Quantum Defect
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Quantum Defect
The term quantum defect refers to two concepts: energy loss in lasers and energy levels in alkali elements. Both deal with quantum systems where matter interacts with light. In laser science In laser science, the term "quantum defect" refers to the fact that the energy of a pump photon is generally higher than that of a ''signal photon'' (photon of the output radiation). The energy difference is lost to heat, which may carry away the excess entropy delivered by the multimode incoherent pump. The quantum defect of a laser can be defined as part of the energy of the pumping photon, which is lost (not turned into photons at the lasing wavelength) in the gain medium at the lasing. At given frequency \omega_ of pump and given frequency \omega_ of lasing, the quantum defect q = \hbar \omega_ - \hbar\omega_. Such quantum defect has dimension of energy; for the efficient operation, the temperature of the gain medium (measured in units of energy) should be small compared to the quantum def ...
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Alkali Metal
The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names for the elements in some languages, such as German and Russian. rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute Group (periodic table)#Group names, group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an atomic orbital, s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of periodic trends, group trends in properties in the periodic table, with elements exhibiting well-characterised homology (chemistry), homologous behaviour. This family of elements is also known as the lithium family after its leading element. The alkali metals are all sh ...
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Hydrogen Atom
A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe. In everyday life on Earth, isolated hydrogen atoms (called "atomic hydrogen") are extremely rare. Instead, a hydrogen atom tends to combine with other atoms in compounds, or with another hydrogen atom to form ordinary ( diatomic) hydrogen gas, H2. "Atomic hydrogen" and "hydrogen atom" in ordinary English use have overlapping, yet distinct, meanings. For example, a water molecule contains two hydrogen atoms, but does not contain atomic hydrogen (which would refer to isolated hydrogen atoms). Atomic spectroscopy shows that there is a discrete infinite set of states in which a hydrogen (or any) atom can exist, contrary to the predictions of classical physics. Attempts to develop a theore ...
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Quantum Efficiency Of A Solar Cell
Solar-cell efficiency refers to the portion of energy in the form of sunlight that can be converted via photovoltaics into electricity by the solar cell. The efficiency of the solar cells used in a photovoltaic system, in combination with latitude and climate, determines the annual energy output of the system. For example, a solar panel with 20% efficiency and an area of 1 m2 will produce 200 kWh/yr at Standard Test Conditions if exposed to the Standard Test Condition solar irradiance value of 1000 W/m2 for 2.74 hours a day. Usually solar panels are exposed to sunlight for longer than this in a given day, but the solar irradiance is less than 1000 W/m2 for most of the day. A solar panel can produce more when the sun is high in the sky and will produce less in cloudy conditions or when the sun is low in the sky, usually the sun is lower in the sky in the winter. Two location dependant factors that affect solar PV efficiency are the dispersion and intensity ...
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External Quantum Efficiency
The term quantum efficiency (QE) may apply to incident photon to converted electron (IPCE) ratio of a photosensitive device, or it may refer to the TMR effect of a Magnetic Tunnel Junction. This article deals with the term as a measurement of a device's electrical sensitivity to light. In a charge-coupled device (CCD) or other photodetector, it is the ratio between the number of charge carriers collected at either terminal and the number of photons hitting the device's photoreactive surface. As a ratio, QE is dimensionless, but it is closely related to the responsivity, which is expressed in amps per watt. Since the energy of a photon is inversely proportional to its wavelength, QE is often measured over a range of different wavelengths to characterize a device's efficiency at each photon energy level. For typical semiconductor photodetectors, QE drops to zero for photons whose energy is below the band gap. A photographic film typically has a QE of much less than 10%, while CCD ...
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Alkali Metals
The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names for the elements in some languages, such as German and Russian. rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterised homologous behaviour. This family of elements is also known as the lithium family after its leading element. The alkali metals are all shiny, soft, highly reactive metals at standard temperature and pressure and readily lose ...
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Rydberg Formula
In atomic physics, the Rydberg formula calculates the wavelengths of a spectral line in many chemical elements. The formula was primarily presented as a generalization of the Balmer series for all atomic electron transitions of hydrogen. It was first empirically stated in 1888 by the Swedish physicist Johannes Rydberg, then theoretically by Niels Bohr in 1913, who used a primitive form of quantum mechanics. The formula directly generalizes the equations used to calculate the wavelengths of the hydrogen spectral series. History In 1880, Rydberg worked on a formula describing the relation between the wavelengths in spectral lines of alkali metals. He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/''λ'', the inverse of the wavelength) as his unit of measurement. He plotted the wavenumbers (''n'') of successive lines in each series against consecutive integers w ...
