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Polycarboxylate
Polycarboxylates are linear polymers with a high molecular mass (Mr ≤ 100 000) and with many carboxylate groups. They are polymers of acrylic acid or copolymers of acrylic acid and maleic acid. The polymer is used as the sodium salt (see: sodium polyacrylate). Use Polycarboxylates are used as builders in detergents. Their high chelating power, even at low concentrations, reduces deposits on the laundry and inhibits the crystal growth of calcite. Polycarboxylate ethers (PCE) are used as superplasticizers in concrete production. Safety Polycarboxylates are poorly biodegradable but have a low ecotoxicity. In the sewage treatment plant, the polymer remains largely in the sludge and is separated from the wastewater. Polyamino acids like polyaspartic acid and polyglutamic acid have better biodegradability but lower chelating performance than polyacrylates. They are also less stable towards heat and alkali. Since they contain nitrogen, they contribute to eutrophication Eutr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aminopolycarboxylic Acid
left, 120px, a metal complex with the EDTA anion 120px, Aspartic acid is an aminodicarboxylic acid and precursor to other ligands. An aminopolycarboxylic acid (sometimes abbreviated APCA) is a chemical compound containing one or more nitrogen atoms connected through carbon atoms to two or more carboxyl groups. Aminopolycarboxylates that have lost acidic protons form strong complexes with metal ions. This property makes aminopolycarboxylic acids useful complexone in a wide variety of chemical, medical, and environmental applications. Structure The parent of this family of ligands is the amino acid glycine, H2NCH2COOH, in which the amino group, NH2, is separated from the carboxyl group, COO>H by a single methylene group, CH2. When the carboxyl group is deprotonated the glycinate ion can function as a bidentate ligand, binding the metal centre through the nitrogen and one of two carboxylate oxygen atoms, to form chelate complexes of metal ions. Replacement of a hydrogen atom on t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Builder (detergent)
Laundry detergent is a type of detergent (cleaning agent) used for cleaning dirty laundry (clothes). Laundry detergent is manufactured in powder (washing powder) and liquid form. While powdered and liquid detergents hold roughly equal share of the worldwide laundry detergent market in terms of value, powdered detergents are sold twice as much compared to liquids in terms of volume. History From ancient times, chemical additives were used to facilitate the mechanical washing of textile fibers with water. The earliest recorded evidence of the production of soap-like materials dates back to around 2800 BC in ancient Babylon. German chemical companies developed an alkyl sulfate surfactant in 1917, in response to shortages of soap ingredients during the Allied Blockade of Germany during World War I. In the 1930s, commercially viable routes to fatty alcohols were developed, and these new materials were converted to their sulfate esters, key ingredients in the commerciall ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superplasticizer
Superplasticizers (SPs), also known as high range water reducers, are additives used in making high strength concrete. Plasticizers are chemical compounds that enable the production of concrete with approximately 15% less water content. Superplasticizers allow reduction in water content by 30% or more. These additives are employed at the level of a few weight percent. Plasticizers and superplasticizers retard the curing of concrete. Generally, superplasticizer can be classified into such types:purified lignosulfonates, carboxylate synthetic polymers, sulfonated synthetic polymers and synthetic polymers with mixed functionality cementitious materials. SPs are used where well-dispersed particle suspension is required to improve the flow characteristics (rheology) of suspensions such as in concrete applications. Their addition to concrete or Mortar (masonry), mortar allows the reduction of the water to cement ratio without negatively affecting the workability of the mixture, and enab ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German ''Calcit'', a term from the 19th century that came from the Latin word for Lime (material), lime, ''calx'' (genitive calcis) with the suffix "-ite" used to name minerals. It is thus etymologically related to chalk. When applied by archaeology, archaeologists and stone trade pr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eutrophication
Eutrophication is the process by which an entire body of water, or parts of it, becomes progressively enriched with minerals and nutrients, particularly nitrogen and phosphorus. It has also been defined as "nutrient-induced increase in phytoplankton productivity". Water bodies with very low nutrient levels are termed oligotrophic and those with moderate nutrient levels are termed mesotrophic. Advanced eutrophication may also be referred to as dystrophic and hypertrophic conditions. Eutrophication can affect freshwater or salt water systems. In freshwater ecosystems it is almost always caused by excess phosphorus. In coastal waters on the other hand, the main contributing nutrient is more likely to be nitrogen, or nitrogen and phosphorus together. This depends on the location and other factors. When occurring naturally, eutrophication is a very slow process in which nutrients, especially phosphorus compounds and organic matter, accumulate in water bodies. These nutrients deriv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biodegradability
