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Potassium Superoxide
Potassium superoxide is an inorganic compound with the formula KO2. It is a yellow paramagnetic solid that decomposes in moist air. It is a rare example of a stable salt of the superoxide anion. It is used as a scrubber, dehumidifier, and generator in rebreathers, spacecraft, submarines, and spacesuits. Production and reactions Potassium superoxide is produced by burning molten potassium in an atmosphere of excess oxygen. :K + → The salt consists of and ions, linked by ionic bonding. The O−O distance is 1.28 Å. Reactivity Potassium superoxide is a source of superoxide, which is a reductant and a nucleophile, depending on its reaction partner. Upon contact with water, it undergoes disproportionation to potassium hydroxide, oxygen, and hydrogen peroxide: :2 + → 2 KOH + : + → KOH + + It reacts with carbon dioxide, releasing oxygen: :2 + → K2CO3 + :2 + 2 + H2O → 2 KHCO3 + Potassium superoxide finds only niche uses as a laboratory reag ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolysis is the cleavage of biomolecules where a water molecule is consumed to effect the separation of a larger molecule into component parts. When a carbohydrate is broken into its component sugar molecules by hydrolysis (e.g., sucrose being broken down into glucose and fructose), this is recognized as saccharification. Hydrolysis reactions can be the reverse of a condensation reaction in which two molecules join into a larger one and eject a water molecule. Thus hydrolysis adds water to break down, whereas condensation builds up by removing water. Types Usually hydrolysis is a chemical process in which a molecule of water is added to a substance. Sometimes this addition causes both the substance and water molecule to split into two parts. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spacesuit
A space suit or spacesuit is a garment worn to keep a human alive in the harsh environment of outer space, vacuum and temperature extremes. Space suits are often worn inside spacecraft as a safety precaution in case of loss of cabin pressure, and are necessary for extravehicular activity (EVA), work done outside spacecraft. Space suits have been worn for such work in Earth orbit, on the surface of the Moon, and en route back to Earth from the Moon. Modern space suits augment the basic pressure garment with a complex system of equipment and environmental systems designed to keep the wearer comfortable, and to minimize the effort required to bend the limbs, resisting a soft pressure garment's natural tendency to stiffen against the vacuum. A self-contained oxygen supply and environmental control system is frequently employed to allow complete freedom of movement, independent of the spacecraft. Three types of space suits exist for different purposes: IVA (intravehicular activity ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mine Rescue
Mine rescue or mines rescue is the specialised job of rescuing miners and others who have become trapped or injured in underground mines because of mining accidents, roof falls or floods and disasters such as explosions. Background Mining laws in developed countries require trained, equipped mine rescue personnel to be available at all mining operations at surface and underground mining operations. Mine rescue teams must know the procedures used to rescue miners trapped by various hazards, including fire, explosions, cave-ins, toxic gas, smoke inhalation, and water entering the mine. Most mine rescue teams are composed of miners who know the mine and are familiar with the mining machinery they may encounter during the rescue, the layout of workings and geological conditions and working practices. Local and state governments may have teams on-call ready to respond to mine accidents. Rescuers and equipment The first mines rescuers were the colliery managers and volunte ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fire Fighting
Firefighting is the act of extinguishing or preventing the spread of unwanted fires from threatening human lives and destroying property and the environment. A person who engages in firefighting is known as a firefighter. Firefighters typically undergo a high degree of technical training. This involves structural firefighting and wildland firefighting. Specialized training includes aircraft firefighting, shipboard firefighting, aerial firefighting, maritime firefighting, and proximity firefighting. Firefighting is a dangerous profession due to the toxic environment created by combustible materials, with major risks are smoke, oxygen deficiency, elevated temperatures, poisonous atmospheres, and violent air flows. To combat some of these risks, firefighters carry self-contained breathing apparatus. Additional hazards include falls — a constant peril while navigating unfamiliar layouts or confined spaces amid shifting debris under limited visibility – and structural collapse ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Soyuz Spacecraft
Soyuz () is a series of spacecraft which has been in service since the 1960s, having made more than 140 flights. It was designed for the Soviet space program by the Korolev Design Bureau (now Energia). The Soyuz succeeded the Voskhod spacecraft and was originally built as part of the Soviet crewed lunar programs. It is launched on a Soyuz rocket from the Baikonur Cosmodrome in Kazakhstan. Between the 2011 retirement of the Space Shuttle and the 2020 demo flight of SpaceX Crew Dragon, the Soyuz served as the only means to ferry crew to or from the International Space Station, for which it remains heavily used. Although China did launch crewed Shenzhou flights during this time, none of them docked with the ISS. History The first Soyuz flight was uncrewed and started on 28 November 1966. The first Soyuz mission with a crew, Soyuz 1, launched on 23 April 1967 but ended with a crash due to a parachute failure, killing cosmonaut Vladimir Komarov. The following flight was ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Oxygen Generator
A chemical oxygen generator is a device that releases oxygen via a chemical reaction. The oxygen source is usually an inorganic superoxide, chlorate, or perchlorate; ozonides are a promising group of oxygen sources. The generators are usually ignited by a firing pin, and the chemical reaction is usually exothermic, making the generator a potential fire hazard. Potassium superoxide was used as an oxygen source on early crewed missions of the Soviet space program, in submarines for use in emergency situations, for firefighters, and for mine rescue. In commercial airliners Commercial aircraft provide emergency oxygen to passengers to protect them in case of loss of cabin pressure. Chemical oxygen generators are not used for the cockpit crew, who are typically supplied using compressed oxygen canisters, also known as oxygen bottles. In narrow body airliners, for each row of seats there were overhead oxygen masks and oxygen generators. In some wide-body airliners, such as t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Russian Space Agency
