmospheric pressure. R-134a cylinders are colored light blue. A phaseout and transition to HFO-1234yf and other refrigerants, with GWPs similar to CO2, began in 2012 within the automotive market. Uses 1,1,1,2-Tetrafluoroethane is a non-flammable gas used primarily as a "high-temperature" refrigerant for domestic refrigeration and automobile air conditioners. These devices began using 1,1,1,2-tetrafluoroethane in the early 1990s as a replacement for the more environmenta ...
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Global Warming Potential
Global warming potential (GWP) is the heat absorbed by any greenhouse gas in the atmosphere, as a multiple of the heat that would be absorbed by the same mass of carbon dioxide (). GWP is 1 for . For other gases it depends on the gas and the time frame. Carbon dioxide equivalent (e or eq or -e) is calculated from GWP. For any gas, it is the mass of that would warm the earth as much as the mass of that gas. Thus it provides a common scale for measuring the climate effects of different gases. It is calculated as GWP times mass of the other gas. Methane has GWP (over 100 years) of 27.9 meaning that, for example, a leak of a tonne of methane is equivalent to emitting 27.9 tonnes of carbon dioxide. Similarly a tonne of nitrous oxide, from manure for example, is equivalent to 273 tonnes of carbon dioxide. Values Carbon dioxide is the reference. It has a GWP of 1 regardless of the time period used. emissions cause increases in atmospheric concentrations of that will last thousands ...
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