Biodegradation is the breakdown of organic matter by microorganisms, such as bacteria and fungi. It is generally assumed to be a natural process, which differentiates it from composting. Composting is a human-driven process in which biodegradation occurs under a specific set of circumstances. The process of biodegradation is threefold: first an object undergoes biodeterioration, which is the mechanical weakening of its structure; then follows biofragmentation, which is the breakdown of materials by microorganisms; and finally assimilation, which is the incorporation of the old material into new cells. In practice, almost all chemical compounds and materials are subject to biodegradation, the key element being time. Things like vegetables may degrade within days, while glass and some plastics take many millennia to decompose. A standard for biodegradability used by the European Union is that greater than 90% of the original material must be converted into , water and minerals by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyglutamic Acid
Polyglutamic acid (PGA) is a polymer of the amino acid glutamic acid (GA). Gamma PGA (Poly-γ-glutamic acid, γ-PGA) - the form where the peptide bonds are between the amino group of GA and the carboxyl group at the end of the GA side chain - is a major constituent of the Japanese food nattō. Gamma PGA is formed by bacterial fermentation. Gamma PGA has a wide number of potential uses ranging from food, medicine and cosmeceuticals to water treatment. The other isomer, poly-α-glutamic acid is being used as a drug delivery Drug delivery refers to approaches, formulations, manufacturing techniques, storage systems, and technologies involved in transporting a pharmaceutical compound to its target site to achieve a desired therapeutic effect. Principles related to dr ... system in cancer treatment and research is underway for its application in a treatment of type I diabetes and its potential use in the production of an AIDS vaccine. Heavy metal removal G-PGA covalently inco ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyaspartic Acid
Polyaspartic acid (PASA) is a biodegradable, water-soluble condensation polymer based on the amino acid aspartic acid. It is a biodegradable replacement for water softeners and related applications. PASA can be chemically crosslinked with a wide variety of methods to yield PASA hydrogels. The resulting hydrogels are pH-sensitive such that under acidic conditions, they shrink, while the swelling capacity increases under alkaline conditions. Sodium polyaspartate is a sodium salt of polyaspartic acid. In nature, PASA has been found in as fragments of larger proteins with length up to 50 amino acids, but as of 2004 had not been isolated as a pure homo polymeric material from any natural source. The first isolation of synthetic oligomeric sodium polyaspartate, obtained by thermal polycondensation of aspartic acid, was reported by Hugo Schiff in late 19th century. Later it was proposed that thermal polymerization process leads through polysuccinimide intermediate. Polyaspartic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wastewater
Wastewater is water generated after the use of freshwater, raw water, drinking water or saline water in a variety of deliberate applications or processes. Another definition of wastewater is "Used water from any combination of domestic, industrial, commercial or agricultural activities, surface runoff / storm water, and any sewer inflow or sewer infiltration". In everyday usage, wastewater is commonly a synonym for sewage (also called sewerage, domestic wastewater, or municipal wastewater), which is wastewater that is produced by a community of people. As a generic term wastewater may also be used to describe water containing contaminants accumulated in other settings, such as: * Industrial wastewater: waterborne waste generated from a variety of industrial processes, such as manufacturing operations, mineral extraction, power generation, or water and wastewater treatment. ** Cooling water, released with potential thermal pollution after use to condense steam or reduce machi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sewage Treatment Plant
Sewage treatment (or domestic wastewater treatment, municipal wastewater treatment) is a type of wastewater treatment which aims to remove contaminants from sewage to produce an effluent that is suitable for discharge to the surrounding environment or an intended reuse application, thereby preventing water pollution from raw sewage discharges. Sewage contains wastewater from households and businesses and possibly pre-treated industrial wastewater. There are a high number of sewage treatment processes to choose from. These can range from decentralized systems (including on-site treatment systems) to large centralized systems involving a network of pipes and pump stations (called sewerage) which convey the sewage to a treatment plant. For cities that have a combined sewer, the sewers will also carry urban runoff (stormwater) to the sewage treatment plant. Sewage treatment often involves two main stages, called primary and secondary treatment, while advanced treatment also incor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ecotoxicity
Ecotoxicity, the subject of study in the field of ecotoxicology (a portmanteau of ecology and toxicology), refers to the biological, chemical or physical stressors that affect ecosystems. Such stressors could occur in the natural environment at densities, concentrations, or levels high enough to disrupt natural biochemical and physiological behavior and interactions. This ultimately affects all living organisms that comprise an ecosystem. Ecotoxicology has been defined as a branch of toxicology that focuses on the study of toxic effects, caused by natural or synthetic pollutants. These pollutants affect animals (including humans), vegetation, and microbes, in an intrinsic way. Acute vs. chronic ecotoxicity According to Barrie Peake in their paper “Impact of Pharmaceuticals on the Environment.”, The ecotoxicity of chemicals can be described based on the amount of exposure to any hazardous materials. There are two categories of ecotoxicity founded off of this description: ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