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Wavefunction
A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements made on the system can be derived from it. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi, respectively). The wave function is a function of the degrees of freedom corresponding to some maximal set of commuting observables. Once such a representation is chosen, the wave function can be derived from the quantum state. For a given system, the choice of which commuting degrees of freedom to use is not unique, and correspondingly the domain of the wave function is also not unique. For instance, it may be taken to be a function of all the position coordinates of the particles over position space, or the momenta of all the particles over momentum space; the two are related by a Fourier trans ...
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Angular Momentum Operator
In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum problems involving rotational symmetry. Such an operator is applied to a mathematical representation of the physical state of a system and yields an angular momentum value if the state has a definite value for it. In both classical and quantum mechanical systems, angular momentum (together with linear momentum and energy) is one of the three fundamental properties of motion.Introductory Quantum Mechanics, Richard L. Liboff, 2nd Edition, There are several angular momentum operators: total angular momentum (usually denoted J), orbital angular momentum (usually denoted L), and spin angular momentum (spin for short, usually denoted S). The term ''angular momentum operator'' can (confusingly) refer to either the total or the orbital angular momen ...
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Principal Quantum Number
In quantum mechanics, the principal quantum number (symbolized ''n'') is one of four quantum numbers assigned to each electron in an atom to describe that electron's state. Its values are natural numbers (from 1) making it a discrete variable. Apart from the principal quantum number, the other quantum numbers for bound electrons are the azimuthal quantum number ''ℓ'', the magnetic quantum number ''ml'', and the spin quantum number ''s''. Overview and history As ''n'' increases, the electron is also at a higher energy and is, therefore, less tightly bound to the nucleus. For higher ''n'' the electron is farther from the nucleus, on average. For each value of ''n'' there are ''n'' accepted ''ℓ'' (azimuthal) values ranging from 0 to ''n'' − 1 inclusively, hence higher-''n'' electron states are more numerous. Accounting for two states of spin, each ''n''- shell can accommodate up to 2''n''2 electrons. In a simplistic one-electron model described bel ...
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Speed Of Light
The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit for the speed at which conventional matter or energy (and thus any signal carrying information) can travel through space. All forms of electromagnetic radiation, including visible light, travel at the speed of light. For many practical purposes, light and other electromagnetic waves will appear to propagate instantaneously, but for long distances and very sensitive measurements, their finite speed has noticeable effects. Starlight viewed on Earth left the stars many years ago, allowing humans to study the history of the universe by viewing distant objects. When communicating with distant space probes, it can take minutes to hours for signals to travel from Earth to the spacecraft and vice versa. In computing, the speed of light fixes ...
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Rydberg Constant
In spectroscopy, the Rydberg constant, symbol R_\infty for heavy atoms or R_\text for hydrogen, named after the Swedish physicist Johannes Rydberg, is a physical constant relating to the electromagnetic spectra of an atom. The constant first arose as an empirical fitting parameter in the Rydberg formula for the hydrogen spectral series, but Niels Bohr later showed that its value could be calculated from more fundamental constants via his Bohr model. Before the redefinition of the SI base units in , R_\infty and the electron spin ''g''-factor were the most accurately measured physical constants. The constant is expressed for either hydrogen as R_\text, or at the limit of infinite nuclear mass as R_\infty. In either case, the constant is used to express the limiting value of the highest wavenumber (inverse wavelength) of any photon that can be emitted from an atom, or, alternatively, the wavenumber of the lowest-energy photon capable of ionizing an atom from its ground state. T ...
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Binding Energy
In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly used in condensed matter physics, atomic physics, and chemistry, whereas in nuclear physics the term ''separation energy'' is used. A bound system is typically at a lower energy level than its unbound constituents. According to relativity theory, a decrease in the total energy of a system is accompanied by a decrease in the total mass, where . Types of binding energy There are several types of binding energy, each operating over a different distance and energy scale. The smaller the size of a bound system, the higher its associated binding energy. Mass–energy relation A bound system is typically at a lower energy level than its unbound constituents because its mass must be less than the total mass of its unbound constituents. For sys ...
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