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Prismanes
The prismanes are a class of hydrocarbon compounds consisting of prism-like polyhedra of various numbers of sides on the polygonal base. Chemically, it is a series of fused cyclobutane rings (a ladderane, with all-cis/all- syn geometry) that wraps around to join its ends and form a band, with cycloalkane edges. Their chemical formula is (C2H2)n, where ''n'' is the number of cyclobutane sides (the size of the cycloalkane base), and that number also forms the basis for a system of nomenclature within this class. The first few chemicals in this class are: Triprismane, tetraprismane, and pentaprismane have been synthesized and studied experimentally, and many higher members of the series have been studied using computer models. The first several members do indeed have the geometry of a regular prism, with flat ''n''-gon bases. As ''n'' becomes increasingly large, however, modeling experiments find that highly symmetric geometry is no longer stable, and the molecule distorts into les ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Prism (geometry)
In geometry, a prism is a polyhedron comprising an polygon Base (geometry), base, a second base which is a Translation (geometry), translated copy (rigidly moved without rotation) of the first, and other Face (geometry), faces, necessarily all parallelograms, joining corresponding sides of the two bases. All Cross section (geometry), cross-sections parallel to the bases are translations of the bases. Prisms are named after their bases, e.g. a prism with a pentagonal base is called a pentagonal prism. Prisms are a subclass of prismatoids. Like many basic geometric terms, the word ''prism'' () was first used in Euclid's Elements. Euclid defined the term in Book XI as “a solid figure contained by two opposite, equal and parallel planes, while the rest are parallelograms”. However, this definition has been criticized for not being specific enough in relation to the nature of the bases, which caused confusion among later geometry writers. Oblique prism An oblique prism is a pr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Allotropes Of Carbon
Carbon is capable of forming many allotropy, allotropes (structurally different forms of the same element) due to its Valence (chemistry), valency. Well-known forms of carbon include diamond and graphite. In recent decades, many more allotropes have been discovered and researched, including ball shapes such as buckminsterfullerene and sheets such as graphene. Larger-scale structures of carbon include carbon nano tube, nanotubes, Carbon nanobud, nanobuds and Graphene nanoribbon, nanoribbons. Other unusual forms of carbon exist at very high temperatures or extreme pressures. Around 500 hypothetical 3‑periodic allotropes of carbon are known at the present time, according to the Samara Carbon Allotrope Database (SACADA). Diamond Diamond is a well-known allotrope of carbon. The hardness, extremely high refractive index, and high Dispersion (optics), dispersion of light make diamond useful for industrial applications and for jewelry. Diamond is the hardest known natural min ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cubane
Cubane () is a synthetic hydrocarbon compound that consists of eight carbon atoms arranged at the corners of a cube, with one hydrogen atom attached to each carbon atom. A solid crystalline substance, cubane is one of the Platonic hydrocarbons and a member of the prismanes. It was first synthesized in 1964 by Philip Eaton and Thomas Cole. Before this work, Eaton believed that cubane would be impossible to synthesize due to the "required 90 degree bond angles". The cubic shape requires the carbon atoms to adopt an unusually sharp 90° bonding angle, which would be highly strained as compared to the 109.45° angle of a tetrahedral carbon. Once formed, cubane is quite kinetically stable, due to a lack of readily available decomposition paths. It is the simplest hydrocarbon with octahedral symmetry. Having high potential energy but kinetic stability makes cubane and its derivative compounds useful for controlled energy storage. For example, octanitrocubane and heptanitrocubane have ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclohexane
Cyclohexane is a cycloalkane with the molecular formula . Cyclohexane is non-polar. Cyclohexane is a colorless, flammable liquid with a distinctive detergent-like odor, reminiscent of cleaning products (in which it is sometimes used). Cyclohexane is mainly used for the industrial production of adipic acid and caprolactam, which are precursors to nylon. Cyclohexyl () is the alkyl substituent of cyclohexane and is abbreviated Cy. Production Modern On an industrial scale, cyclohexane is produced by hydrogenation of benzene in the presence of a Raney nickel catalyst. Producers of cyclohexane account for approximately 11.4% of global demand for benzene. The reaction is highly exothermic, with ΔH(500 K) = -216.37 kJ/mol. Dehydrogenation commenced noticeably above 300 °C, reflecting the favorable entropy for dehydrogenation. : Early Unlike benzene, cyclohexane is not found in natural resources such as coal. For this reason, early investigators synthesized their cyclohexane ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methylene Group
In organic chemistry, a methylene group is any part of a molecule that consists of two hydrogen atoms bound to a carbon atom, which is connected to the remainder of the molecule by two single bonds. The group may be represented as , where the '<' denotes the two bonds. This can equally well be represented as . This stands in contrast to a situation where the carbon atom is bound to the rest of the molecule by a double bond, which is preferably called a , represented . Formerly the methylene name was used for both isomers. The name ““ can be used for the single-bonded isomer, to emphatically exclude methylidene. The distinction is often important, because the double bond is chemically di ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Asterane
