Photothermal Spectroscopy
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Photothermal Spectroscopy
Photothermal spectroscopy is a group of high sensitivity spectroscopy techniques used to measure optical absorption and thermal characteristics of a sample. The basis of photothermal spectroscopy is the change in thermal state of the sample resulting from the absorption of radiation. Light absorbed and not lost by emission results in heating. The heat raises temperature thereby influencing the thermodynamic properties of the sample or of a suitable material adjacent to it. Measurement of the temperature, pressure, or density changes that occur due to optical absorption are ultimately the basis for the photothermal spectroscopic measurements. As with photoacoustic spectroscopy, photothermal spectroscopy is an indirect method for measuring optical absorption, because it is not based on the direct measure of the light which is involved in the absorption. In another sense, however, photothermal (and photoacoustic) methods measure ''directly'' the absorption, rather than e.g. calculate it ...
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Spectroscopy
Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO) In simpler terms, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum. Historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Spectroscopy, primarily in the electromagnetic spectrum, is a fundamental exploratory tool in the fields of astronomy, chemistry, materials science, and physics, allowing the composition, physical structure and e ...
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Radiance
In radiometry, radiance is the radiant flux emitted, reflected, transmitted or received by a given surface, per unit solid angle per unit projected area. Radiance is used to characterize diffuse emission and reflection of electromagnetic radiation, and to quantify emission of neutrinos and other particles. The SI unit of radiance is the watt per steradian per square metre (). It is a ''directional'' quantity: the radiance of a surface depends on the direction from which it is being observed. The related quantity spectral radiance is the radiance of a surface per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. Historically, radiance was called "intensity" and spectral radiance was called "specific intensity". Many fields still use this nomenclature. It is especially dominant in heat transfer, astrophysics and astronomy. "Intensity" has many other meanings in physics, with the most common being power per unit ar ...
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Photothermal Microspectroscopy
Photothermal microspectroscopy (PTMS), alternatively known as photothermal temperature fluctuation (PTTF), is derived from two parent instrumental techniques: infrared spectroscopy and atomic force microscopy (AFM). In one particular type of AFM, known as scanning thermal microscopy (SThM), the imaging probe is a sub-miniature temperature sensor, which may be a thermocouple or a resistance thermometer. This same type of detector is employed in a PTMS instrument, enabling it to provide AFM/SThM images: However, the chief additional use of PTMS is to yield infrared spectra from sample regions below a micrometer, as outlined below. Technique The AFM is interfaced with an infrared spectrometer. For work using Fourier transform infrared spectroscopy (FTIR), the spectrometer is equipped with a conventional black body infrared source. A particular region of the sample may first be chosen on the basis of the image obtained using the AFM imaging mode of operation. Then, when material at this ...
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Photothermal Effect
Photothermal effect is a phenomenon associated with electromagnetic radiation. It is produced by the photoexcitation of material, resulting in the production of thermal energy (heat). It is sometimes used during treatment of blood vessel lesions, laser resurfacing, laser hair removal and laser surgery. External linksQuantities, Terminology, and Symbols in Photothermal and Related SpectroscopiesResearch paper from IUPAC The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is ...Amazing Nano Materials: Photothermal and Photoacoustic Effects Photochemistry {{chem-stub ...
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Applied Optics
''Applied Optics'' is a peer-reviewed scientific journal published by The Optical Society three times a month. It was established in 1962 with John N. Howard as founding editor-in-chief. The journal covers all aspects of optics, photonics, imaging, and sensing. According to the ''Journal Citation Reports'', the journal has a 2021 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a scientometric index calculated by Clarivate that reflects the yearly mean number of citations of articles published in the last two years in a given journal, as i ... of 1.905. References External links * {{Official website, http://www.osapublishing.org/ao/ Optics journals Optica (society) academic journals English-language journals Publications established in 1962 Journals published between 27 and 51 times per year ...
