Praseodymium(III) Fluoride
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Praseodymium(III) Fluoride
Praseodymium(III) fluoride is an inorganic compound with the formula PrF3, being the most stable fluoride of praseodymium. Production The reaction between praseodymium(III) nitrate and sodium fluoride will produce praseodymium(III) fluoride as a green crystalline solid: : Pr(NO3)3 + 3 NaF → 3 NaNO3 + PrF3 See also *Praseodymium(III) chloride *Praseodymium(IV) fluoride Praseodymium(IV) fluoride (also praseodymium tetrafluoride) is a binary inorganic compound, a highly oxidised metal salt of praseodymium and fluoride with the chemical formula PrF4. It forms light yellow crystals. Synthesis Praseodymium(IV) fluor ... References {{Lanthanide halides Fluorides Praseodymium compounds Inorganic compounds Lanthanide halides ...
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Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ...
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Chemical Formula
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include Subscript and superscript, subscripts and superscripts. A chemical formula is not a chemical nomenclature, chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called ''empirical formulae'', which use letters and numbers ind ...
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Fluoride
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nom ...
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Praseodymium
Praseodymium is a chemical element with the Symbol (chemistry), symbol Pr and the atomic number 59. It is the third member of the lanthanide series and is considered to be one of the rare-earth metals. It is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. It is too reactive to be found in native form, and pure praseodymium metal slowly develops a green oxide coating when exposed to air. Praseodymium always occurs naturally together with the other rare-earth metals. It is the sixth-most abundant rare-earth element and fourth-most abundant lanthanide, making up 9.1 parts per million of the Earth's crust, an abundance similar to that of boron. In 1841, Swedish chemist Carl Gustav Mosander extracted a rare-earth oxide residue he called didymium from a residue he called "lanthana", in turn separated from cerium salts. In 1885, the Austrian chemist Baron Carl Auer von Welsbach separated didymium into two elements that ...
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Praseodymium(III) Nitrate
Praseodymium(III) nitrate is a green-colored chemical compound with the chemical formula Pr(NO3)3. It is very hygroscopic and forms a hexahydrate. It is soluble in polar solvents. Uses Praseodymium(III) nitrate is used in fluorescent display tubes and phosphors. It is also used in the ultrasonic synthesis of praseodymium molybdate In chemistry a molybdate is a compound containing an oxoanion with molybdenum in its highest oxidation state of 6. Molybdenum can form a very large range of such oxoanions which can be discrete structures or polymeric extended structures, althoug .... It also plays a role in the preparation in lanthanide oxysulfides. References {{Nitrates Praseodymium compounds Nitrates Phosphors and scintillators ...
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Sodium Fluoride
Sodium fluoride (NaF) is an inorganic compound with the formula . It is used in trace amounts in the fluoridation of drinking water, in toothpaste, in metallurgy, and as a flux. It is a colorless or white solid that is readily soluble in water. It is a common source of fluoride in the production of pharmaceuticals and is used to prevent dental cavities. In 2020, it was the 265th most commonly prescribed medication in the United States, with more than 1million prescriptions. Uses Dental caries Fluoride salts are often added to municipal drinking water (as well as to certain food products in some countries) for the purpose of maintaining dental health. The fluoride enhances the strength of teeth by the formation of fluorapatite, a naturally occurring component of tooth enamel. Although sodium fluoride is used to fluoridate water and is the standard by which other water-fluoridation compounds are gauged, hexafluorosilicic acid (H2SiF6) and its salt sodium hexafluorosilica ...
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Materials Letters
''Materials Letters'' is an interdisciplinary, peer-reviewed journal published by Elsevier which according to its website "is dedicated to publishing novel, cutting edge reports of broad interest to the materials community." Abstracting and indexing The journal is indexed in Inspec. According to the ''Journal Citation Reports'', the journal has a 2020 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a scientometric index calculated by Clarivate that reflects the yearly mean number of citations of articles published in the last two years in a given journal, as i ... of 3.423. References External links * Materials science journals Elsevier academic journals English-language journals Publications established in 1982 {{science-journal-stub ...
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Praseodymium(III) Chloride
Praseodymium(III) chloride is the inorganic compound with the formula Pr Cl3. Like other lanthanide trichlorides, it exists both in the anhydrous and hydrated forms. It is a blue-green solid that rapidly absorbs water on exposure to moist air to form a light green heptahydrate. Preparation Praseodymium(III) chloride is prepared by treating praseodymium metal with hydrogen chloride:L. F. Druding, J. D. Corbett, "Lower Oxidation States of the Lanthanides. Neodymium(II) Chloride and Iodide", ''J. Am. Chem. Soc.'' 83, 2462 (1961); J. D. Corbett, ''Rev. Chim. Minerale'' 10, 239 (1973), :2 Pr + 6 HCl → 2 PrCl3 + 3 H2 It is usually purified by vacuum sublimation. Hydrated salts of praseodymium(III) chloride can be prepared by treatment of either praseodymium metal or praseodymium(III) carbonate with hydrochloric acid: :Pr2(CO3)3 + 6 HCl + 15 H2O → 2 r(H2O)9l3 + 3 CO2 PrCl3∙7H2O is a hygroscopic substance, that will not crystallize from the mother liquor unless it is l ...
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Praseodymium(IV) Fluoride
Praseodymium(IV) fluoride (also praseodymium tetrafluoride) is a binary inorganic compound, a highly oxidised metal salt of praseodymium and fluoride with the chemical formula PrF4. It forms light yellow crystals. Synthesis Praseodymium(IV) fluoride can be prepared by the effect of krypton difluoride on praseodymium(IV) oxide: ::\mathsf Praseodymium(IV) fluoride can also be made by the dissolution of sodium hexafluoropraseodymate(IV) in liquid hydrogen fluoride: ::\mathsf Properties Praseodymium(IV) fluoride forms light yellow crystals. The crystal structure is anticubic and isomorphic to that of uranium tetrafluoride UF4. Decomposes when heated: ::\mathsf Due to the high normal potential of the tetravalent praseodymium cations (Pr3+ / Pr4+: +3.2 V), praseodymium(IV) fluoride decomposes in water, releasing oxygen, O2. See also * Praseodymium(III) fluoride *Uranium tetrafluoride Uranium tetrafluoride is the inorganic compound with the formula UF4. It is a green solid with a ...
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Fluorides
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nomenc ...
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Praseodymium Compounds
Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known. Oxides Praseodymium can form oxides in many different ways, although the only oxides that are stable at room temperature are Pr2O3, Pr6O11 and PrO2. Praseodymium(III) oxide is a green powder that forms hexagonal crystals, and crystallizes in the manganese(III) oxide or bixbyite structure. Praseodymium(IV) oxide can be produced by boiling Pr6O11 in water or acetic acid: zh, 《无机化学丛书》.第七卷 钪 稀土元素. 科学出版社. 1.3.4 氧化态+4的化合物., translation=Inorganic Chemistry Series. Volume VII Rare Earth Elements. Science Press. 1.3.4 Compounds with oxidation state +4. P193~195 : Pr6O11 + 3 H2O → 4 PrO2 ...
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Inorganic Compounds
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ...
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