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Potential Theory Of Polanyi
The potential theory of Polanyi, also called Polanyi adsorption potential theory, is a model of adsorption proposed by Michael Polanyi where adsorption can be measured through the equilibrium between the chemical potential of a gas near the surface and the chemical potential of the gas from a large distance away. In this model, he assumed that the attraction largely due to Van Der Waals forces of the gas to the surface is determined by the position of the gas particle from the surface, and that the gas behaves as an ideal gas until condensation where the gas exceeds its equilibrium vapor pressure. While the adsorption theory of Henry is more applicable in low pressure and BET adsorption isotherm equation is more useful at from 0.05 to 0.35 P/Po, the Polanyi potential theory has much more application at higher P/Po (~0.1–0.8). Overview Michael Polanyi Michael Polanyi, FRS (11 March 1891 – 22 February 1976) was a Hungarian polymath, who made theoretical contribution to physica ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Michael Polanyi
Michael Polanyi (; hu, Polányi Mihály; 11 March 1891 – 22 February 1976) was a Hungarian-British polymath, who made important theoretical contributions to physical chemistry, economics, and philosophy. He argued that positivism supplies an imperfect account of knowing as no observer is perfectly impartial. His wide-ranging research in physical science included chemical kinetics, x-ray diffraction, and adsorption of gases. He pioneered the theory of fibre diffraction analysis in 1921, and the dislocation theory of plastic deformation of ductile metals and other materials in 1934. He immigrated to Germany, in 1926 becoming a chemistry professor at the Kaiser Wilhelm Institute in Berlin, and then in 1933 to England, becoming first a chemistry professor, and then a social sciences professor at the University of Manchester. Two of his pupils, and his son John Charles Polanyi won Nobel Prizes in Chemistry. In 1944 Polanyi was elected to the Royal Society. The contribution ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Dipole Moment
The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system, that is, a measure of the system's overall polarity. The SI unit for electric dipole moment is the coulomb-meter (C⋅m). The debye (D) is another unit of measurement used in atomic physics and chemistry. Theoretically, an electric dipole is defined by the first-order term of the multipole expansion; it consists of two equal and opposite charges that are infinitesimally close together, although real dipoles have separated charge.Many theorists predict elementary particles can have very tiny electric dipole moments, possibly without separated charge. Such large dipoles make no difference to everyday physics, and have not yet been observed. (See electron electric dipole moment). However, when making measurements at a distance much larger than the charge separation, the dipole gives a good approximation of the actual electric field. The dipole is represented by a v ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
The Theory Of Volume Filling Micropores (TVFM)
''The'' () is a grammatical article in English, denoting persons or things already mentioned, under discussion, implied or otherwise presumed familiar to listeners, readers, or speakers. It is the definite article in English. ''The'' is the most frequently used word in the English language; studies and analyses of texts have found it to account for seven percent of all printed English-language words. It is derived from gendered articles in Old English which combined in Middle English and now has a single form used with pronouns of any gender. The word can be used with both singular and plural nouns, and with a noun that starts with any letter. This is different from many other languages, which have different forms of the definite article for different genders or numbers. Pronunciation In most dialects, "the" is pronounced as (with the voiced dental fricative followed by a schwa) when followed by a consonant sound, and as (homophone of pronoun ''thee'') when followed by a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fritz London
Fritz Wolfgang London (March 7, 1900 – March 30, 1954) was a German physicist and professor at Duke University. His fundamental contributions to the theories of chemical bonding and of intermolecular forces (London dispersion forces) are today considered classic and are discussed in standard textbooks of physical chemistry. With his brother Heinz London, he made a significant contribution to understanding electromagnetic properties of superconductors with the London equations and was nominated for the Nobel Prize in Chemistry on five separate occasions. Biography London was born in Breslau, Germany (now Wrocław, Poland) as the son of Franz London (1863-1917). Being a Jew, London lost his position at the University of Berlin after Hitler's Nazi Party passed the 1933 racial laws. He took visiting positions in England and France, and emigrated to the United States in 1939, of which he became a naturalized citizen in 1945. Later in his life, London was a professor at Duke Universi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Berlin, Germany
Berlin ( , ) is the capital and largest city of Germany by both area and population. Its 3.7 million inhabitants make it the European Union's most populous city, according to population within city limits. One of Germany's sixteen constituent states, Berlin is surrounded by the State of Brandenburg and contiguous with Potsdam, Brandenburg's capital. Berlin's urban area, which has a population of around 4.5 million, is the second most populous urban area in Germany after the Ruhr. The Berlin-Brandenburg capital region has around 6.2 million inhabitants and is Germany's third-largest metropolitan region after the Rhine-Ruhr and Rhine-Main regions. Berlin straddles the banks of the Spree, which flows into the Havel (a tributary of the Elbe) in the western borough of Spandau. Among the city's main topographical features are the many lakes in the western and southeastern boroughs formed by the Spree, Havel and Dahme, the largest of which is Lake Müggelsee. Due to its locat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kaiser Wilhelm Institute For Physical Chemistry