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Perfluorocarbon
Fluorocarbons are chemical compounds with carbon-fluorine bonds. Compounds that contain many C-F bonds often has distinctive properties, e.g., enhanced stability, volatility, and hydrophobicity. Fluorocarbons and their derivatives are commercial polymers, refrigerants, drugs, and anesthetics. Nomenclature Perfluorocarbons or PFCs, are organofluorine compounds with the formula CxFy, i.e., they contain only carbon and fluorine. The terminology is not strictly followed and many fluorine-containing organic compounds are called fluorocarbons. Compounds with the prefix perfluoro- are hydrocarbons, including those with heteroatoms, wherein all C-H bonds have been replaced by C-F bonds. Fluorocarbons includes perfluoroalkanes, fluoroalkenes, fluoroalkynes, and perfluoroaromatic compounds. Perfluoroalkanes Chemical properties Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. Its strength is a re ...
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Optics Letters
''Optics Letters'' is a biweekly peer-reviewed scientific journal published by The Optical Society (formerly known as Optical Society of America). It was established in July 1977. The editor-in-chief is Miguel Alonso (University of Rochester). The journal covers all topics pertaining to optics and photonics. Publishing formats are short and rapid communications, with articles being limited to four journal pages. Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2021 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a scientometric index calculated by Clarivate that reflects the yearly mean number of citations of articles published in the last two years in a given journal, as i ... of 3.560. References External links *{{Official website, http://www.osapublishing.org/ol/ Optics journals Optica (society) academic journals Publications established in ...
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Prism (optics)
An optical prism is a transparent optics, optical element with flat, polished surfaces that are designed to refraction, refract light. At least one surface must be angled — elements with two parallel surfaces are ''not'' prisms. The most familiar type of optical prism is the triangular prism, which has a triangular base and rectangular sides. Not all optical prisms are prism (geometry), geometric prisms, and not all geometric prisms would count as an optical prism. Prisms can be made from any material that is transparent to the wavelengths for which they are designed. Typical materials include glass, acrylic glass, acrylic and fluorite#Optics, fluorite. A dispersive prism can be used to break white#White light, white light up into its constituent spectral colors (the colors of the rainbow) as described in the following section. Other types of prisms noted below can be used to reflection (physics), reflect light, or to split light into components with different polarization (w ...
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Total Reflection
Total internal reflection (TIR) is the optical phenomenon in which waves arriving at the interface (boundary) from one medium to another (e.g., from water to air) are not refracted into the second ("external") medium, but completely reflected back into the first ("internal") medium. It occurs when the second medium has a higher wave speed (i.e., lower refractive index) than the first, and the waves are incident at a sufficiently oblique angle on the interface. For example, the water-to-air surface in a typical fish tank, when viewed obliquely from below, reflects the underwater scene like a mirror with no loss of brightness (Fig.1). TIR occurs not only with electromagnetic waves such as light and microwaves, but also with other types of waves, including sound and water waves. If the waves are capable of forming a narrow beam (Fig.2), the reflection tends to be described in terms of "rays" rather than waves; in a medium whose properties are independent of direction, such as air, ...
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Photothermal Optical Microscopy
Photothermal optical microscopy / "photothermal single particle microscopy" is a technique that is based on detection of non-fluorescent labels. It relies on absorption properties of labels (gold nanoparticles, semiconductor nanocrystals, etc.), and can be realized on a conventional microscope using a resonant modulated heating beam, non-resonant probe beam and lock-in detection of photothermal signals from a single nanoparticle. It is the extension of the macroscopic photothermal spectroscopy to the nanoscopic domain. The high sensitivity and selectivity of photothermal microscopy allows even the detection of single molecules by their absorption. Similar to Fluorescence Correlation Spectroscopy (FCS), the photothermal signal may be recorded with respect to time to study the diffusion and advection characteristics of absorbing nanoparticles in a solution. This technique is called photothermal correlation spectroscopy (PhoCS). Forward detection scheme In this detection scheme a co ...
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Infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around 1 millimeter (300 GHz) to the nominal red edge of the visible spectrum, around 700  nanometers (430  THz). Longer IR wavelengths (30 μm-100 μm) are sometimes included as part of the terahertz radiation range. Almost all black-body radiation from objects near room temperature is at infrared wavelengths. As a form of electromagnetic radiation, IR propagates energy and momentum, exerts radiation pressure, and has properties corresponding to both those of a wave and of a particle, the photon. It was long known that fires emit invisible heat; in 1681 the pioneering experimenter Edme Mariotte showed that glass, though transparent to sunlight, obstructed radiant heat. In 1800 the astronomer Sir William Herschel discovered ...
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