The State Space Corporation "Roscosmos" (russian: Государственная корпорация по космической деятельности «Роскосмос»), commonly known simply as Roscosmos (russian: Роскосмос), is a state corporation of the Russian Federation responsible for space flights, cosmonautics programs, and aerospace research. Originating from the Soviet space program founded in the 1950s, Roscosmos emerged following the dissolution of the Soviet Union in 1991. It initially began as the Russian Space Agency, which was established on 25 February 1992russian: Российское космическое агентство, ''Rossiyskoye kosmicheskoye agentstvo'', or RKA (russian: РКА). and restructured in 1999 and 2004, as the Russian Aviation and Space Agencyrussian: Российское авиационно-космическое агентство, ''Rossiyskoye aviatsionno-kosmicheskoye agentstvo'', commonly known as (ru ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetramethylammonium Hydroxide
Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with molecular formula N(CH3)4+ OH−. It is commonly encountered in form of concentrated solutions in water or methanol. TMAH in solid state and its aqueous solutions are all colorless, but may be yellowish if impure. Although TMAH has virtually no odor when pure, samples often have a strong fishy smell due to presence of trimethylamine which is a common impurity. TMAH has several diverse industrial and research applications. Chemical properties Structure TMAH is most commonly encountered as an aqueous solution, in concentrations from ~2–25%, and less frequently as solutions in methanol. These solutions are identified by CAS numbe75-59-2 Several hydrates such as N(CH3)4OH·xH2O. have been crystallized. These salts contain well separated Me4N+ cations and hydroxide anions ( Me is an abbreviation of methyl group). The hydroxide groups are linked by hydrogen bonds to the water of crystallizati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diacyl Peroxide
Benzoyl peroxide is a chemical compound (specifically, an organic peroxide) with structural formula , often abbreviated as (BzO)2. In terms of its structure, the molecule can be described as two benzoyl (, Bz) groups connected by a peroxide (). It is a white granular solid with a faint odour of benzaldehyde, poorly soluble in water but soluble in acetone, ethanol, and many other organic solvents. Benzoyl peroxide is an oxidizer, but it is principally used as in the production of polymers. Benzoyl peroxide is mainly used in production of plastics and for bleaching flour, hair, plastics and textiles. Synthesis, structure, and chemical reactivity The original 1858 synthesis by Liebig reacted benzoyl chloride with barium peroxide, a reaction described by the following idealized equation: : Benzoyl peroxide is usually prepared by treating hydrogen peroxide with benzoyl chloride under alkaline conditions. : As in many other peroxides, the C-O-O-C linkage has a dihedra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nucleophile
In chemistry, a nucleophile is a chemical species that forms bonds by donating an electron pair. All molecules and ions with a free pair of electrons or at least one pi bond can act as nucleophiles. Because nucleophiles donate electrons, they are Lewis bases. ''Nucleophilic'' describes the affinity of a nucleophile to bond with positively charged atomic nuclei. Nucleophilicity, sometimes referred to as nucleophile strength, refers to a substance's nucleophilic character and is often used to compare the affinity of atoms. Neutral nucleophilic reactions with solvents such as alcohols and water are named solvolysis. Nucleophiles may take part in nucleophilic substitution, whereby a nucleophile becomes attracted to a full or partial positive charge, and nucleophilic addition. Nucleophilicity is closely related to basicity. History The terms ''nucleophile'' and '' electrophile'' were introduced by Christopher Kelk Ingold in 1933, replacing the terms ''anionoid'' and ''catio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetraethylammonium
Tetraethylammonium (TEA), () or (Et4N+) is a quaternary ammonium cation consisting of four ethyl groups attached to a central nitrogen atom, and is positively charged. It is a counterion used in the research laboratory to prepare lipophilic salts of inorganic anions. It is used similarly to tetrabutylammonium, the difference being that its salts are less lipophilic and more easily crystallized. Preparation The chloride salt is prepared by the reaction of triethylamine and an ethyl halide: :Et3N + EtX → Et4N+X− This method works well for the preparation of tetraethylammonium iodide (where X = I). Most tetraethylammonium salts are prepared by salt metathesis reactions. For example, the synthesis of tetraethylammonium perchlorate, a salt that has been useful as a supporting electrolyte for polarographic studies in non-aqueous solvents, is carried out by mixing the water-soluble salts tetraethylammonium bromide and sodium perchlorate in water, from which the water-insoluble tetr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crown Ether
In organic chemistry, crown ethers are cyclic chemical compounds that consist of a ring containing several ether groups (). The most common crown ethers are cyclic oligomers of ethylene oxide, the repeating unit being ethyleneoxy, i.e., . Important members of this series are the tetramer (''n'' = 4), the pentamer (''n'' = 5), and the hexamer (''n'' = 6). The term "crown" refers to the resemblance between the structure of a crown ether bound to a cation, and a crown sitting on a person's head. The first number in a crown ether's name refers to the number of atoms in the cycle, and the second number refers to the number of those atoms that are oxygen. Crown ethers are much broader than the oligomers of ethylene oxide; an important group are derived from catechol. Crown ethers strongly bind certain cations, forming complexes. The oxygen atoms are well situated to coordinate with a cation located at the interior of the ring, whereas the exterior of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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