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Quantum Number
In quantum physics and chemistry, quantum numbers describe values of conserved quantities in the dynamics of a quantum system. Quantum numbers correspond to eigenvalues of operators that commute with the Hamiltonian—quantities that can be known with precision at the same time as the system's energyspecifically, observables \widehat that commute with the Hamiltonian are simultaneously diagonalizable with it and so the eigenvalues a and the energy (eigenvalues of the Hamiltonian) are not limited by an uncertainty relation arising from non-commutativity.—and their corresponding eigenspaces. Together, a specification of all of the quantum numbers of a quantum system fully characterize a basis state of the system, and can in principle be measured together. An important aspect of quantum mechanics is the quantization of many observable quantities of interest.Many observables have discrete spectra (sets of eigenvalues) in quantum mechanics, so the quantities can only be ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Orbitals N123 M-eigenstates
Atomic may refer to: * Of or relating to the atom, the smallest particle of a chemical element that retains its chemical properties * Atomic physics, the study of the atom * Atomic Age, also known as the "Atomic Era" * Atomic scale, distances comparable to the dimensions of an atom * Atom (order theory), in mathematics * Atomic (cocktail), a champagne cocktail * Atomic (magazine), ''Atomic'' (magazine), an Australian computing and technology magazine * Atomic Skis, an Austrian ski producer Music * Atomic (band), a Norwegian jazz quintet * Atomic (Lit album), ''Atomic'' (Lit album), 2001 * Atomic (Mogwai album), ''Atomic'' (Mogwai album), 2016 * ''Atomic'', an album by Rockets (band), Rockets, 1982 * Atomic (EP), ''Atomic'' (EP), by , 2013 * Atomic (song), "Atomic" (song), by Blondie, 1979 * "Atomic", a song by Tiger Army from ''Tiger Army III: Ghost Tigers Rise'' See also * * * Atom (other) * Atomicity (database systems) * Nuclear (other) * Atomism, ph ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Infinity
Infinity is that which is boundless, endless, or larger than any natural number. It is often denoted by the infinity symbol . Since the time of the ancient Greeks, the philosophical nature of infinity was the subject of many discussions among philosophers. In the 17th century, with the introduction of the infinity symbol and the infinitesimal calculus, mathematicians began to work with infinite series and what some mathematicians (including l'Hôpital and Bernoulli) regarded as infinitely small quantities, but infinity continued to be associated with endless processes. As mathematicians struggled with the foundation of calculus, it remained unclear whether infinity could be considered as a number or magnitude and, if so, how this could be done. At the end of the 19th century, Georg Cantor enlarged the mathematical study of infinity by studying infinite sets and infinite numbers, showing that they can be of various sizes. For example, if a line is viewed as the set of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Principal Quantum Number
In quantum mechanics, the principal quantum number (symbolized ''n'') is one of four quantum numbers assigned to each electron in an atom to describe that electron's state. Its values are natural numbers (from 1) making it a discrete variable. Apart from the principal quantum number, the other quantum numbers for bound electrons are the azimuthal quantum number ''ℓ'', the magnetic quantum number ''ml'', and the spin quantum number ''s''. Overview and history As ''n'' increases, the electron is also at a higher energy and is, therefore, less tightly bound to the nucleus. For higher ''n'' the electron is farther from the nucleus, on average. For each value of ''n'' there are ''n'' accepted ''ℓ'' (azimuthal) values ranging from 0 to ''n'' − 1 inclusively, hence higher-''n'' electron states are more numerous. Accounting for two states of spin, each ''n''- shell can accommodate up to 2''n''2 electrons. In a simplistic one-electron model described bel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Complete Set Of Commuting Observables
In quantum mechanics, a complete set of commuting observables (CSCO) is a set of commuting operators whose common eigenvectors can be used as a basis to express any quantum state. In the case of operators with discrete spectra, a CSCO is a set of commuting observables whose simultaneous eigenspaces span the Hilbert space, so that the eigenvectors are uniquely specified by the corresponding sets of eigenvalues. Since each pair of observables in the set commutes, the observables are all compatible so that the measurement of one observable has no effect on the result of measuring another observable in the set. It is therefore ''not'' necessary to specify the order in which the different observables are measured. Measurement of the complete set of observables constitutes a complete measurement, in the sense that it projects the quantum state of the system onto a unique and known vector in the basis defined by the set of operators. That is, to prepare the completely specified state, we h ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Commutivity
In mathematics, a binary operation is commutative if changing the order of the operands does not change the result. It is a fundamental property of many binary operations, and many mathematical proofs depend on it. Most familiar as the name of the property that says something like or , the property can also be used in more advanced settings. The name is needed because there are operations, such as division and subtraction, that do not have it (for example, ); such operations are ''not'' commutative, and so are referred to as ''noncommutative operations''. The idea that simple operations, such as the multiplication and addition of numbers, are commutative was for many years implicitly assumed. Thus, this property was not named until the 19th century, when mathematics started to become formalized. A similar property exists for binary relations; a binary relation is said to be symmetric if the relation applies regardless of the order of its operands; for example, equality is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Linear Independence