The Kaiser Wilhelm Society for the Advancement of Science (German: ''Kaiser-Wilhelm-Gesellschaft zur Förderung der Wissenschaften'') was a German scientific institution established in the German Empire in 1911. Its functions were taken over by the Max Planck Society. The Kaiser Wilhelm Society was an umbrella organisation for many institutes, testing stations, and research units created under its authority. Constitution The Kaiser Wilhelm Gesellschaft (KWG) was founded in 1911 in order to promote the natural sciences in Germany, by founding and maintaining research institutions formally independent from the state and its administrations. The institutions were to be under the guidance of prominent directors, which included the physicists and chemists Walther Bothe, Peter Debye, Albert Einstein, Fritz Haber and Otto Hahn; a board of trustees also provided guidance. Funding was ultimately obtained from sources internal and external to Germany. Internally, money was raised from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fritz Haber
Fritz Haber (; 9 December 186829 January 1934) was a German chemist who received the Nobel Prize in Chemistry in 1918 for his invention of the Haber–Bosch process, a method used in industry to synthesize ammonia from nitrogen gas and hydrogen gas. This invention is important for the large-scale synthesis of fertilisers and explosives. It is estimated that one-third of annual global food production uses ammonia from the Haber–Bosch process, and that this supports nearly half of the world's population. Haber, along with Max Born, proposed the Born–Haber cycle as a method for evaluating the lattice energy of an ionic solid. Haber, a known German nationalist, is also considered the "father of chemical warfare" for his years of pioneering work developing and weaponising chlorine and other poisonous gases during World War I, especially his actions during the Second Battle of Ypres. His work was later also used to develop Zyklon B, used for the murder of more than 1 million of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hungary In World War I
At the outbreak of World War I in August 1914, Hungary was part of the Dual Monarchy of Austria-Hungary. Although there are no significant battles specifically connected to Hungarian regiments, the troops suffered high losses throughout the war as the Empire suffered defeat after defeat. The result was the breakup of the Empire and eventually, Hungary suffered severe territorial losses by the closing Trianon Peace Treaty. The Empire during the outbreak of the war In 1914, Austria-Hungary was one of the great powers of Europe, with an area of 676,443 km2 and a population of 52 million, of which Hungary had 325,400 km2 with population of 21 million. By 1913, the combined length of the railway tracks of the Austrian Empire and Kingdom of Hungary reached 43,280 kilometres (26,890 miles). In Western Europe only Germany had more extended railway network (63,378 km, 39,381 mi); the Austro-Hungarian Empire was followed by France (40,770 km, 25,330 mi), the United Kingdom (32, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Austria-Hungary
Austria-Hungary, often referred to as the Austro-Hungarian Empire,, the Dual Monarchy, or Austria, was a constitutional monarchy and great power in Central Europe between 1867 and 1918. It was formed with the Austro-Hungarian Compromise of 1867 in the aftermath of the Austro-Prussian War and was dissolved shortly after its defeat in the First World War. Austria-Hungary was ruled by the House of Habsburg and constituted the last phase in the constitutional evolution of the Habsburg monarchy. It was a multinational state and one of Europe's major powers at the time. Austria-Hungary was geographically the second-largest country in Europe after the Russian Empire, at and the third-most populous (after Russia and the German Empire). The Empire built up the fourth-largest machine building industry in the world, after the United States, Germany and the United Kingdom. Austria-Hungary also became the world's third-largest manufacturer and exporter of electric home appliances, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nobel Prize
The Nobel Prizes ( ; sv, Nobelpriset ; no, Nobelprisen ) are five separate prizes that, according to Alfred Nobel's will of 1895, are awarded to "those who, during the preceding year, have conferred the greatest benefit to humankind." Alfred Nobel was a Swedish chemist, engineer, and industrialist most famously known for the invention of dynamite. He died in 1896. In his will, he bequeathed all of his "remaining realisable assets" to be used to establish five prizes which became known as "Nobel Prizes." Nobel Prizes were first awarded in 1901. Nobel Prizes are awarded in the fields of Physics, Chemistry, Physiology or Medicine, Literature, and Peace (Nobel characterized the Peace Prize as "to the person who has done the most or best to advance fellowship among nations, the abolition or reduction of standing armies, and the establishment and promotion of peace congresses"). In 1968, Sveriges Riksbank (Sweden's central bank) funded the establishment of the Prize in Economi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Langmuir Equation
The Langmuir adsorption model explains adsorption by assuming an adsorbate behaves as an ideal gas at isothermal conditions. According to the model, adsorption and desorption are reversible processes. This model even explains the effect of pressure i.e at these conditions the adsorbate's partial pressure, p_A, is related to the volume of it, , adsorbed onto a solid adsorbent. The adsorbent, as indicated in the figure, is assumed to be an ideal solid surface composed of a series of distinct sites capable of binding the adsorbate. The adsorbate binding is treated as a chemical reaction between the adsorbate gaseous molecule A_\text and an empty sorption site, . This reaction yields an adsorbed species A_\text with an associated equilibrium constant K_\text: : A_ + S A_ From these basic hypotheses the mathematical formulation of the Langmuir adsorption isotherm can be derived in various independent and complementary ways: by the kinetics, the thermodynamics, and the statistical ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Willem Hendrik Keesom
Willem Hendrik Keesom () (21 June 1876, Texel – 3 March 1956, Leiden) was a Dutch physicist who, in 1926, invented a method to freeze liquid helium. He also developed the first mathematical description of dipole–dipole interactions in 1921. Thus, dipole–dipole interactions are also known as Keesom interactions. He was previously a student of Heike Kamerlingh Onnes, who had discovered superconductivity (a feat for which Kamerlingh Onnes received the 1913 Nobel Prize in Physics). He also discovered the lambda point transition specific-heat maximum between Helium-I and Helium-II in 1930. In 1924 he became member of the Royal Netherlands Academy of Arts and Sciences. In 1966, the minor planet '' 9686 Keesom'' was named after him. See also *Timeline of low-temperature technology The following is a timeline of low-temperature technology and cryogenic technology (refrigeration down to –273.15 °C, –459.67 °F or 0 K). It also lists important milestones in t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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