Asteranes are members of a series of cage hydrocarbons consisting of two cycloalkane rings linked to each other by methylene groups. Each linking face is thus a cyclohexane, which has a boat conformation. They can be considered as homologues of the prismanes, but with a carbon linker between the faces rather than direct bonding. The molecules having triangular and square bases, sterane and sterane, have been synthesized and studied experimentally, and many higher members of the series have been studied using computer models Computer simulation is the process of mathematical modelling, performed on a computer, which is designed to predict the behaviour of, or the outcome of, a real-world or physical system. The reliability of some mathematical models can be deter .... Modeling experiments predict that the highly symmetric geometry is no longer stable starting with sterane. References {{reflist Hydrocarbons ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flag Of Israel
The flag of Israel ( he, דגל ישראל '; ar, علم إسرائيل ') was adopted on 28 October 1948, five months after the establishment of the Israel, State of Israel. It depicts a blue hexagram on a white background, between two horizontal blue stripes. The Israeli flag legislation states that the official measurements are 160 × 220 cm. Therefore, the official proportions are 8:11. Variants can be found at a wide range of proportions, with 2:3 being common. The blue colour is described as "dark sky-blue",Israel Ministry of Foreign Affairs publicatioThe Flag and the Emblem by art historian Alec Mishory, wherein he quotes "The Provisional Council of State Proclamation of the Flag of the State of Israel" made on October 28, 1948 by Joseph Sprinzak, Speaker. and varies from flag to flag, ranging from a hue of pure blue, sometimes tints and shades, shaded almost as dark as navy blue, to hues about 75% toward pure cyan and shades as light as very light blue. An early ve ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flag Of Switzerland
The national flag of Switzerland (german: Schweizerfahne; french: drapeau de la Suisse; it, bandiera svizzera; rm, bandiera da la Svizra) displays a white cross in the centre of a square red field. The white cross is known as the Swiss cross or the federal cross. Its arms are equilateral, and their ratio of length to width is 7:6. The size of the cross in relation to the field was set in 2017 as 5:8.Appendix 2 ''Wappenschutzgesetz'' (SR 232.21), 21 June 2013 (effective 1 January 2017) engt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Geometric Isomer
Geometry (; ) is, with arithmetic, one of the oldest branches of mathematics. It is concerned with properties of space such as the distance, shape, size, and relative position of figures. A mathematician who works in the field of geometry is called a ''geometer''. Until the 19th century, geometry was almost exclusively devoted to Euclidean geometry, which includes the notions of point, line, plane, distance, angle, surface, and curve, as fundamental concepts. During the 19th century several discoveries enlarged dramatically the scope of geometry. One of the oldest such discoveries is Carl Friedrich Gauss' ("remarkable theorem") that asserts roughly that the Gaussian curvature of a surface is independent from any specific embedding in a Euclidean space. This implies that surfaces can be studied ''intrinsically'', that is, as stand-alone spaces, and has been expanded into the theory of manifolds and Riemannian geometry. Later in the 19th century, it appeared that geometri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dodecagon
In geometry, a dodecagon or 12-gon is any twelve-sided polygon. Regular dodecagon A regular dodecagon is a figure with sides of the same length and internal angles of the same size. It has twelve lines of reflective symmetry and rotational symmetry of order 12. A regular dodecagon is represented by the Schläfli symbol and can be constructed as a truncated hexagon, t, or a twice-truncated triangle, tt. The internal angle at each vertex of a regular dodecagon is 150°. Area The area of a regular dodecagon of side length ''a'' is given by: :\begin A & = 3 \cot\left(\frac \right) a^2 = 3 \left(2+\sqrt \right) a^2 \\ & \simeq 11.19615242\,a^2 \end And in terms of the apothem ''r'' (see also inscribed figure), the area is: :\begin A & = 12 \tan\left(\frac\right) r^2 = 12 \left(2-\sqrt \right) r^2 \\ & \simeq 3.2153903\,r^2 \end In terms of the circumradius ''R'', the area is: :A = 6 \sin\left(\frac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Computational Chemistry
Computational chemistry is a branch of chemistry that uses computer simulation to assist in solving chemical problems. It uses methods of theoretical chemistry, incorporated into computer programs, to calculate the structures and properties of molecules, groups of molecules, and solids. It is essential because, apart from relatively recent results concerning the hydrogen molecular ion (dihydrogen cation, see references therein for more details), the quantum many-body problem cannot be solved analytically, much less in closed form. While computational results normally complement the information obtained by chemical experiments, it can in some cases predict hitherto unobserved chemical phenomena. It is widely used in the design of new drugs and materials. Examples of such properties are structure (i.e., the expected positions of the constituent atoms), absolute and relative (interaction) energies, electronic charge density distributions, dipoles and higher multipole moments, vi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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