In the theory of vector spaces, a set of vectors is said to be if there is a nontrivial linear combination of the vectors that equals the zero vector. If no such linear combination exists, then the vectors are said to be . These concepts are central to the definition of dimension. A vector space can be of finite dimension or infinite dimension depending on the maximum number of linearly independent vectors. The definition of linear dependence and the ability to determine whether a subset of vectors in a vector space is linearly dependent are central to determining the dimension of a vector space. Definition A sequence of vectors \mathbf_1, \mathbf_2, \dots, \mathbf_k from a vector space is said to be ''linearly dependent'', if there exist scalars a_1, a_2, \dots, a_k, not all zero, such that :a_1\mathbf_1 + a_2\mathbf_2 + \cdots + a_k\mathbf_k = \mathbf, where \mathbf denotes the zero vector. This implies that at least one of the scalars is nonzero, say a_1\ne 0, and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eigenvalue
In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denoted by \lambda, is the factor by which the eigenvector is scaled. Geometrically, an eigenvector, corresponding to a real nonzero eigenvalue, points in a direction in which it is stretched by the transformation and the eigenvalue is the factor by which it is stretched. If the eigenvalue is negative, the direction is reversed. Loosely speaking, in a multidimensional vector space, the eigenvector is not rotated. Formal definition If is a linear transformation from a vector space over a field into itself and is a nonzero vector in , then is an eigenvector of if is a scalar multiple of . This can be written as T(\mathbf) = \lambda \mathbf, where is a scalar in , known as the eigenvalue, characteristic value, or characteristic root a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Operator
In physics, an operator is a function over a space of physical states onto another space of physical states. The simplest example of the utility of operators is the study of symmetry (which makes the concept of a group useful in this context). Because of this, they are very useful tools in classical mechanics. Operators are even more important in quantum mechanics, where they form an intrinsic part of the formulation of the theory. Operators in classical mechanics In classical mechanics, the movement of a particle (or system of particles) is completely determined by the Lagrangian L(q, \dot, t) or equivalently the Hamiltonian H(q, p, t), a function of the generalized coordinates ''q'', generalized velocities \dot = \mathrm q / \mathrm t and its conjugate momenta: :p = \frac If either ''L'' or ''H'' is independent of a generalized coordinate ''q'', meaning the ''L'' and ''H'' do not change when ''q'' is changed, which in turn means the dynamics of the particle are still the same ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fundamental Force
In physics, the fundamental interactions, also known as fundamental forces, are the interactions that do not appear to be reducible to more basic interactions. There are four fundamental interactions known to exist: the gravitational and electromagnetic interactions, which produce significant long-range forces whose effects can be seen directly in everyday life, and the strong and weak interactions, which produce forces at minuscule, subatomic distances and govern nuclear interactions. Some scientists hypothesize that a fifth force might exist, but these hypotheses remain speculative. Each of the known fundamental interactions can be described mathematically as a '' field''. The gravitational force is attributed to the curvature of spacetime, described by Einstein's general theory of relativity. The other three are discrete quantum fields, and their interactions are mediated by elementary particles described by the Standard Model of particle physics. Within the Standard Mode ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Internal Symmetry
In physics, a symmetry of a physical system is a physical or mathematical feature of the system (observed or intrinsic) that is preserved or remains unchanged under some transformation. A family of particular transformations may be ''continuous'' (such as rotation of a circle) or '' discrete'' (e.g., reflection of a bilaterally symmetric figure, or rotation of a regular polygon). Continuous and discrete transformations give rise to corresponding types of symmetries. Continuous symmetries can be described by Lie groups while discrete symmetries are described by finite groups (see ''Symmetry group''). These two concepts, Lie and finite groups, are the foundation for the fundamental theories of modern physics. Symmetries are frequently amenable to mathematical formulations such as group representations and can, in addition, be exploited to simplify many problems. Arguably the most important example of a symmetry in physics is that the speed of light has the same value in all fra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flavour (particle Physics)
In particle physics, flavour or flavor refers to the ''species'' of an elementary particle. The Standard Model counts six flavours of quarks and six flavours of leptons. They are conventionally parameterized with ''flavour quantum numbers'' that are assigned to all subatomic particles. They can also be described by some of the family symmetries proposed for the quark-lepton generations. Quantum numbers In classical mechanics, a force acting on a point-like particle can only alter the particle's dynamical state, i.e., its momentum, angular momentum, etc. Quantum field theory, however, allows interactions that can alter other facets of a particle's nature described by non dynamical, discrete quantum numbers. In particular, the action of the weak force is such that it allows the conversion of quantum numbers describing mass and electric charge of both quarks and leptons from one discrete type to another. This is known as a flavour change, or flavour transmutation. Due to their ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin (physics)
Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbital angular momentum operator is the quantum-mechanical counterpart to the classical angular momentum of orbital revolution and appears when there is periodic structure to its wavefunction as the angle varies. For photons, spin is the quantum-mechanical counterpart of the polarization of light; for electrons, the spin has no classical counterpart. The existence of electron spin angular momentum is inferred from experiments, such as the Stern–Gerlach experiment, in which silver atoms were observed to possess two possible discrete angular momenta despite having no orbital angular momentum. The existence of the electron spin can also be inferred theoretically from the spin–statistics theorem and from the Pauli exclusion principle—and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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